The Emerging Strategy of Symmetry Breaking for Enhancing Energy Conversion and Storage Performance DOI
Yongqi Liu,

Yixiang Luo,

Mengyang Zhang

et al.

Small Methods, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 24, 2024

Abstract Symmetry breaking has emerged as a novel strategy to enhance energy conversion and storage performance, which refers changes in the atomic configurations within material reducing its internal symmetry. According location of symmetry breaking, it can be classified into spontaneous material, local on surface caused by external fields outside material. However, there are currently few summaries this field, so is necessary summarize how improves performance. In review, fundamentals first introduced, allows for deeper understanding meaning. Then applications systematically summarized, providing various mechanisms storage, well improve performance efficiency. Last but not least, current summarized provide an outlook future development. It hoped that review new insights promote further

Language: Английский

Facet Engineering of Copper for Product Specific CO2 Electroreduction DOI
Shikha Dhakar, Sudhanshu Sharma

The Journal of Physical Chemistry C, Journal Year: 2024, Volume and Issue: 128(12), P. 4862 - 4881

Published: Feb. 12, 2024

The electroreduction of carbon dioxide (CO2) using copper-based catalysts presents an effective strategy for reducing greenhouse gas emissions while generating lucrative chemical feedstocks. Copper (Cu) has emerged as one the most efficient CO2 (CO2ER) due to its abundant availability, high selectivity, and low cost. extensively researched CO2ER always depend heavily on valence states copper. However, performance Cu can also vary significantly depending their crystallographic facets. In recent years, considerable attention been directed toward understanding role crystal facets in impact electrocatalytic CO2ER. This review article aims provide a comprehensive state art overview literature with more emphasis facet-dependent thin films. primary focus is advancements context electroreduction, enhancing selectivity C2 products film electrocatalyst. Along this, brief mention mechanistic investigations included. Finally, perspective this research direction provided addition.

Language: Английский

Citations

5
Evaluating the efficiency of single-double atom catalysts in electrochemical NH3 production from NO based on CN monolayers DOI

Mengshan Chen,

Zhouhao Zhu, Jing Chen

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(23), P. 14035 - 14044

Published: Jan. 1, 2024

The electrochemical NO reduction reaction (NORR) for the synthesis of NH 3 from nitric oxide (NO) presents a promising alternative to conventional Haber process ammonia production.

Language: Английский

Citations

4
Highly dispersed atomic-level Ni active sites confined in defects for efficient electrocatalytic reduction of carbon dioxide DOI
Wenjun Zhang, Zhao Chen, Yang Yang

et al.

Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 99, P. 1 - 10

Published: July 24, 2024

Language: Английский

Citations

4
Atomistic simulations of heterogeneous electrocatalysis at the center of sustainable carbon feedstocks DOI Creative Commons
Stefan Ringe, G. Raabe

Current Opinion in Electrochemistry, Journal Year: 2025, Volume and Issue: unknown, P. 101671 - 101671

Published: Feb. 1, 2025

Language: Английский

Citations

0
Investigating the temperature-dependent selectivity of CO2 reduction on Ru-cluster catalysts supported by MXene DOI Creative Commons
Yi Liu, Xiang Li, Yi Li

et al.

Journal of CO2 Utilization, Journal Year: 2025, Volume and Issue: 95, P. 103088 - 103088

Published: April 19, 2025

Language: Английский

Citations

0
Uncovering the Role of Critical Bonds in the Thermomechanical Response of Zn2(1,4-benzenedicarboxylate)2(1,4-diazabicyclo[2,2,2]octane) Using Ab Initio Simulations and Physics-Constrained Neural Networks DOI
Ranjana Chowdhury,

Biswajit Ghose,

Deep Choudhuri

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: May 7, 2025

Metal-organic frameworks (MOFs) are susceptible to harsh conditions involving high temperatures, mechanical loading, host/guest chemical interactions, or a combination thereof due the disruption of underlying bonds. Here, we probed thermomechanical response Zn2(BDC)2(DABCO) (BDC = 1,4-benzenedicarboxylate and DABCO 1,4-diazabicyclo[2,2,2]octane) MOF Zn-DMOF, whose metal nodes connected two BDC linkers via Zn-O N-Zn bonds, respectively. We have examined relative contributions such bonds toward Zn-MOF's at 200 300 K, by training physics-constrained neural network with ab initio molecular dynamics (AIMD)-derived interatomic vibration data, quantitatively estimated bond strengths within local environment in body. show that near Zn-based weaker than their surroundings. These findings were followed up separately annealing Zn-DMOF 920 K-AIMD (above its thermal decomposition temperature), mechanically straining it failure using 0 K-DFT, examining interactions aqueous acidic environments K-AIMD. Together, they indicated structural instability was initiated under T ≥ K. Broadly, strength estimates reasonable indicator Zn2(BDC)2(DABCO)'s performance temperatures demonstrate viability employing AIMD simulations networks quantify hybrid organic-inorganic materials.

Language: Английский

Citations

0
Gray mesoporous SnO2 catalyst for CO2 electroreduction with high partial current density and formate selectivity DOI
Mabrook S. Amer,

Haneen A. AlOraij,

Kuo‐Wei Huang

et al.

Environmental Research, Journal Year: 2024, Volume and Issue: 252, P. 118897 - 118897

Published: April 16, 2024

Language: Английский

Citations

3
Hydrogen Evolution and Carbon Dioxide Reduction Pathways on Graphitic Carbon Nitride Decorated by Single Atoms of Transition Metals‡ DOI
Anna Vidal-López,

Joan Gassó-Capdevila,

Miquel Solà

et al.

The Journal of Physical Chemistry C, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

Language: Английский

Citations

0
Divergent Activity Shifts of Tin‐Based Catalysts for Electrochemical CO2 Reduction: pH‐Dependent Behavior of Single‐Atom versus Polyatomic Structures DOI Creative Commons
Yuhang Wang, Di Zhang, Bin Sun

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 28, 2024

Tin (Sn)-based catalysts have been widely studied for electrochemical CO

Language: Английский

Citations

2
State‐of‐the‐art CO2 reduction in electrochemical microfluidic systems: A short review and new perspectives DOI
Mian Abdul Ali, Cinthia R. Zanata, Cauê A. Martins

et al.

ChemNanoMat, Journal Year: 2024, Volume and Issue: unknown

Published: May 3, 2024

Abstract The need to mitigate carbon dioxide has motivated an influx of interest in innovative technologies, and microfluidic systems have emerged as a promising forefront this endeavor. This short review analyzes CO 2 reduction within platforms, thoroughly investigating existing methodologies, challenges, novel perspectives. work commences with detailed exposition the fundamental principles governing electrolyzers, elucidating interaction microchannels electrodes. We show electrochemical reactions supporting reduction, detailing processes at cathode. use encompasses precise control over reaction conditions, efficient mass transport, reduced energy consumption, high throughput screening capabilities, integration analytical tools, portability. Catalyst selection for optimal products, technical complexities, renewable sources, cost‐effectiveness are notable challenges on horizon. A perspective potential pathways resolution is delineated, each impediment succinctly but insightfully addressed. Moreover, extends beyond looking‐back analysis, propounding It posits concept fuel cells directly fueled by . seeks inspire new researchers innovation field comparing present state‐of‐the‐art prospective avenues exploration.

Language: Английский

Citations

1