Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(46), P. 22281 - 22287
Published: Nov. 5, 2024
Electrochemically reducing CO
Language: Английский
Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(46), P. 22281 - 22287
Published: Nov. 5, 2024
Electrochemically reducing CO
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161348 - 161348
Published: March 1, 2025
Language: Английский
Citations
1Green Energy & Environment, Journal Year: 2024, Volume and Issue: unknown
Published: July 1, 2024
High-entropy materials (HEMs) have managed to make their mark in the field of electrocatalysis. The flexibly adjustable component, unique configuration and proprietary core effect endow HEMs with excellent functional feature, superior stability fast reaction kinetics. Recently, relationship between compositions structures high-entropy catalysts electrocatalytic performances has been extensively investigated. Based on this motivation, we comprehensively systematically summarize HEMs, outline intrinsic properties electrochemical advantages, generalize current state-of-the-art synthetic methods, analyze active centers conjunction characterization techniques, utilize theoretical research conduct a high-throughput screening targeted catalyst exploration mechanisms, importantly, focus specially applications propose strategies for regulating electronic structure accelerate kinetics, including morphological control, defect engineering, element regulation, strain engineering so forth. Finally, provide our personal views challenges further technical improvements catalysts. This work can valuable guidance future electrocatalysts.
Language: Английский
Citations
8Materials Today Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 100065 - 100065
Published: Sept. 1, 2024
Language: Английский
Citations
7Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 661, P. 512 - 519
Published: Feb. 2, 2024
Language: Английский
Citations
6Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 1002, P. 175256 - 175256
Published: June 25, 2024
Language: Английский
Citations
6Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 525, P. 216343 - 216343
Published: Nov. 21, 2024
Language: Английский
Citations
6Langmuir, Journal Year: 2024, Volume and Issue: 40(17), P. 9289 - 9298
Published: April 22, 2024
Copper (Cu) emerges as a highly efficient and cheap catalytic agent for the electrochemical reduction of carbon dioxide (CO2RR), promising sustainable route toward neutrality. Despite its utility, Cu catalyst exhibits limitations in terms product selectivity, highlighting need development superior design. Herein, we present density functional theory (DFT) investigation into selectivities Cu–M (M = Pt, Ni, Pd, Zn, Ag, Au) bimetallic catalysts (BMCs) reaction (CO2RR). The interaction between metals makes surface electrons reconstruct so that d-band center shifts to Fermi level. In CO2 activation, Cu–Ni performance. Additionally, Cu–Pd favors formation *COH along pathway, favoring generation CH4. Conversely, preferentially produces *CHO, thereby production CH3OH. For Cu–Ag catalyst, intermediates C2 pathway are *CO–*CHO *COH–*CHO. follows path proceeds via *CO–*CO → *CO–*COH *COH–CHO. On other hand, Cu–Pt sequence *OCH–*OCH. This study provides guiding significance design Cu-based aimed at improving efficiency CO2RR process.
Language: Английский
Citations
5Applied Catalysis A General, Journal Year: 2025, Volume and Issue: unknown, P. 120145 - 120145
Published: Jan. 1, 2025
Language: Английский
Citations
0Applied Surface Science, Journal Year: 2025, Volume and Issue: 696, P. 162892 - 162892
Published: March 5, 2025
Language: Английский
Citations
0The Chemical Record, Journal Year: 2025, Volume and Issue: unknown
Published: March 24, 2025
Abstract COFs have become the most attractive frontier research area in heterogeneous catalysis. Since geometry and electronic structure of are largely determined by their microenvironment, which turn determines performance electrocatalytic processes, precise integration atoms COF building blocks to achieve pre‐designed composition, components functions is core. This paper focuses on structural design, synthesis, mechanism application CO 2 RR (types RR, evaluation indicators relationship between performance). In addition, we also explore challenges faced corresponding solution strategies. Finally, highlighting prospects regulation, hope provide inspiration for further development applications.
Language: Английский
Citations
0