Molecular Catalysis, Journal Year: 2024, Volume and Issue: 572, P. 114792 - 114792
Published: Dec. 26, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 488, P. 151199 - 151199
Published: April 10, 2024
Language: Английский
Citations
6
Journal of Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 1008, P. 123047 - 123047
Published: Feb. 11, 2024
Language: Английский
Citations
4
Nanoscale Advances, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Exploration of single atom catalysts for unmatched efficiency and selectivity in organic transformations through morphological control metal–support interactions.
Language: Английский
Citations
0
Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137386 - 137386
Published: March 1, 2025
Language: Английский
Citations
0
Advanced Sustainable Systems, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Abstract A comprehensive understanding of the electronic structure catalytic active centers and their nearby environments is essential for clarifying link activity. This can facilitate design development novel metal‐free carbon‐based materials with desirable properties from industrial lignin waste. In this research, phosphorus (P) or nitrogen (N) atoms are incorporated into sulfur (S)‐doped porous carbon using a highly effective collosol doping carbonization method, which alters configuration sites enhances performance. The P S co‐doped (SPC) demonstrates remarkable effectiveness in oxidation benzyl alcohol (BA), reaching high conversion rate 96.6% within 2 h benzaldehyde (BAD) yield 92.5%, along turnover frequency (TOF) value 8.6 × 10 −3 mol·g −1 ·h . It also exhibits strong selectivity other functionalized alcohols. Density functional theory calculations (DFT) indicate that incorporation N atom S‐doped increases electron density at Fermi level modifies Mulliken charge distributions sites, enhancing cooperative regulation activity, particularly co‐doping structures. These findings offer guidance advanced catalysts.
Language: Английский
Citations
0
Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 9, 2025
The development of novel host-guest catalysts with nanoscale active sites provides new opportunities to gain highly efficient catalytic performance for the oxidation aromatic alcohols into high-value compounds. In this work, we develop a green and facile synthesis method incorporate Pd nanoparticles (PdNP) robust hierarchical porous Zr-metal-organic framework (Zr-IPA) through in situ solvent-free wet reduction techniques. optimized PdNP/Zr-IPA catalyst exhibits exceptional benzyl alcohol performance, selectively oxidizing 95.3% benzaldehyde (yield 97.7%) at 70 °C within 12 h. Additionally, demonstrates superior activity various using different oxidants. turnover frequency reaches 82.3 h-1 °C, which is 4.2 times larger than that pre-PdNP/Zr-IPA surpasses most reported MOF-based reactions. Quenching electron paramagnetic resonance tests verified exposed (111) faces PdNP structure can react oxidants generate •O2- radicals, play dominant role benzaldehyde. Our work strategy confining MOFs enhance targeted
Language: Английский
Citations
0
ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(14), P. 16693 - 16705
Published: July 10, 2024
Language: Английский
Citations
3
Advanced Science, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 12, 2024
Abstract As a nascent class of high‐entropy materials (HEMs), metal–organic frameworks (HE‐MOFs) have garnered significant attention in the fields catalysis and renewable energy technology owing to their intriguing features, including abundant active sites, stable framework structure, adjustable chemical properties. This review offers comprehensive summary latest developments HE‐MOFs, focusing on functional design, synthesis strategies, practical applications. work begins by presenting design principles for strategies along with detailed description commonly employed methods based existing reports. Subsequently, an elaborate discussion recent advancements achieved HE‐MOFs diverse catalytic systems storage technologies is provided. Benefiting from application strategy, derivatives demonstrate exceptional activity impressive electrochemical performance. Finally, this identifies prevailing challenges current research proposes corresponding solutions provide valuable guidance future advanced desired
Language: Английский
Citations
3
Green Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
A Co-SAC with oxidase-like active sites (CoN 4 ) has been fabricated for the construction of quinazolines and quinazolinones using ethanol as C 2 -synthon. Kinetic studies suggest that dehydrogenation is RDS reaction.
Language: Английский
Citations
2
ACS Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 18256 - 18267
Published: Nov. 26, 2024
The catalytic hydrogen transfer (CHT) cascade reaction coupling alcohols with nitro compounds to synthesize imines is highly significant due its remarkable efficiency and atom economy. However, the complicated multistep process makes single-site catalysts exhibit unsatisfactory performance for CHT reaction. Herein, inspired by findings of DFT calculations that Co nanocluster (CoNC) single (CoSA) can act as optimal active sites alcohol oxidation reduction, respectively, one dual-active site catalyst (CoSA-CoNC/CN), containing CoSA CoNC sites, was synthesized a two-step vacuum pyrolysis strategy. Benefiting from relay-like tandem catalysis CoSA, CoSA-CoNC/CN achieved an impressive 93% nitrobenzene conversion 99% imine selectivity at 160 °C in 4 h, record turnover frequency 20.9 h–1. This work provides insights into functions single-atom sheds light on rational preparation catalysts.
Language: Английский
Citations
2