Published: Jan. 1, 2024
Language: Английский
Published: Jan. 1, 2024
Language: Английский
Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 116083 - 116083
Published: March 1, 2025
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162273 - 162273
Published: April 1, 2025
Language: Английский
Citations
0Synfacts, Journal Year: 2024, Volume and Issue: 20(05), P. 0512 - 0512
Published: April 15, 2024
Key words palladium catalysis - ruthenium benzofurans hydrogenation nanoparticles
Language: Английский
Citations
0Organic Letters, Journal Year: 2024, Volume and Issue: 26(26), P. 5534 - 5538
Published: June 25, 2024
The reduction of alkenes to their respective alkanes is one the most important transformations in organic chemistry, given abundance natural and commercial olefins. Metal-catalyzed hydrogenation common way reduce alkenes; however, use H2 gas combination with precious metals required for these conditions can be impractical, dangerous, expensive. More complex substrates often require extremely high pressures H2, further emphasizing safety concerns associated reactions. Here we report a safe, cheap, practical photochemical alkene using readily available organophotocatalyst, catalytic thiol, formate. These variety di-, tri-, tetra-substituted good yield as well dearomatize pharmaceutically relevant heterocycles generate sp3-rich isosteres benzofurans indoles. formal-hydrogenation tolerate broad range functionalities that would otherwise sensitive typical hydrogenations are likely industry applications.
Language: Английский
Citations
0Published: Jan. 1, 2024
Language: Английский
Citations
0