In-situ construction of homogeneous Bi clusters by β-particle: MoS2/BiFeO3-x@POPs-β activate oxalate to photocatalytic oxidate hazardous oxygenated salts DOI
Jiang Wang,

Binbin Tan,

Z.F. Zhang

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 354, P. 128615 - 128615

Published: June 30, 2024

Language: Английский

Electrocatalytic Generation of Singlet Oxygen via ROS-Mediated Redox Chain Reaction for Efficient Disinfection DOI

Hao Shi,

Tianming Wu,

Meilin Duan

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(23), P. 6939 - 6947

Published: May 30, 2024

The risk of harmful microorganisms to ecosystems and human health has stimulated exploration singlet oxygen (1O2)-based disinfection. It can be potentially generated via an electrocatalytic process, but is limited by the low production yield unclear intermediate-mediated mechanism. Herein, we designed a two-site catalyst (Fe/Mo–N/C) for selective 1O2 generation. Mo sites enhance generation precursors (H2O2), accompanied intermediate •HO2/•O2–. Fe site facilitates activation H2O2 into •OH, which accelerates •HO2/•O2– 1O2. A possible mechanism promoting through ROS-mediated chain reaction reported. as-developed electrochemical disinfection system kill 1 × 107 CFU mL–1 E. coli within 8 min, leading cell membrane damage DNA degradation. effectively applied medical wastewater. This work provides general strategy electrocatalysis efficient

Language: Английский

Citations

10
Low-energy photoredox catalysis DOI
David C. Cabanero, Tomislav Rovis

Nature Reviews Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 11, 2024

Language: Английский

Citations

10
Insights into Substituent Effects on the Fundamental Photocatalytic Processes of Covalent Organic Frameworks toward H2 Evolution and H2O2 Production Reactions DOI
Yingying Gu, Junxia Wang, Qingqing Tang

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(15), P. 11262 - 11272

Published: July 13, 2024

Language: Английский

Citations

9
Reticular Materials for Photocatalysis DOI
Kang Sun, Yunyang Qian, Dandan Li

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 27, 2024

Abstract Photocatalysis leverages solar energy to overcome the thermodynamic barrier, enabling efficient chemical reactions under mild conditions. It can greatly reduce reliance on traditional sources and has attracted significant research interest. Reticular materials, including metal‐organic frameworks (MOFs) covalent organic (COFs), represent a class of crystalline materials constructed from molecular building blocks linked by coordination bonds, respectively. function as heterogeneous catalysts, combining well‐defined structures high tailorability akin homogeneous catalysts. In this review, regulation light absorption, charge separation, surface in photocatalytic process through precise molecular‐level design based features reticular is elaborated. Notably, for MOFsmicroenvironment modulation around catalytic sites affects performance delved, with emphasis their unique dynamic flexible microenvironments. For COFs, inherent excitonic effects due fully nature discussed highlight strategies regulate charge‐ and/or energy‐transfer‐mediated photocatalysis. Finally, current challenges future directions field, aiming provide comprehensive understanding how be optimized enhanced photocatalysis discussed.

Language: Английский

Citations

8
Reactive oxygen species generation for catalysis and biotherapeutic applications based on crystalline porous materials DOI
Yunyang Qian, Bo Li, Muhammad Irfan

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 518, P. 216068 - 216068

Published: July 17, 2024

Language: Английский

Citations

5
Photocatalytic Applications of Covalent Organic Frameworks: Synthesis, Characterization, and Utility DOI Creative Commons

Jared G. Doremus,

Bertha Lotsi,

Amit Sharma

et al.

Nanoscale, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This review highlights the recent advances in utilizing covalent organic frameworks (COFs) for photocatalytic applications.

Language: Английский

Citations

5
Molecular-based porous polymers with precise sites for photoreduction of carbon dioxide DOI
Wei-Jia Wang, Kaihong Chen

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: 36(1), P. 109998 - 109998

Published: May 11, 2024

Language: Английский

Citations

4
Visible-light-driven Z-scheme La-MOF/BiOBr heterojunction for the efficient removal of rhodamine B and hexavalent chromium from wastewater DOI

Qing Zhu,

Nan Lan,

Weikang Xu

et al.

Surfaces and Interfaces, Journal Year: 2024, Volume and Issue: 51, P. 104685 - 104685

Published: June 25, 2024

Language: Английский

Citations

4
Confining polyoxometalates in porphyrin-based porous cationic polymer toward boosting visible-light-driven synthesis of sulfoxides and detoxification of mustard gas simulants DOI
Qingshan Zhu, Haiyan An,

Yuting Wei

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 436, P. 115627 - 115627

Published: July 1, 2024

Language: Английский

Citations

4
Quinoid-locking of dyes in porous polymers enables efficient photocatalytic detoxification of sulfur mustards and green synthesis of benzimidazoles DOI
Soumitra Sau, Sudharanjan Bera, Bipul Mondal

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: 437, P. 115658 - 115658

Published: July 16, 2024

Language: Английский

Citations

4