Cited by Unravelling the synergy of platinum-oxygen vacancy in CoOx for modulating hydrogenation performance

Synergistic Catalysis of Cobalt Single Atoms and Clusters Loaded on Carbon Film: Enhancing Peroxymonosulfate Activation for Degradation of Norfloxacin DOI

Chenglin Hao,

Tinghang Li,

Yanjie Xie

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 1, 2024

Abstract Many existing research focuses on the differences or performance comparisons between single‐atom small‐sized nanocluster catalysts, but there is a lack of comprehensive coupling relationship structure and activity mechanism synergy. This study investigates combined catalytic potential cobalt single atoms (SAs) nanoclusters (NCs) for enhanced peroxymonosulfate (PMS) activation to degrade norfloxacin (NFX). A novel Co SAs‐NCs /CN/TiO 2 catalyst synthesized, featuring SAs NCs uniformly dispersed carbon film wrapping TiO , degradation efficiency NFX solution almost completely degraded, with mineralization rate 76.35%. Density functional theory (DFT) calculations indicate that synergistic interaction promotes more efficient PMS adsorption significantly reduces energy barrier, which enhances electron transfer increases reactive oxygen species (ROS) generation. highlights robust versatile nature this system in addressing various contaminants. elucidates providing new ideas advanced oxidation processes (AOPs) environmental remediation, linking emphasizes practicality importance effectively long‐term remediation water pollutants.

Language: Английский

Citations

Advanced carbon nitride‐based single‐atom photocatalysts DOI

Zifan Zhang, Kun Xiang, Haitao Wang

et al.

SusMat, Journal Year: 2024, Volume and Issue: 4(5)

Published: July 18, 2024

Abstract Single‐atom catalysts (SACs) have rapidly become a hot topic in photocatalytic research due to their unique physical and chemical properties, high activity, selectivity. Among many semiconductor carriers, the special structure of carbon nitride (C 3 N 4 ) perfectly meets substrate requirements for stabilizing SACs; they can also compensate defects C materials by modifying energy bands electronic structures. Therefore, developing advanced ‐based SACs is great significance. In this review, we focus on elucidating efficient preparation strategies burgeoning applications SACs. We outline prospective enhancing performance future. A comprehensive array methodologies presented identifying characterizing This includes an exploration potential atomic catalytic mechanisms through simulation regulation behaviors synergistic effects single or multiple sites. Subsequently, forward‐looking perspective adopted contemplate future prospects challenges associated with encompasses considerations, such as loading, regulatory design, integration machine learning techniques. It anticipated that review will stimulate novel insights into synthesis high‐load durable SACs, thereby providing theoretical groundwork scalable controllable field.

Language: Английский

Citations

Biomass upgrading of furfural to cyclopentanone via selective aqueous-phase hydrogenative rearrangement over Pd/g-C3N4 catalysts DOI

Shihao Zhang, Ruilin Xu,

Meng Chen

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159752 - 159752

Published: Jan. 1, 2025

Language: Английский

Citations

Atomically Dispersed Palladium Catalyst for Chemoselective Hydrogenation of Quinolines DOI

Shunwu Wang,

Zhenbo Guo,

Ligang Wang

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 23, 2024

Chemoselective hydrogenation of quinoline and its derivatives is a significant strategy to achieve the corresponding 1,2,3,4-tetrahydroquinolines (py-THQ) for various potential applications. Here, we precisely constructed titanium carbide supported atomically dispersed Pd catalyst (Pd

Language: Английский

Citations

Metal-nitrogen coordinated single atomic photocatalysts for solar energy conversion DOI

Yiqiao Wang,

Liling Liao,

Gangqiang Zhu

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 523, P. 216254 - 216254

Published: Oct. 15, 2024

Language: Английский

Citations

Development of efficient catalysts for selective hydrogenation through multi-site division DOI

Xiaomin Ren,

Huicong Dai,

Xin Liu

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 62, P. 108 - 123

Published: July 1, 2024

Language: Английский

Citations

Rational Design of Indium–Palladium Intermetallic Catalysts for Selective CO₂ Hydrogenation to Methanol DOI

Jiabao Lv,

Hongman Sun, Guanying Liu

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 15(1), P. 23 - 33

Published: Dec. 12, 2024

Indium–palladium intermetallic catalysts have shown great potential for CO2 hydrogenation to methanol. A deep understanding of the synergistic relationship between various components is key developing efficient indium–palladium catalysts. Here, we rationally designed a series with In–Pd ratios and found that InPd(2:1)/m-ZrO2 demonstrated highest reactivity (5.1 mmol/gcat/h), maintaining this performance even after 70 h stability testing at 270 °C 4 MPa. This impressive attributed formation stable compound chemical formula In3Pd2 which close In2O3 phase during reduction process. In situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) density functional theory (DFT) calculations were further conducted confirm formate path more favorable Adsorption energy reactants determine roles In2O3: tends adsorb activate CO2, while has an advantage dissociation H2, could compensate insufficient ability In2O3, thereby promoting reaction intermediates. These findings highlight crucial role compounds in selective

Language: Английский

Citations

Recent progress in single atom catalysts for biomass conversion DOI

Yuxin Gao,

Jinling Cheng,

Xiangwen Liu

et al.

Microstructures, Journal Year: 2025, Volume and Issue: 5(1)

Published: Feb. 17, 2025

Biomass, as an emerging environmental and renewable resource derived from various green sources, is increasingly being recognized for its inherent structural characteristics that are conducive to the production of high-value chemicals. The complicated structure oxygen-rich nature biomass derivatives necessitate targeted conversion, typically involving liquid-phase hydrogenation or addition acidic basic environments. These processes impose stringent requirements on efficiency durability catalysts. Recently, innovation single atom catalysts (SACs) with individual catalytic sites dispersed supports has demonstrated high good selectivity. Owing their atomic utilization cost-efficiency, SACs have emerged one most promising heterogeneous This review summarizes current progress conversion mediated by SACs. Significant emphasis placed unique active reaction mechanisms in kinds methods (thermocatalysis, electrocatalysis, photocatalysis). In order facilitate comparison, reactions categorized according type raw material (cellulose, hemicellulose, lignin, etc. ). Especially, developing strategies preparing summarized better satisfy industrial requirements. Finally, we provide anticipatory outlook future developments this field, focusing advanced systems.

Language: Английский

Citations

Enhanced Methyl Nitrite Carbonylation to Dimethyl Carbonate via Fully Exposed Palladium Cluster Catalysts DOI

Lingqian Ji, Lifeng Zhang, J. Y. Li

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

A fully exposed Pd cluster catalyst exhibited high activity and selectivity through the L–H mechanism.

Language: Английский

Citations

Highly active interface of Carbon-Supported Single-Atom platinum on cobalt nanoclusters for hydrogen production from sodium borohydride hydrolysis DOI

Lei Sun, Mingjie Liu, Zhijun Hou

et al.

Fuel, Journal Year: 2025, Volume and Issue: 393, P. 135069 - 135069

Published: March 13, 2025

Language: Английский

Citations