Regulating protonation paths for enhanced photocatalytic CO2 methanation by coupling Pt sites on WO2.9/TiO2 DOI
Jiajun Du, Jun Deng, Changan Zhou

et al.

Catalysis Science & Technology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Coupling Pt sites on WO 2.9 /TiO 2 can effectively regulate the hydrogen spillover by and Lewis acidity of , which facillitates CO activation.

Language: Английский

S-scheme heterojunction photocatalysts: Mechanism, challenges and opportunities DOI

Chenhui Wang,

Yuanyuan Zhao,

Chao Cheng

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 521, P. 216177 - 216177

Published: Aug. 29, 2024

Language: Английский

Citations

45
Synergy of Ni single atoms and NiO nanoclusters in carbon nitride to create local charge polarization for enhanced CO2 photoreduction DOI
Lei Li, Xinyan Dai,

Chao Cheng

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160101 - 160101

Published: Feb. 1, 2025

Language: Английский

Citations

4
N3C-Defect-Tuned g-C3N4 Photocatalysts: Structural Optimization and Enhanced Tetracycline Degradation Performance DOI Creative Commons
Lu Yu, Chengbao Liu, Leizhi Zheng

et al.

Nanomaterials, Journal Year: 2025, Volume and Issue: 15(6), P. 466 - 466

Published: March 19, 2025

The introduction of nitrogen defects in graphitic carbon nitride (g-C3N4) has the important effect improving its photocatalytic performance. This study employs a simple and environmentally friendly one-step pyrolysis method, successfully preparing g-C3N4 materials with adjustable N3C defect concentrations through calcination urea ammonium acetate mixture. By introducing adjusting band structure, conduction was shifted downward by 0.12 V, overcoming traditional application limitations enabling an innovative transition from enhanced oxidation to reduction capabilities. significantly adsorption activation O2. Characterization results showed that increased specific surface area 44.07 m2/g 87.08 m2/g, enriching reactive sites, while narrowing bandgap 2.41 eV visible light absorption capacity. activity, achieving peak performance 54.8% for tetracycline (TC), approximately 1.5 times original g-C3N4, only 5.4% (49.4%) decrease efficiency after four cycles testing. demonstrates enhances expanding potential applications environmental remediation.

Language: Английский

Citations

2
Realizing C–C Coupling via Accumulation of C1 Intermediates within Dual‐Vacancy‐Induced Dipole‐Limited Domain Field to Propel Photoreduction of CO2‐to‐C2 Fuel DOI Open Access
Yang Li, Yujie Chen, Qiu Wang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Abstract Photocatalytic conversion of CO 2 and H O into high‐value‐added C2 fuels remains a tough challenge, mainly due to the insufficient concentration photogenerated electrons for instability C1 intermediates, which often tend desorb easily disable form C─C bonds. In this work, photoreduction ‐to‐C 6 is successfully achieved by introducing adjacent C, N dual‐vacancy sites within heptazine rings ultrathin g‐C 3 4 , results in opening two neighboring forms distinctive dipole‐limited domain field (DLDF) structure. situ X‐ray photoelectron spectra fourier transform infrared provide direct evidence rapid accumulation transformation especially * CHO DLDF. Ab initio molecular dynamics further substantiates role DLDF promoting C–C coupling between through analysis interaction trajectories energy changes their central atoms, ultimately achieving high yield C up 57.86 µmol g −1 h . It first time propose concept significant advancement ‐to‐C2 fuel with evident breakthrough address challenge carbon‐containing intermediates active sites, offering new insights design single‐component photocatalysts.

Language: Английский

Citations

1
Enhancement of photocatalytic activity of 2D/2D Sb2WO6/g-C3N4 Z-scheme heterojunction via effective interfacial charge transfer DOI
Jinxin Liu, Jin‐Yuan Liu,

Qichang Peng

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2025, Volume and Issue: unknown, P. 136342 - 136342

Published: Feb. 1, 2025

Language: Английский

Citations

1
Defect‐Enriched Cobalt‐Based Coordination Polymers for Selective and Efficient Nitrate Electroreduction to Ammonia DOI Open Access

Yidan Ding,

S. Zhang, Yunxia Liu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract Electrocatalytic nitrate reduction to ammonia (NRA) offers an arousing route for converting widespread pollutant under mild conditions. Among other NRA catalysts, single‐atom catalyst (SAC) has emerged as a promising candidate due its numerous advantages such maximum metal‐atom‐utilization efficiency, homogeneous and tailorable active sites, which still encounters formidable challenge accelerate the kinetics simultaneously suppress competitive hydrogen evolution reaction, especially when operated in electrolytes with low concentration nitrate. Herein, general strategy is reported prepare defect‐enriched coordination polymer catalysts featuring well‐defined unsaturated metal can exhibit exceptional performance even at surpass SACs toward catalysis. Taking cobalt (Co) example, Co‐based polymers (d‐CoCP) counterpart CoCP without defects are investigated proof‐of‐concept study. Both experimental theoretical results elucidate that elaborately‐engineered d‐CoCP markedly decrease thermodynamic barrier reducing *NO *HNO rate‐limiting step along pathway, thus accelerating adsorption of promoting kinetics.

Language: Английский

Citations

1
Sulfur vacancy-rich ZnS on ordered microporous carbon frameworks for efficient photocatalytic CO2 reduction DOI

Xiaowu Gao,

Linglong Li,

Ziwei Zhao

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: unknown, P. 124835 - 124835

Published: Nov. 1, 2024

Language: Английский

Citations

5
Modulating the Moderate d‐Band Center of Indium in InVO4 Nanobelts by Synergizing MnOx and Oxygen Vacancies for High‐Efficiency CO2 Photoreduction DOI
Lei Li,

Huanhuan Liu,

Tianqi Li

et al.

Small, Journal Year: 2024, Volume and Issue: 20(45)

Published: July 27, 2024

Abstract Modulating the electronic properties of transition metal sites in photocatalysts at atomic level is essential for achieving high‐activity carbon dioxide photoreduction (CO 2 PR). An strategy herein proposed to engineer In‐d‐band center InVO 4 by incorporating MnO x nanoparticles and oxygen vacancies (V O ) into holey nanobelts (MnO /V ‐InVO ), which synergistically modulates a moderate consequently leads high‐efficiency CO PR. The catalyst with optimized property exhibits single evolution rate up 145.3 µmol g −1 h monoxide (CO) product selectivity 92.6%, coming out front reported ‐based materials. It discovered that modulated favors interaction between In their intermediates, thereby improves thermodynamics kinetics PR‐to‐CO reaction. This work not only demonstrates effective engineering d orbital low‐coordination atoms promote PR, but also paves way application tuning d‐band develop catalysts.

Language: Английский

Citations

4
Silicalite-1 Zeolite Enables Graphitic Carbon Nitride High Selectivity toward CO2 Photoreduction DOI
Xiaohang Yang,

Xingbo Bian,

Panxin Wang

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 115004 - 115004

Published: Dec. 1, 2024

Language: Английский

Citations

3
Supramolecular self-assembled graphitic carbon nitride catalyst: A comprehensive review on design principle, synthesis strategy, functionalization and application DOI Creative Commons
Hao Yang, Shaodong Sun, Qing Yang

et al.

Nano Materials Science, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 1, 2024

Language: Английский

Citations

3