Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131765 - 131765
Published: Jan. 1, 2025
Language: Английский
Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131765 - 131765
Published: Jan. 1, 2025
Language: Английский
Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
This review examines the strategies of symmetry breaking (charge/coordination/geometric) in single-atom catalysts to regulate active site electronic structures, greatly enhancing catalytic performance.
Language: Английский
Citations
1Rare Metals, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 11, 2025
Language: Английский
Citations
0Carbon Energy, Journal Year: 2025, Volume and Issue: unknown
Published: March 7, 2025
ABSTRACT Ruthenium (Ru)‐based electrocatalysts show great promise as substitutes for platinum (Pt) the alkaline hydrogen evolution reaction (HER) because of their efficient water dissociation capabilities. Nevertheless, strong adsorption Ru–OH intermediates (Ru‐OH ad ) blocks active site, leading to unsatisfactory HER performance. In this study, we report a universal ligand‐exchange strategy synthesizing MOF‐on‐MOF‐derived FeP–CoP heterostructure‐anchored Ru single‐atom site catalyst (Ru‐FeP‐CoP/NPC). The obtained shows low overpotential (28 mV at 10 mA cm −2 and high mass activity (9.29 A mg −1 100 mV), surpassing performance commercial Pt/C by factor 46. Theoretical studies that regulating local charge distribution sites could alleviate surrounding OH − blockages, accelerating facilitating adsorption/desorption, thus enhancing activity. This work aims inspire further design highly durable with tailored electronic properties high‐purity production.
Language: Английский
Citations
0Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 162132 - 162132
Published: March 1, 2025
Language: Английский
Citations
0Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: April 3, 2025
Electrochemical conversion has been regarded as an ideal technology for achieving clean and sustainable energy, showing significant promise in addressing the increasingly serious energy crisis environmental pollution. Ru-containing electrocatalysts (RUCE) outperform other precious metals due to elevated intrinsic activity superior cost-effectiveness, developing into a promising candidate electrochemical reactions. A challenge field of catalyst discovery lies its heavy reliance on empirical methods, rather than approaches that are rooted rational design principles. This review first concentrates catalytically active sites critical factors governing catalytic performance durability. Then, comprehensive summary multifunctional modification strategies ranging from nanoscale atomic scale is explored control structure improve performance. By unveiling roles each component modified RUCE at level, their identified discussed establish structure-performance relationship catalysts. Finally, challenges perspectives Ru-based materials hydrogen, oxygen, nitrogen reactions presented inspire further efforts toward understanding meet ever-growing demand future.
Language: Английский
Citations
0Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 536, P. 216651 - 216651
Published: April 6, 2025
Language: Английский
Citations
0Journal of Electroanalytical Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 119163 - 119163
Published: April 1, 2025
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137754 - 137754
Published: April 1, 2025
Language: Английский
Citations
0International Journal of Hydrogen Energy, Journal Year: 2024, Volume and Issue: 89, P. 618 - 623
Published: Sept. 30, 2024
Language: Английский
Citations
3Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131765 - 131765
Published: Jan. 1, 2025
Language: Английский
Citations
0