Recent Progress in Heteroatom-Containing Metalloporphyrin-Based Catalysts for CO2 Reduction DOI Creative Commons
Zhuo Li,

Qianqian Wei,

Zhixin Ren

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(11), P. 2287 - 2287

Published: May 23, 2025

Metalloporphyrins, owing to their structural resemblance natural enzyme active sites and highly tunable coordination environments, have emerged as promising catalysts for converting CO2 into value-added chemicals fuels. Considerable efforts been made modify metalloporphyrins improve catalytic capability reduction. One approach involves modifying the metal environment (known first sphere) generate heteroatom-containing metalloporphyrins, particularly N-confused O/S-substituted variants. While were synthesized in 1989, use reduction catalysis was not reported until after 2020. Herein, we review recent progress design, performance, mechanistic studies of towards This encompasses both experimental theoretical computational work, well porphyrins photocatalysis electrocatalysis. Finally, based on current research advances, present critical recommendations future directions, with a focus studies, hope facilitating rational design novel sustainable energy conversion environmental remediation.

Language: Английский

Recent Progress in Heteroatom-Containing Metalloporphyrin-Based Catalysts for CO2 Reduction DOI Creative Commons
Zhuo Li,

Qianqian Wei,

Zhixin Ren

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(11), P. 2287 - 2287

Published: May 23, 2025

Metalloporphyrins, owing to their structural resemblance natural enzyme active sites and highly tunable coordination environments, have emerged as promising catalysts for converting CO2 into value-added chemicals fuels. Considerable efforts been made modify metalloporphyrins improve catalytic capability reduction. One approach involves modifying the metal environment (known first sphere) generate heteroatom-containing metalloporphyrins, particularly N-confused O/S-substituted variants. While were synthesized in 1989, use reduction catalysis was not reported until after 2020. Herein, we review recent progress design, performance, mechanistic studies of towards This encompasses both experimental theoretical computational work, well porphyrins photocatalysis electrocatalysis. Finally, based on current research advances, present critical recommendations future directions, with a focus studies, hope facilitating rational design novel sustainable energy conversion environmental remediation.

Language: Английский

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