Impact of Impurities in 2,5-Furandicarboxylic Acid on the Synthesis of Poly(ethylene 2,5-furandicarboxylate) and Its Purification by Crystallization in a Binary Solvent System DOI

Weizhen Xie,

Xing Zhang, Yue Tang

et al.

Chinese Journal of Chemical Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Strategic Metal Doping in MnOx Catalysts Unlocks High-Yield 2,5-Furandicarboxylic Acid Production via Tailored Lattice Oxygen Activity and Oxygen Vacancies DOI
Qing Liu,

Yuan Gong,

Jing Zeng

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 21, 2025

Language: Английский

Citations

1

A Metal‐Free Carbonaceous Material for Highly Efficient and Robust Electrochemical Biomass Valorization DOI Open Access
Changlong Wang, Ziyi Zhao,

Weijin Cao

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 16, 2025

Abstract 2,5‐Furandicarboxylic acid (FDCA) synthesis holds significant importance for both bio‐polymer production and emerging sustainable bio‐based alternatives environmental energy applications. Here, a metal‐free carbonaceous material—that is, biomass substrate 5‐hydroxymethylfurfural‐derived graphene‐like nitrogen doped porous carbon sheet (GNPCH)—and its application as new catalyst electrochemical FDCA is presented. The study scrutinized the catalytic principles, demonstrated surprising robustness, explored origin of high efficiency GNPCH catalyzed electro‐synthesis FDCA. Initially, facial pyrolysis 5‐hydroxymethylfurfural urea forms ultrathin with rich micropores defects. By employing GNPCH‐900 catalyst, stable, continuous operation >400 h yields Faraday efficiencies >90% achieved; those values not only represent best that are comparable to state‐of‐the‐art metal‐based counterparts, but also showcase one longest‐running reactions. A series measurements, in situ characterization, density functional theory calculations indicate mainly from pyridinic‐N‐related active sites clarify reaction pathway. These findings suggest will be potential alternative catalysts valorization.

Language: Английский

Citations

1

Oxygen vacancy-induced interfacial Frustrated Lewis Pairs on Co3O4 for selective hydrogenation of 5-Hydroxymethylfurfural to 2,5-Bis(hydroxymethyl)furan DOI

Xiaoqing Liao,

Haishuai Cui,

He’an Luo

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 509, P. 161231 - 161231

Published: March 5, 2025

Language: Английский

Citations

1

Calcium carbonate promoted 2,5-furandicarboxylic acid production from 5‑hydroxymethylfurfural over Co-OMS-2 catalyst DOI Creative Commons
Xuyang Liu, Deguang Liu, Jiang Li

et al.

Industrial Crops and Products, Journal Year: 2025, Volume and Issue: 225, P. 120511 - 120511

Published: Jan. 20, 2025

Language: Английский

Citations

0

Mechanistic insights into highly efficient oxygenation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over natural sepiolite-supported bimetallic PdAu catalysts DOI

Xiuping Wang,

Xuemin Zhong,

Honghai Wu

et al.

Applied Surface Science, Journal Year: 2025, Volume and Issue: unknown, P. 162798 - 162798

Published: Feb. 1, 2025

Language: Английский

Citations

0

Biomass-derived Semiconductor for renewable energy technologies DOI

Siyu Ji,

Shuai Tian,

Pengcheng Guan

et al.

Chemical Communications, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

This review examines the potential of biomass-derived semiconductor materials in renewable energy technologies, highlighting key synthesis strategies from biomass precursors, as well their properties and applications.

Language: Английский

Citations

0

Impact of Impurities in 2,5-Furandicarboxylic Acid on the Synthesis of Poly(ethylene 2,5-furandicarboxylate) and Its Purification by Crystallization in a Binary Solvent System DOI

Weizhen Xie,

Xing Zhang, Yue Tang

et al.

Chinese Journal of Chemical Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0