Challenges and Progress in Rechargeable Magnesium‐Ion Batteries: Materials, Interfaces, and Devices

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 17, 2024

Abstract Rechargeable magnesium‐ion batteries (RMBs) have garnered increasing research interest in the field of post‐lithium‐ion battery technologies owing to their potential for high energy density, enhanced safety, cost‐effectiveness, and material resourcefulness. Despite substantial advancements RMB research, a number intrinsic challenges remain unresolved, such as strong Coulombic interaction between Mg 2+ host crystal structure cathode materials, sluggish diffusion kinetic, poor electrolyte compatibility, formation passivation films on anode interface. These issues hinder commercial applications RMBs. This review provides comprehensive overview progress key areas including representative storage cathode/anode materials conducting electrolytes. Additionally, recent developments electrode‐electrolyte interface regulations pouch‐cell fabrication are outlined, highlighting current implementation effective solutions. Finally, future directions proposed guide development high‐performance RMBs with practical applications.

Language: Английский

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Gel Polymer Electrolytes Based on Facile In Situ Ring‐Opening Polymerization Enabling High‐Performance Rechargeable Magnesium Batteries

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(48)

Published: June 29, 2024

Abstract Rechargeable magnesium batteries (RMBs) have emerged as one of the promising energy storage devices, and polymer electrolytes with high safety, stability, structural flexibility are ideal choice for RMBs. Herein, a novel in situ crosslinked gel electrolyte, PDTE is reported, via facile ring‐opening polymerization The electrolyte exhibits remarkable room‐temperature ionic conductivity 2.8 × 10 −4 S cm −1 highly reversible Mg plating/stripping behavior (98.9% Coulombic efficiency, 2000 cycles) low overpotential (<0.1 V). Mo 6 8 ||PDTE||Mg coin cells demonstrate exceptional cycling stability rate capability at wide temperature range (−20 to 50 °C), characterizing an average discharge capacity 81.6 mAh g C 7500 cycles room temperature, 97.4 111.7 0.2 400 −20 °C, respectively. pouch cell density 204 Wh kg retention 90.6% 350 cycles, along significantly improved safety flexibility. Additionally, good compatibility conversion‐type cathode Cu 3 Se 2 validates application versatility PDTE. development this provides feasible approach research on semi‐solid‐state

Language: Английский

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Recent Advances in Electrolytes for Magnesium Batteries: Bridging the gap between Chemistry and Electrochemistry

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(61)

Published: Aug. 22, 2024

Abstract Rechargeable magnesium batteries (RMBs) have the potential to provide a sustainable and long‐term solution for large‐scale energy storage due high theoretical capacity of (Mg) metal as an anode, its competitive redox (Mg/Mg 2+ :−2.37 V vs. SHE) natural abundance. To develop viable with density, electrolytes must meet range requirements: ionic conductivity, wide electrochemical window, chemical compatibility electrode materials other battery components, favourable electrode‐electrolyte interfacial properties cost‐effective synthesis. In recent years, significant progress in electrolyte development has been made. Herein, comprehensive overview these advancements is presented. Beginning early developments, we particularly focus on aspects their correlations properties. We also highlight design new anions practical electrolytes, use additives optimize anode‐electrolyte interfaces polymer electrolytes.

Language: Английский

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General and simple salts-mediating approach enables superior magnesium plating/stripping properties

Next Energy, Journal Year: 2025, Volume and Issue: 7, P. 100247 - 100247

Published: Feb. 3, 2025

Language: Английский

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Oxidation-Induced Nucleophilic Substitution at Electron-Rich B(12) Vertex in [CB₁₁H₁₂]^– under Catalyst-Free Conditions

Chemical Science, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Highly regioselective B(12) substitutions of the monocarborane anion [CB11H12]- has been a challenge. Here, we synthesized stable B-O-N zwitterionic compound with an impressive yield (isolated up to 98%) and excellent regioselectivity at position under catalyst-free conditions. The kinetics, substituent effect, capture experiments are paired theoretical calculations, showing that reaction mechanism is oxidation-induced nucleophilic substitution. hydride abstracted by oxoammonium oxidant lower cleavage energy 4.2 kcal mol-1 than B(7-11) positions, thereby changing electronegativity upon conversion neutral [CB11H11], in turn giving very high for This work presents effective method synthesizing oxygen derivatives anion.

Language: Английский

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A Global Challenge, A Global Solution: Battery Reuse and Recycling

Published: Feb. 21, 2025

Language: Английский

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Combustion Resistant Borohydrides and Their Chemical Interactions with Li-Metal Surfaces: An Experimental and Theoretical Study

ACS Central Science, Journal Year: 2025, Volume and Issue: unknown

Published: April 23, 2025

Language: Английский

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Directing Group Assisted Transition Metal Catalyzed Selective BH Functionalization of o-Carboranes

Synthesis, Journal Year: 2024, Volume and Issue: unknown

Published: June 11, 2024

Abstract Carboranes are a type of molecular clusters consisting carbon, hydrogen, and boron atoms. They possess unique characteristics, such as three-dimensional aromaticity, icosahedral geometry, robustness. Functionalized carboranes have been utilized in various fields, including medicine, materials, organometallic/coordination chemistry. In this context, selective functionalization o-carboranes has received tremendous attention, specifically the regio- enantioselective modification ten chemically similar BH vertices within carborane cage. recent years, significant progress made catalytic vertex-specific functionalization, well achieving cage BH. This review provides an overview advancements research field. 1 Introduction 2 Carboxy-Assisted Functionalization 2.1 Formation B–C Bonds 2.2 B–N 2.3 B–O 2.4 B–X 2.5 Consecutive B–Y (Y = N, O) 3 N-Based Directing-Group-Assisted B–H 3.1 Acylamino Directing Group 3.2 Amide 3.3 Pyridyl 3.4 Imine 4 Phosphinyl-Assisted Cage 5 Bidentate-Directing-Group-Assisted 6 Other 7 Conclusions

Language: Английский

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ACS Central Science Virtual Issue on Advanced Materials and Processes for Building Low-Carbon Energy Systems

ACS Central Science, Journal Year: 2024, Volume and Issue: 10(6), P. 1118 - 1124

Published: June 14, 2024

ADVERTISEMENT RETURN TO ARTICLES ASAPPREVEditorialNEXTACS Central Science Virtual Issue on Advanced Materials and Processes for Building Low-Carbon Energy SystemsChengyi HuChengyi HuMore by Chengyi Hu Nanfeng Zheng*Nanfeng Zheng*Email: [email protected]More Zhenghttps://orcid.org/0000-0001-9879-4790Cite this: ACS Cent. Sci. 2024, XXXX, XXX, XXX-XXXPublication Date (Web):June 14, 2024Publication History Published online14 June 2024https://pubs.acs.org/doi/10.1021/acscentsci.4c00925https://doi.org/10.1021/acscentsci.4c00925editorialACS Publications© 2024 American Chemical Society. This publication is licensed under CC-BY 4.0. License Summary*You are free to share (copy redistribute) this article in any medium or format adapt (remix, transform, build upon) the material purpose, even commercially within parameters below:Creative Commons (CC): a Creative license.Attribution (BY): Credit must be given creator.View full license*DisclaimerThis summary highlights only some of key features terms actual license. It not license has no legal value. Carefully review before using these materials. Open Access indicated. Learn MoreArticle Views150Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views COUNTER-compliant sum text downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated reflect usage leading up last few days.Citations number other articles citing article, calculated Crossref daily. Find more information about citation counts.The Altmetric Attention Score quantitative measure attention that research received online. Clicking donut icon will load page at altmetric.com with additional details score social media presence article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail (1 MB) Get e-AlertscloseSUBJECTS:Batteries,Electrocatalysts,Electrodes,Electrolytes,Materials e-Alerts

Language: Английский

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Redox-Active Carboranyl Diphosphine as an Electron and Proton Transfer Agent

Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 63(32), P. 15053 - 15060

Published: July 27, 2024

In this work, we report the first example of PCET reactivity for a boron cluster compound, zwitterionic nido-carboranyl diphosphonium derivative 7-P(H)tBu2-10-P(H)iPr2-nido-C2B10H10. This main-group reagent efficiently transfers two electrons and protons to quinones yield hydroquinones regenerate neutral closo-carboranyl diphosphine, 1-PtBu2-2-PiPr2-closo-C2B10H10. As have previously reported conversion diphosphine into nido- upon reaction with main group hydrides, transformation herein represents complete synthetic cycle metal-free reduction quinones, redox-active carboranyl scaffold acting as mediator. The proposed mechanism reduction, based on pKa determination, electrochemical studies, kinetic isotope effect involves electron transfer from quinone coupled delivery protons.

Language: Английский

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