Critical Reviews in Environmental Science and Technology, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 24
Published: Dec. 2, 2024
Mineral-organic matter (OM) associations sequester metal(loid)s in the environment, controlling their mobility and bioavailability soils. This review describes processes mechanisms operating at interfaces between OM mineral phases mineral-metal(loid)-OM metal(loid)-OM-mineral associations. It will demonstrate assumption that interact with "pure" matrixes soils is overly simplistic as numerous interactions such adsorption, precipitation incorporation of on surfaces, or within minerals can occur. For example, multi-layer organic compounds control regulate carbon sequestration. To simplify complex metal(loid)-mineral-OM interactions, we propose five nanometric for sequestration by mineral-OM associations: I. heterogeneous nucleation metal(loid)s-bearing nanomaterials (NMs) matrix, II. NMs via reduction metal(loid) species OM/mineral III. transformation preexisting NMs, IV. inclusions V. diffusion homogeneous distribution metals matrix. helps to develop potential materials (a) remediation techniques allow effective removal metal pollutants from water soil (b) biomass storage sequestrate stabilize terrestrial systems thus help fight current climate change. Future studies need identify spatial functional complexity structure composition associations, which adsorbed incorporated transform during multi-dynamic processes.
Language: Английский