MXenes and Their Derivatives for Advanced Solid‐State Energy Storage Devices DOI
Quanyan Man, Yongling An, Hengtao Shen

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 33(41)

Published: June 7, 2023

Abstract Solid‐state energy storage devices (SSESDs) are believed to significantly improve safety, long‐term electrochemical/thermal stability, and energy/power density as well reduce packaging demands, showing the huge application potential in large‐scale storage. Nevertheless, some key issues like low ionic conductivities, poor interface contact, dendrites growth limit practical of SSESDs. In recent years, MXenes for SSESDs have received reassuring advances on account unique parameters. overall reviews about subject seldom. this review, current their derivatives solid‐state Li–metal, Li‐ion, Li–I/S, Na‐ion, Zn–air, Zn–metal batteries, supercapacitors cathode/anode optimization, medication, electrolyte fillers, etc., comprehensively reviewed. First all, essential principles shown, such precursors, etching/delamination strategies, superior properties systems. Meanwhile, classification evaluation parameters electrolytes summarized. Subsequently, application, modification mechanism, design strategy boosting electrochemical behaviors systematically reviewed discussed. At last, perspectives challenges future construction strategies recommended. This review shall assist scientists build advanced with along safety.

Language: Английский

Enabling All‐Solid‐State Li Metal Batteries Operated at 30 °C by Molecular Regulation of Polymer Electrolyte DOI
Ying Wei, Te‐Huan Liu, Wenjiang Zhou

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(10)

Published: Jan. 20, 2023

Abstract The low ionic conductivity of poly(ethylene oxide) (PEO)‐based polymer electrolytes at room temperature and the undesired lithium‐dendrite growth Li|PEO interface impede their further application. Herein, a PEO is regulated molecular level through copper ion (Cu 2+ ) coordination effect with both Li salts to achieve high + 0.2 mS cm −1 transference number 0.42 30 °C. Moreover, Cu‐coordinated electrolyte neither sticky nor hygroscopic because hydrophilic oxygen groups in are terminated by Cu ions. Furthermore, situ formed F/Li‐rich inorganic layer induced CuF 2 additive accelerates transport kinetics enables uniform deposition during plating/stripping. As result, ‐coordinated deliver critical current density 1.5 mA −2 An all‐solid‐state Li‐LiNi 0.83 Co 0.12 Mn 0.05 O (NCM83) battery such coordinated exhibits long cycle life over 500 cycles capacity retention 71% under 0.6 C When mass loading increases record 7 mg , Li‐NCM83 cell delivers areal 1.07 mAh 0.1

Language: Английский

Citations

123
Priority and Prospect of Sulfide‐Based Solid‐Electrolyte Membrane DOI
Hong Liu, Yuhao Liang, Chao Wang

et al.

Advanced Materials, Journal Year: 2022, Volume and Issue: 35(50)

Published: Aug. 19, 2022

Abstract All‐solid‐state lithium batteries (ASSLBs) employing sulfide solid electrolytes (SEs) promise sustainable energy storage systems with energy‐dense integration and critical intrinsic safety, yet they still require cost‐effective manufacturing the of thin membrane‐based SE separators into large‐format cells to achieve scalable deployment. This review, based on an overview materials, is expounded why implementing a separator priority for mass production ASSLBs criteria capturing high‐quality membrane are identified. Moreover, from aspects material availability, processing, cell integration, major challenges associated strategies described meet these throughout whole chain provide realistic assessment current status membranes. Finally, future directions prospects manufacturable membranes presented.

Language: Английский

Citations

77
Solid-state lithium batteries-from fundamental research to industrial progress DOI
Dengxu Wu, Liquan Chen, Hong Li

et al.

Progress in Materials Science, Journal Year: 2023, Volume and Issue: 139, P. 101182 - 101182

Published: Aug. 18, 2023

Language: Английский

Citations

72
A Dynamically Stable Mixed Conducting Interphase for All‐Solid‐State Lithium Metal Batteries DOI
Shuai Li,

Shi‐Jie Yang,

Gui‐Xian Liu

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 36(3)

Published: Oct. 18, 2023

Abstract All‐solid‐state lithium (Li) metal batteries (ASSLMBs) employing sulfide solid electrolytes have attracted increasing attention owing to superior safety and high energy density. However, the instability of against Li induces formation two types incompetent interphases, electrolyte interphase (SEI) mixed conducting (MCI), which significantly blocks rapid Li‐ion transport uneven deposition continuous interface degradation. In this contribution, a dynamically stable (S‐MCI) is proposed by in situ stress self‐limiting reaction achieve compatibility with composite (Li 6 PS 5 Cl (LPSCl) 10 GeP 2 S 12 (LGPS)). The rational design utilizes expansion induced decomposition turn constrain further LGPS. Consequently, S‐MCI inherits dynamical stability LPSCl‐derived SEI lithiophilic affinity Li–Ge alloy LGPS‐derived MCI. Li||Li symmetric cells protection can operate stably for 1500 h at 0.5 mA cm −2 mAh . Li||NCM622 full present cycling 100 cycles 0.1 C high‐capacity retention 93.7%. This work sheds fresh insight into constructing electrochemically high‐performance ASSLMBs.

Language: Английский

Citations

66
Electron Redistribution Enables Redox‐Resistible Li6PS5Cl towards High‐Performance All‐Solid‐State Lithium Batteries DOI
Chong Liu, Butian Chen, Tianran Zhang

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(22)

Published: March 29, 2023

Sulfide electrolytes with high ionic conductivity hold great promise for all-solid-state lithium batteries. However, the parasitic redox reactions between sulfide electrolyte and Li metal result in interfacial instability rapid decline of battery performance. Herein, a redox-resistible Li6 PS5 Cl (LPSC) is created by regulating electron distribution LPSC Mg F incorporation. The introduction triggers agglomeration around S atom, inhibiting acceptance from Li, generates self-limiting interface, which hinders metal. This Cl-MgF2 therefore presents critical current density (2.3 times that pristine electrolyte). LiCoO2 /Li6 /Li cell shows an outstanding cycling stability (93.3 %@100 cycles at 0.2 C). study highlights electronic structure modulation to address issues on sulfide-based

Language: Английский

Citations

58
Practical considerations for enabling Li|polymer electrolyte batteries DOI Creative Commons
Peter Lennartz, Benjamin Paren, Abraham Herzog‐Arbeitman

et al.

Joule, Journal Year: 2023, Volume and Issue: 7(7), P. 1471 - 1495

Published: June 30, 2023

Language: Английский

Citations

56
In Situ Topological Interphases Boosting Stable Solid‐State Lithium Metal Batteries DOI Open Access
Hantao Xu, Jianyong Zhang, Hong Zhang

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(21)

Published: April 23, 2023

Abstract Incompatible interphases resulting from the irreconcilable contradiction between impedance and mechanical strength have become one of major obstacles to practical application solid‐state lithium metal batteries (SSLMBs). With employment a decoupling strategy by rational topological design, herein polymer‐reinforced interphase layer is in situ constructed using synthesized solid polymer electrolyte. As result, electrolyte (SEI) harmonizes enhanced mechanochemical stability fast diffusion dynamics Li + , which maintains integrity SEI during cycling. In addition, highly stable reversible nucleation/stripping behaviors exceeding 3000 h superior cycling performance LiFePO 4 /Li battery beyond 500 cycles can be achieved virtue formation layer. This design constructing decouple activation energy transport provides feasible paradigm for realizing SSLMBs.

Language: Английский

Citations

53
Ultrastable 1T-2H WS2 Heterostructures by Nanoarchitectonics of Phosphorus-Triggered Phase Transition for Hybrid Supercapacitors DOI
Pragati A. Shinde, Nilesh R. Chodankar, Hyung‐Jin Kim

et al.

ACS Energy Letters, Journal Year: 2023, Volume and Issue: 8(10), P. 4474 - 4487

Published: Oct. 2, 2023

Tungsten disulfide (WS2) has recently emerged as a nontrivial material for electrochemical applications; however, boundaries associated with its 1T and 2H phases limit performance. Here, this issue is addressed by evolving dual-phase 1T-2H WS2 heterostructure that combines two different directly on the current collector. The resulting demonstrated 2D transformable phase structure, large interlayer distance, highly exposed edge-active sites. Theoretical calculations confirmed formed after phosphorus doping exhibits semimetallic feature, elucidating high electronic conductivity. edge-enriched metallic engineering of validate exceptional Na+ ion intercalation. hybrid supercapacitor cell assembled anode Prussian blue analogue (PBA) cathode shows specific energy 65.5 Wh kg–1 at 784 W kg–1, 95.7% cycling stability. This work paves technique transition sheds light expansion efficient storage devices.

Language: Английский

Citations

53
From Liquid to Solid-State Lithium Metal Batteries: Fundamental Issues and Recent Developments DOI Creative Commons
Zhao Zhang, Wei‐Qiang Han

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 16(1)

Published: Nov. 20, 2023

The widespread adoption of lithium-ion batteries has been driven by the proliferation portable electronic devices and electric vehicles, which have increasingly stringent energy density requirements. Lithium metal (LMBs), with their ultralow reduction potential high theoretical capacity, are widely regarded as most promising technical pathway for achieving batteries. In this review, we provide a comprehensive overview fundamental issues related to reactivity migrated interfaces in LMBs. Furthermore, propose improved strategies involving interface engineering, 3D current collector design, electrolyte optimization, separator modification, application alloyed anodes, external field regulation address these challenges. utilization solid-state electrolytes can significantly enhance safety LMBs represents only viable approach advancing them. This review also encompasses variation design transition from liquid solid electrolytes. Particularly noteworthy is that introduction SSEs will exacerbate differences electrochemical mechanical properties at interface, leading increased inhomogeneity-a critical factor contributing failure all-solid-state lithium Based on recent research works, perspective highlights status developing high-performance

Language: Английский

Citations

50
Li–Solid Electrolyte Interfaces/Interphases in All-Solid-State Li Batteries DOI Creative Commons

Linan Jia,

Jinhui Zhu, Xi Zhang

et al.

Electrochemical Energy Reviews, Journal Year: 2024, Volume and Issue: 7(1)

Published: March 18, 2024

Abstract The emergence of all-solid-state Li batteries (ASSLBs) represents a promising avenue to address critical concerns like safety and energy density limitations inherent in current Li-ion batteries. Solid electrolytes (SEs) show significant potential curtailing dendrite intrusion, acting as natural barriers against short circuits. However, the substantial challenges at SEs−electrode interface, particularly concerning anode, pose impediments practical implementation ASSLBs. This review aims delineate most viable strategies for overcoming anode interfacial hurdles across four distinct categories SEs: sulfide SEs, oxide polymer halide SEs. Initially, pivotal issues such side reactions, inadequate physical contact, formation are comprehensively outlined. Furthermore, effective methodologies aimed enhancing stability expounded, encompassing approaches solid electrolyte interface (SEI) interlayer insertion, SE optimization, adoption alloy lieu metal, each tailored specific categories. Moreover, this presents novel insights into fostering interfaces between diverse types anodes, while also advocating perspectives recommendations future advancement Graphical

Language: Английский

Citations

45