ACS Applied Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: May 1, 2025
Language: Английский
National Science Review, Journal Year: 2024, Volume and Issue: 11(7)
Published: May 25, 2024
ABSTRACT High-voltage aqueous zinc ion batteries (AZIBs) with a high-safety near-neutral electrolyte is of great significance for practical sustainable application; however, they suffer from anode and electrode/electrolyte interfacial incompatibility. Herein, conversion-type chemistry low anodic potential, which guided by the Gibbs free energy change conversion reaction, was designed high-voltage AZIBs. A reversible reaction between ZnC2O4·2H2O particles three-dimensional Zn metal networks well-matched in CH3COOLi-based revealed. This mechanism can be universally validated battery systems sodium or iodine ions. More importantly, cathodic crowded micellar water confinement effect proposed lies core stability reversibility cathode under an operating platform voltage beyond 2.0 V, obtaining capacity retention 95% after 100 cycles. Remarkably, scientific technological challenges coin cell to Ah-scale battery, sluggish kinetics solid-solid electrode excitation high loading active material, preparation complexities associated large-area quasi-solid electrolytes, were explored, successfully achieving 88% more than 20 mg cm−2 particularly 1.1 Ah-level pouch cell. work provides path designing low-cost, eco-friendly batteries.
Language: Английский
Citations
35
Nano-Micro Letters, Journal Year: 2024, Volume and Issue: 16(1)
Published: Aug. 14, 2024
Zinc-ion batteries are promising for large-scale electrochemical energy storage systems, which still suffer from interfacial issues, e.g., hydrogen evolution side reaction (HER), self-corrosion, and uncontrollable dendritic Zn electrodeposition. Although the regulation of electric double layer (EDL) has been verified principle to select additive as regulator is misted. Here, several typical amino acids with different characteristics were examined reveal behaviors in regulated EDL on anode. Negative charged acidic polarity (NCAP) unveiled guideline selecting reconstruct an inner zincophilic H
Language: Английский
Citations
23
Nano Letters, Journal Year: 2024, Volume and Issue: 24(43), P. 13653 - 13661
Published: Oct. 21, 2024
Reducing the charging voltage is a prerequisite for improving chargeability and energy efficiency of Zn-air batteries (ZABs). Herein, Fe
Language: Английский
Citations
16
Journal of Energy Chemistry, Journal Year: 2024, Volume and Issue: 96, P. 359 - 386
Published: May 15, 2024
Language: Английский
Citations
15
ACS Energy Letters, Journal Year: 2024, Volume and Issue: 9(7), P. 3269 - 3289
Published: June 7, 2024
Zinc metal batteries have emerged as promising candidates for next-generation energy storage devices due to their high capacities, safety, and cost-effectiveness. However, the implementation of Zn anodes (ZMAs) faces significant challenges, including uncontrollable dendrite growth, pronounced corrosion, notable side reactions. To address these issues, extensive research efforts are underway, focusing on tailored structures, compositions, interfaces ZMAs, supported by multi-level engineering approaches. Various efficient solutions been proposed verified, homogenizing ion flux/electric field, enriching nucleation site number, reducing barriers, providing sufficient space deposition. This Review provides a thorough summary recent advancements in innovative design from viewpoints structural interfacial strategies. Key concepts functional mechanisms resolving aforementioned issues ZMAs highlighted. Furthermore, remaining challenges discussed, future directions also identified.
Language: Английский
Citations
13
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 497, P. 154916 - 154916
Published: Aug. 17, 2024
Language: Английский
Citations
10
Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 76 - 87
Published: Sept. 3, 2024
Language: Английский
Citations
9
Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104113 - 104113
Published: Feb. 1, 2025
Language: Английский
Citations
1
Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: March 10, 2025
In this field guide, we outline empirical and theory-based approaches to characterize the fundamental properties of liquid multivalent-ion battery electrolytes, including (i) structure chemistry, (ii) transport, (iii) electrochemical properties. When detailed molecular-scale understanding multivalent electrolyte behavior is insufficient use examples from well-studied lithium-ion electrolytes. recognition that coupling techniques highly effective, but often nontrivial, also highlight recent characterization efforts uncover a more comprehensive nuanced underlying structures, processes, reactions drive performance system-level behavior. We hope insights these discussions will guide design future studies, accelerate development next-generation batteries through modeling with experiments, help avoid pitfalls ensure reproducibility results.
Language: Английский
Citations
1
cMat., Journal Year: 2024, Volume and Issue: 1(2)
Published: Sept. 1, 2024
Abstract Aqueous zinc metal batteries have attracted much attention in the field of large‐scale energy storage due to their abundant resources, high safety, low cost, and theoretical density. However, Zn anodes suffer from serious problems such as dendrite growth, hydrogen evolution reaction, corrosion, passivation. Cu‐based materials a wide range applications excellent zincophilicity. Unfortunately, relevant review on anode electrode is still lacking. This focuses progress, issues, optimization strategies anodes. The application Cu collectors corresponding modifications are also highlighted. Finally, insights future directions related for modified presented provide scientific guidance research.
Language: Английский
Citations
7