Recent Advances in Buffer Layer Engineering for Performance Enhancement in Inverted Perovskite Solar Cells: Material-Based Classification DOI
Y. S. Lim, Soo Young Kim

Transactions on Electrical and Electronic Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 24, 2025

Language: Английский

Tailoring Buried Interface and Minimizing Energy Loss Enable Efficient Narrow and Wide Bandgap Inverted Perovskite Solar Cells by Aluminum Glycinate Based Organometallic Molecule DOI Open Access
Ming Cheng, Yuwei Duan, Dexin Zhang

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 3, 2025

Abstract Rational regulation of Me‐4PACz/perovskite interface has emerged as a significant challenge in the pursuit highly efficient and stable perovskite solar cells (PSCs). Herein, an organometallic molecule aluminum glycinate (AG) that contained amine (‐NH 2 ) hydroxyl (Al‐OH) groups is developed to tailor buried minimize interface‐driven energy losses. The Al‐OH selectively bonded with unanchored O═P‐OH bare NiO‐OH optimize surface morphology levels, while ‐NH group interacted specifically Pb 2+ retard crystallization, passivate Pb‐related defects, release residual stress. These interactions facilitate carrier extraction reduce losses, thereby realizing balanced charge transport. Consequently, AG‐modified narrow bandgap (1.55 eV) PSC demonstrates efficiency 26.74% (certified 26.21%) fill factor 86.65%; wide (1.785 realizes 20.71% champion excellent repeatability. PSCs maintain 91.37%, 91.92%, 92.00% their initial after aging air atmosphere, nitrogen‐filled atmosphere at 85 °C, continuously tracking maximum power‐point under one‐sun illumination (100 mW cm −2 for 1200 h, respectively.

Language: Английский

Citations

1

Multi-functional interface modification and/or passivation materials in inverted perovskite solar cells DOI

N. K. Chen,

Jian Zhou,

Youyou Yuan

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 106084 - 106084

Published: Feb. 1, 2025

Language: Английский

Citations

1

Ferrocene Interlayer for a Stable and Gap-Free P3HT-Based Perovskite Solar Cell as a Low-Cost Power Source for Indoor IoTs DOI Creative Commons
Chaowaphat Seriwattanachai, Somboon Sahasithiwat, Thana Chotchuangchutchaval

et al.

ACS Photonics, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 15, 2025

Although poly(3-hexylthiophene-2,5-diyl) (P3HT) with its stability-boosting hydrophobic surface is a promising low-cost alternative dopant-free hole transport material for n-i-p perovskite solar cells (PSCs), the P3HT-based PSCs suffer from energy mismatch between hydrophilic and P3HT, which results in interlayer gap, poor electronic contact, charge extraction. In this study, ferrocene (Fc) acts as an at perovskite/P3HT interface, inducing replacement of edge-on stacking alkyl side chains π–π thiophene rings within P3HT structure to mitigate such mismatch. With optimal amount Fc, average PCE 23.6% has been achieved under indoor light 1000 lux comparison 20.6% without Fc. addition, unencapsulated device can retain 80% initial (T80) over 12 months dark 70% RH, longer than T80 8 Finally, Bluetooth sensor module powered by three Fc-passivated connected series demonstrate capacity replacing batteries used Internet Things (IoTs).

Language: Английский

Citations

0

Ferrocene-Driven Revolution in Perovskite Photovoltaics DOI
Mingxia Lu, Xueke Sun, Cong Chen

et al.

Nano Energy, Journal Year: 2025, Volume and Issue: unknown, P. 110720 - 110720

Published: Jan. 1, 2025

Citations

0

Toughened Interface by Engineering the Side Group of Conjugated Polymers to Stabilize Flexible Perovskite Solar Modules DOI Open Access
Wei Zhang, Peng Xu, Jin Wang

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: March 10, 2025

Perovskite solar cells (PSCs) have attracted considerable attention due to their high power conversion efficiency (PCE), cost-effective manufacturing processes, as well the potential flexibility. However, a significant challenge commercial applications of PSCs is mechanical reliability. In this work, three naphthalene diimide polymers with distinct donor units are chosen reduce surface trap states and enhance long-term stability reliability photovoltaic devices. The champion rigid incorporating conjugated achieved 373% increase adhesion toughness at interface, PCE 25.5% for 0.16 cm2 single cell 22.3% 30.9 module retain 97% initial after 2000 h continuous light soaking. Especially, flexible exhibited improved stability, achieving 24.8% 20.3% 27.9 module, maintaining 95% 5,000 bending cycles. This study highlights interfacial polymer in enhancing PSCs.

Language: Английский

Citations

0

Interface regulation with D-A-D type small molecule for efficient and durable perovskite solar cells DOI
Mengde Zhai,

Zhanglin Guo,

Jinman Yang

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

Citations

0

N‐Type Doping Characteristics Enabled by 1D Perovskite for Advancing Perovskite Photovoltaics: From 1.55 to 1.85 eV Bandgap DOI

Xianfang Zhou,

Fei Wang,

Yonggui Sun

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 15, 2025

Abstract Developing low‐dimensional perovskites to enhance both single‐junction and tandem solar cells is of great interest for improving photovoltaic performance durability. Herein, a novel 1D perovskite based on 1,3‐thiazole‐2‐carboximidamide (TZC) cation introduced, which exhibits robust chemical interactions with PbI 2 3D perovskite, enabling the fabrication high‐quality mixed‐dimensional films identified by HR‐TEM GIWAXS analyses. Benefiting from lower formation energy barrier perovskites, they can preferentially form act as crystal seeds regulate crystallization kinetics optimized morphology improved crystallinity. In addition effectively passivating surface defects suppressing nonradiative recombination, TZC‐enabled exhibit pronounced n‐type doping characteristics, leading an elevated Fermi level (from −4.63 −4.44 eV) facilitating charge carrier extraction transport in p‐i‐n devices. As result, this strategy not only significantly enhances power conversion efficiency (PCE) widely studied 1.55 eV bandgap but also boosts PCE 1.68 1.85 wide‐bandgap devices, achieving outstanding PCEs 22.52% 18.65%, respectively. These findings highlight immense potential TZC‐functionalized enhancing high‐performance cell applications.

Language: Английский

Citations

0

Recent Advances in Buffer Layer Engineering for Performance Enhancement in Inverted Perovskite Solar Cells: Material-Based Classification DOI
Y. S. Lim, Soo Young Kim

Transactions on Electrical and Electronic Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 24, 2025

Language: Английский

Citations

0