Molecular composition of secondary brown carbon from styrene at low-to-high oxidation degrees
Shan Zhang,
No information about this author
Kun Li,
No information about this author
Xiaowen Chen
No information about this author
et al.
Environmental Pollution,
Journal Year:
2025,
Volume and Issue:
368, P. 125795 - 125795
Published: Feb. 3, 2025
Language: Английский
Evolution of black carbon and brown carbon during summertime in Southwestern China: An assessment of control measures during the 2023 Chengdu Summer World University Games
Zhier Bao,
No information about this author
Xiaoling Zeng,
No information about this author
Jiawei Zhou
No information about this author
et al.
Environmental Pollution,
Journal Year:
2024,
Volume and Issue:
357, P. 124467 - 124467
Published: June 29, 2024
Language: Английский
Light Absorption Properties of Brown Carbon Aerosol During Winter at a Polluted Rural Site in the North China Plain
Yanan Tao,
No information about this author
Zheng Yang,
No information about this author
Xinyu Tan
No information about this author
et al.
Atmosphere,
Journal Year:
2024,
Volume and Issue:
15(11), P. 1294 - 1294
Published: Oct. 28, 2024
Brown
carbon
aerosols
(BrC),
a
subfraction
of
organic
aerosols,
significantly
influence
the
atmospheric
environment,
climate
and
human
health.
The
North
China
Plain
(NCP)
is
hotspot
for
BrC
research
in
China,
yet
our
understanding
optical
properties
rural
regions
still
very
limited.
In
this
study,
we
characterize
chemical
components
light
absorption
at
site
during
winter
NCP.
average
mass
concentration
PM1
135.1
±
82.3
μg/m3;
organics
nitrate
are
main
PM1.
coefficient
(babs,BrC)
53.6
45.7
Mm−1,
accounting
39.5
10.2%
total
370
nm.
Diurnal
variations
reveal
that
babs,BrC
lower
afternoon,
attributed
to
evolution
planetary
boundary
layers.
mainly
emitted
locally,
both
aqueous
phase
photooxidation
reactions
can
increase
babs,BrC.
Notably,
reduced
when
RH
>
65%.
During
foggy
conditions,
facilitate
formation
secondary
contribute
bleaching
BrC.
This
process
ultimately
causes
decrease
Ångström
exponent
(AAE)
efficiency
(MAE).
contrast,
babs,BrC,
along
with
AAE
MAE,
rise
due
substantial
primary
emissions.
study
enhances
polluted
Language: Английский
Chemical Fate of Particulate Sulfur from Nighttime Oxidation of Thiophene
Michael Lum,
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Kunpeng Chen,
No information about this author
B. Ries
No information about this author
et al.
ACS ES&T Air,
Journal Year:
2024,
Volume and Issue:
1(12), P. 1637 - 1649
Published: Nov. 27, 2024
Sulfur-containing
volatile
organic
compounds
emitted
during
wildfire
events,
such
as
dimethyl
sulfide,
are
known
to
form
secondary
aerosols
containing
inorganic
sulfate
(SO42–)
and
surfactant-like
compounds;
however,
little
is
about
the
fate
of
sulfur
in
other
reduced
organosulfur
species.
This
study
aimed
determine
sulfurous
product
distribution
resulting
from
nighttime
oxidation
thiophene
a
model
system.
Ion
chromatography
(IC)
aerosol
mass
spectrometry
(a
mini
spectrometer,
mAMS)
were
used
constrain
proportions
produced
under
wildfire-relevant
conditions
([NO2]/[O3]
=
0.1).
With
constraints
IC,
results
indicated
that
particle
consisted
30.3
±
6.6%
SO42–,
while
mAMS
fractionation
attributed
24.5
1.6%
total
signal
15.4
1.9%
organosulfates,
60.1
0.9%
sulfonates.
Empirical
formulas
products
identified
C1–C8
organosulfates
sulfonates
using
complementary
techniques.
highlights
its
derivatives
source
SO42–
particulate
compounds,
which
have
important
implications
for
atmospheric
budget
aerosol/droplet
physical
chemical
properties.
Language: Английский
The semi-solid phase of atmospheric particles facilitates the formation of secondary brown carbon: possible contribution of ionic strength to Maillard-like reactions
Jiali Xie,
No information about this author
Feixue Zheng,
No information about this author
Yusheng Zhang
No information about this author
et al.
Atmospheric Environment,
Journal Year:
2024,
Volume and Issue:
unknown, P. 120991 - 120991
Published: Dec. 1, 2024
Language: Английский
Ultrafine Particle Generation from Ozone Oxidation of Cannabis Smoke
Environmental Science & Technology,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 18, 2024
Cannabis
smoke
is
a
complex
aerosol
mixture,
featuring
characteristic
monoterpenes
and
sesquiterpenes
which
are
susceptible
to
reaction
with
ozone
other
oxidants.
These
reactions
form
less-volatile
species
can
contribute
secondary
organic
(SOA)
ultrafine
particle
(UFP)
formation.
In
this
work,
the
of
cannabis
was
observed
in
an
environmental
chamber.
Particle
size
distribution,
gas-phase
particle-phase
composition
were
monitored
real
time.
The
diameter
primary
particles
ranged
from
10
Language: Английский