Construction of Cu2Y2O5/g-C3N4 Novel Composite for the Sensitive and Selective Trace-Level Electrochemical Detection of Sulfamethazine in Food and Water Samples DOI Creative Commons

R. Surya,

Subramanian Sakthinathan,

Ganesh Abinaya Meenakshi

et al.

Sensors, Journal Year: 2024, Volume and Issue: 24(17), P. 5844 - 5844

Published: Sept. 9, 2024

The most frequently used sulfonamide is sulfamethazine (SMZ) because it often found in foods made from livestock, which hazardous for individuals. Here, we have developed an easy, quick, selective, and sensitive analytical technique to efficiently detect SMZ. Recently, transition metal oxides attracted many researchers their excellent performance as a promising sensor SMZ analysis of superior redox activity, electrocatalytic electroactive sites, electron transfer properties. Further, Cu-based resilient electrical conductivity; however, boost extreme extent, composite including two-dimensional (2D) graphitic carbon nitride (g-C3N4) nanosheets needs be constructed ready (denoted g-C3N4/Cu2Y2O5). Moreover, several techniques, X-ray diffraction analysis, scanning microscopy energy-dispersive spectroscopy, Fourier transform infrared Raman spectroscopy were employed analyze the composites. electrochemical measurements revealed that g-C3N4/Cu2Y2O5 composites exhibit great activity. Nevertheless, achieved outstanding repeatability reproducibility alongside low limit detection (LOD) 0.23 µM, long linear range 2 276 electrode sensitivity 8.86 µA µM−1 cm−2. Finally, proposed GCE/g-C3N4/Cu2Y2O5 proved highly effective food samples, with acceptable recoveries. has been successfully applied water samples.

Language: Английский

Graphitic Carbon Nitride Nanosheets Decorated with Strontium Tungstate Nanospheres as an Electrochemical Transducer for Sulfamethazine Sensing DOI

Muthukumar Govindaraj,

Jerome Rajendran,

Udhaya Ganesh P K

et al.

ACS Applied Nano Materials, Journal Year: 2023, Volume and Issue: 6(2), P. 930 - 945

Published: Jan. 9, 2023

Sulfamethazine (SMZ) is one of the most frequently utilized sulfonamides, and it regularly found in animal-derived foods, posing a health risk. Hence, developing quick, easy, selective, sensitive analytical method for on-site detection SMZ essential improving food safety. Recently, transition-metal oxides have attracted great interest as promising sensors detecting sulfamethazine due to their superior redox behavior, electrochemical activity, electroactive sites. However, they tremendously suffer from poor electrical conductivity stability, which limits commercial reality. Herein, highly selective sensor consisting two-dimensional (2D) graphitic carbon nitride nanosheet (g-C3N4) networks anchored strontium tungstate nanospheres (denoted SrWO4/g-C3N4) developed nonenzymatic detection. When employed sensing platform, SrWO4/g-C3N4 hybrid shows enhanced performance with fast response time, high sensitivity, low limit 0.0059 μM, wide ranges 0.2 600 prolonged cycle life over 30 days. The performs well real sample analysis, reflecting its practical applicability. Such may be attributed numerous sites, confined electronic structures, synergistic interaction between active SrWO4 species g-C3N4 matrix. This work demonstrates an innovative protocol SrWO4/g-C3N4-based platforms nanoscale architectures interface configurations.

Language: Английский

Citations

30
A Review on Tetrabromobisphenol A: Human Biomonitoring, Toxicity, Detection and Treatment in the Environment DOI Creative Commons

Baoji Miao,

Salome Yakubu, Qingsong Zhu

et al.

Molecules, Journal Year: 2023, Volume and Issue: 28(6), P. 2505 - 2505

Published: March 9, 2023

Tetrabromobisphenol A (TBBPA) is a known endocrine disruptor employed in range of consumer products and has been predominantly found different environments through industrial processes human samples. In this review, we aimed to summarize published scientific evidence on biomonitoring, toxic effects mode action TBBPA humans. Interestingly, an overview various pretreatment methods, emerging detection treatment methods was elucidated. Studies exposure routes humans, combination adsorbent-based treatments degradation are the preliminary phase have several limitations. Therefore, in-depth studies these subjects should be considered enhance accurate body load non-invasive matrix, external levels, optimal design combined techniques, degrading technology TBBPA. Overall, review will improve comprehension humans as well environment, breakthrough for treating waste containing

Language: Английский

Citations

30
Nanoarchitecture Manipulation by Polycondensation on KCl Crystals toward Crystalline Lamellar Carbon Nitride for Efficient H2O2 Photoproduction DOI
Zhenchun Yang, Lina Li,

Shiqi Zeng

et al.

ACS Applied Materials & Interfaces, Journal Year: 2023, Volume and Issue: 15(6), P. 8232 - 8240

Published: Feb. 6, 2023

A lamellar carbon nitride (CN) framework is one of the most promising materials for solar-driven hydrogen peroxide production. The low dielectric constant organic CN leads to severe recombination excitons, and photon-to-chemical conversion efficiency thus unsatisfactory. In this work, by polycondensation small molecules on KCl crystal surface, K+-incorporated crystalline (CNK) frameworks show significantly extended periodicity stacking layers in-plane orderly organized heptazine/triazine units. CNK exhibit a series favorable photophysical properties, such as enhanced photon absorption, negatively shifted LUMO potentials, attenuated emissive decay excitons. present remarkable performance in photocatalytic selective oxygen reduction reaction production, e.g., from NH4SCN surface could produce at rate 26.7 mmol h-1 g-1 with high apparent quantum yield 25.0%, which 23.5 times that its counterpart synthesized absence KCl. This method generally applicable all precursors synthesis.

Language: Английский

Citations

27
Electrochemical aptasensor based on g-C3N4/rGO nanocomposite modified electrodes for antibiotics detection in raw milk DOI
Gajendar Singh,

Gourang Hari Gupta,

Arvind Verma

et al.

Talanta, Journal Year: 2025, Volume and Issue: 287, P. 127632 - 127632

Published: Feb. 3, 2025

Language: Английский

Citations

1
Triple synergy: Fabrication of novel Cl, C binary-doped g-C3N4 porous wrinkled nanosheets for promoted visible-light-instigated photocatalytic H2 production DOI
Soha M. Albukhari, Tamer M. Khedr, Reda M. Mohamed

et al.

Materials Science and Engineering B, Journal Year: 2025, Volume and Issue: 315, P. 118098 - 118098

Published: Feb. 11, 2025

Language: Английский

Citations

1
Functional graphitic carbon (IV) nitride: A versatile sensing material DOI
Ritu Malik, Nirav Joshi,

Vijay K. Tomer

et al.

Coordination Chemistry Reviews, Journal Year: 2022, Volume and Issue: 466, P. 214611 - 214611

Published: May 13, 2022

Language: Английский

Citations

31
Development of Two-Dimensional Functional Nanomaterials for Biosensor Applications: Opportunities, Challenges, and Future Prospects DOI Creative Commons

Shamsa Kizhepat,

Akash S. Rasal, Jia‐Yaw Chang

et al.

Nanomaterials, Journal Year: 2023, Volume and Issue: 13(9), P. 1520 - 1520

Published: April 29, 2023

New possibilities for the development of biosensors that are ready to be implemented in field have emerged thanks recent progress functional nanomaterials and careful engineering nanostructures. Two-dimensional (2D) exceptional physical, chemical, highly anisotropic, chemically active, mechanical capabilities due their ultra-thin structures. The diversity high surface area, layered topologies, porosity found 2D makes them amenable being engineered with characteristics make it possible targeted identification. By integrating distinctive features several varieties nanostructures employing as scaffolds bimolecular assemblies, biosensing platforms improved reliability, selectivity, sensitivity identification a plethora analytes can developed. In this review, we compile number approaches using biomolecule detection. Subsequently, summarize advantages disadvantages biosensing. Finally, both opportunities challenges exist within potentially fruitful subject discussed. This review will assist readers understanding synthesis nanomaterials, alteration by enzymes composite materials, implementation material-based efficient bioanalysis disease diagnosis.

Language: Английский

Citations

23
Nanomaterials-based aptasensors: An efficient detection tool for heavy-metal and metalloid ions in environmental and biological samples DOI
Abdelmonaim Azzouz, Lamia Hejji, Vanish Kumar

et al.

Environmental Research, Journal Year: 2023, Volume and Issue: 238, P. 117170 - 117170

Published: Sept. 16, 2023

Language: Английский

Citations

23
Carbon Nitride-Based Heterojunction Photoelectrodes with Modulable Charge-Transfer Pathways toward Selective Biosensing DOI
Wang Li, Mingming Zhang, Dan Han

et al.

Analytical Chemistry, Journal Year: 2023, Volume and Issue: 95(36), P. 13716 - 13724

Published: Aug. 31, 2023

Photoelectrochemical (PEC) sensing enables the rapid, accurate, and highly sensitive detection of biologically important chemicals. However, achieving high selectivity without external biological elements remains a challenge because PEC reactions inherently have poor selectivity. Herein, we report strategy to address this problem by regulating charge-transfer pathways using polymeric carbon nitride (pCN)-based heterojunction photoelectrodes. Interestingly, redox at different semiconductor/electrolyte interfaces with specific pathways, each analyte demonstrated unique combination photocurrent-change polarity. Based on principle, pCN-based sensor for selective ascorbic acid in serum against typical interferences, such as dopamine, glutathione, epinephrine, citric was successfully developed. This study sheds light general biorecognition units engineering heterojunctions

Language: Английский

Citations

21
Graphene and graphene-like carbon nanomaterials-based electrochemical biosensors for phytohormone detection DOI

Meiqing Yang,

Lu Wang,

Haozi Lu

et al.

Carbon letters, Journal Year: 2022, Volume and Issue: 33(5), P. 1343 - 1358

Published: Oct. 11, 2022

Language: Английский

Citations

27