Abstract.
Ocean
alkalinity
enhancement
(OAE)
is
a
promising
approach
to
marine
carbon
dioxide
removal
(mCDR)
that
leverages
the
large
surface
area
and
storage
capacity
of
oceans
sequester
atmospheric
CO2
as
dissolved
bicarbonate
(HCO3-).
The
SEAMATE
(Safe
Elevation
Alkalinity
for
Mitigation
Acidification
Through
Electrochemistry)
process
uses
electrochemistry
convert
some
salt
(NaCl)
in
seawater
or
brine
into
aqueous
acid
(HCl),
which
removed
from
system,
base
(NaOH),
returned
ocean
with
remaining
seawater.
resulting
increase
pH
causes
shift
inorganic
(DIC)
speciation
toward
carbonate
decrease
surface-ocean
pCO2.
pCO2
results
enhanced
CO2
uptake
reduced
loss
by
due
gas
exchange.
net
result
this
DIC,
where
it
durably
stored
as
mostly
carbonate.
In
study,
we
systematically
test
efficiency
treated
NaOH
at
beaker
(1
L),
aquaria
(15
tank
(6000
L)
scales
establish
operational
boundaries
safety
scaling
up
field
experiments.
Preliminary
show
equilibration
occurred
on
order
weeks
months,
depending
circulation,
air
forcing,
bubbling
conditions
within
tanks.
An
~0.7–0.9
mol
DIC/
added
(in
form
NaOH)
was
observed
through
analysis
bottle
samples
sensor
data,
consistent
value
expected
given
values
system
equilibrium
calculations
range
salinities
temperatures
tested.
Mineral
precipitation
when
bulk
exceeded
10.0
Ωaragonite
exceeded
30.0.
This
dominated
Mg(OH)2
over
hours
1
day
before
shifting
CaCO3,
aragonite
precipitation.
These
combined
models
dilution
advection
alkaline
plumes,
will
allow
estimation
amount
OAE
pilot
studies.
Future
experiments
should
better
approximate
including
sediment
interactions,
biological
activity,
air-sea
exchange
rates,
mixing-zone
dynamics.
State of the Planet,
Journal Year:
2023,
Volume and Issue:
2-oae2023, P. 1 - 29
Published: Nov. 27, 2023
Abstract.
Ocean
alkalinity
enhancement
(OAE)
is
an
emerging
strategy
that
aims
to
mitigate
climate
change
by
increasing
the
of
seawater.
This
approach
involves
ocean
enhance
its
capacity
absorb
and
store
carbon
dioxide
(CO2)
from
atmosphere.
chapter
presents
overview
technical
aspects
associated
with
full
range
OAE
methods
being
pursued
discusses
implications
for
undertaking
research
on
these
approaches.
Various
have
been
developed
implement
OAE,
including
direct
injection
alkaline
liquid
into
surface
ocean;
dispersal
particles
ships,
platforms,
or
pipes;
addition
minerals
coastal
environments;
electrochemical
removal
acid
Each
method
has
advantages
challenges,
such
as
scalability,
cost
effectiveness,
potential
environmental
impacts.
The
choice
technique
may
depend
factors
regional
oceanographic
conditions,
source
availability,
engineering
feasibility.
considers
methods,
accelerated
weathering
limestone,
liming,
creation
hydrated
carbonates,
environments.
In
each
case,
technologies
are
considered,
best-practice
drawn.
social
impacts
will
likely
specific
technology
local
context
in
which
it
deployed.
Therefore,
essential
feasibility
undertaken
parallel
with,
informed
by,
wider
impact
assessments.
While
shows
promise
a
mitigation
strategy,
acknowledge
limitations
uncertainties.
Further
development
needed
understand
long-term
effects,
optimize
techniques,
address
unintended
consequences.
should
be
viewed
complementary
extensive
emission
reductions,
improved
if
operated
using
energy
supply
chains
minimal
CO2
emissions.
Frontiers in Climate,
Journal Year:
2025,
Volume and Issue:
6
Published: Jan. 7, 2025
The
Paris
Agreement
to
limit
global
warming
well
below
2°C
requires
drastic
reductions
in
greenhouse
gas
emissions
and
the
balancing
of
any
remaining
by
carbon
dioxide
removal
(CDR).
Due
uncertainties
about
potential
durability
many
land-based
approaches
deliver
sufficient
CDR,
marine
CDR
options
are
receiving
more
interest.
We
present
current
state
knowledge
regarding
potentials,
risks,
side
effects
as
challenges
associated
with
technical
feasibility,
governance,
monitoring,
reporting
accounting
covering
a
range
biotic
geochemical
approaches.
specifically
discuss
what
extent
comparison
direct
injection
CO
2
into
seawater,
which
had
been
proposed
decades
ago
is
now
prohibited
international
agreements,
may
provide
guidance
for
evaluating
some
Proceedings of the National Academy of Sciences,
Journal Year:
2024,
Volume and Issue:
121(29)
Published: July 8, 2024
CO
2
mineralization
products
are
often
heralded
as
having
outstanding
potentials
to
reduce
-eq.
emissions.
However,
these
claims
generally
undermined
by
incomplete
consideration
of
the
life
cycle
climate
change
impacts,
material
properties,
supply
and
demand
constraints,
economic
viability
products.
We
investigate
factors
in
detail
for
ten
concrete-related
quantify
their
individual
global
emissions
reduction
potentials.
Our
results
show
that
2020,
3.9
Gt
carbonatable
solid
materials
were
generated
globally,
with
dominant
being
end-of-life
cement
paste
concrete
mortar
(1.4
y
–1
).
All
technologies
investigated
here
when
used
substitute
comparable
conventional
In
potential
economically
competitive
was
0.39
-eq.,
i.e.,
15%
from
production.
This
level
is
limited
paste.
The
also
it
5
times
cheaper
producing
carbonated
than
carbon
capture
storage
(CCS),
demonstrating
its
superior
decarbonization
potential.
On
other
hand,
currently
much
more
expensive
using
some
technologies,
like
normal
weight
aggregate
production,
CCS.
Technologies
policies
increase
recovery
aged
infrastructure
key
unlocking
reducing
footprint
materials.
Frontiers in Climate,
Journal Year:
2025,
Volume and Issue:
7
Published: Feb. 12, 2025
Carbon
Dioxide
Removal
(CDR)
from
the
atmosphere
is
unavoidable
if
we
are
to
meet
Paris
Agreement’s
goal
of
limiting
global
warming
1.5°C,
and
almost
certainly
required
limit
2°C.
The
ocean
exchanges
carbon
dioxide
(CO
2
)
with
a
large
repository
that
could
either
be
partially
emptied
allow
more
CO
absorption
or
have
its
storage
capacity
enhanced
it
remove
additional
atmosphere.
Early-stage
techniques
exist
utilise
in
atmospheric
removal,
but
typically,
removal
these
stimulate
happens
downstream
their
activity.
Verifying
associated
techniques,
while
critical
when
evaluating
approaches
pricing
challenging.
This
study
briefly
reviews
challenges
verifying
non-biological
(abiotic)
engineered
marine
CDR
approaches,
specifically
Ocean
Alkalinity
Enhancement
Direct
Capture
Storage,
presents
findings
workshop
held
interested
parties
spanning
industry
government,
focused
on
collective
requirements
for
Monitoring,
Reporting,
Verification
(MRV)
removal.
We
find
possible
agree
common
set
principles
abiotic
MRV,
identify
delivering
this
MRV
today’s
understanding
technology
prohibitively
expensive.
discuss
focal
areas
drive
down
costs
highlight
importance
specification
criteria
by
an
ultimate
regulator
investment
into
work.
High-quality
important
correctly
price
any
accessibility
transparency
also
key
realising
broader
benefits
society.
ACS Applied Energy Materials,
Journal Year:
2023,
Volume and Issue:
6(14), P. 7636 - 7642
Published: July 4, 2023
The
electrochemical
splitting
of
abundant
seawater
using
renewable
electricity
to
generate
green
hydrogen
holds
a
great
promise
for
energy
transport
and
storage.
However,
direct
electrolysis
suffers
from
side
reactions
degradation
electrodes
due
impurities.
Here,
we
demonstrate
device
that
uses
only
air.
was
desalinated
first
by
oxygen
reduction,
which
created
an
alkaline
environment
concurrently
captured
CO2
remove
Ca
Mg
ions.
Simultaneously,
artificial
reefs
could
be
formed.
softened
immediately
utilized
produce
hydrogen.
This
proof
concept
shows
coupled
with
value-added
processes,
allowing
the
utilization
without
pretreatment
or
purification
circumventing
challenges
posed
impurities
cost.
With
simultaneous
production
H2
reefs,
elimination,
powered
solely
electricity,
this
strategy
provides
approach
sustainable
production.
Elementa Science of the Anthropocene,
Journal Year:
2024,
Volume and Issue:
12(1)
Published: Jan. 1, 2024
Achieving
net
zero
CO2
emissions
requires
gigatonne-scale
atmospheric
removal
(CDR)
to
balance
residual
that
are
extremely
difficult
eliminate.
Marine
CDR
(mCDR)
methods
seen
increasingly
as
potentially
important
additions
a
global
portfolio
of
climate
policy
actions.
The
most
widely
considered
mCDR
coastal
blue
carbon
and
seaweed
farming
primarily
depend
on
biological
manipulations;
ocean
iron
fertilisation,
alkalinity
enhancement,
direct
capture
chemical
artificial
upwelling
depends
physical
manipulation
the
system.
It
is
currently
highly
uncertain
which,
if
any,
these
approaches
might
be
implemented
at
sufficient
scale
make
meaningful
contribution
zero.
Here,
we
derive
framework
based
additionality,
predictability,
governability
assess
implementation
challenges
for
methods.
We
argue
increase
sequestration
due
relative
baseline
state,
will
harder
determine
those
with
relatively
large
inherent
complexity,
therefore
higher
potential
unpredictable
impacts,
both
climatic
non-climatic.
Predictability
inherently
lower
biology
than
relying
or
manipulations.
Furthermore,
predictability
require
multiple
components
an
method
also
affects
its
governability,
complex
outcomes
greater
likelihood
unintended
consequences
more
monitoring
regulation,
risk
management
verified
accounting.
systematic
assessment
increases
their
chances
leading
benefit
informs
political
decision-making
around
implementation.
Frontiers in Climate,
Journal Year:
2024,
Volume and Issue:
6
Published: April 12, 2024
Research
over
the
past
decade
has
resulted
in
various
methods
for
removing
CO
2
from
atmosphere
using
seawater
and
electrochemically
generated
acids
bases.
This
Perspective
aims
to
present
a
unified
framework
comparing
these
approaches.
Specifically,
can
all
be
seen
as
falling
into
one
of
two
categories:
those
that
result
net
increase
ocean
alkalinity
use
“ocean
sponge”
atmospheric
(ocean
enhancement,
or
OAE)
cycle
pump”
cycling,
OAC).
In
this
Perspective,
approaches
marine
carbon
dioxide
removal
(mCDR)
electrochemistry
are
compared
framework,
similarities
differences
categories
explored.