Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130610 - 130610
Published: Nov. 1, 2024
Language: Английский
Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130610 - 130610
Published: Nov. 1, 2024
Language: Английский
Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125207 - 125207
Published: Feb. 1, 2025
Language: Английский
Citations
1Water Research, Journal Year: 2025, Volume and Issue: 275, P. 123205 - 123205
Published: Jan. 28, 2025
Language: Английский
Citations
0Advanced Science, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 24, 2025
Green and eco-friendly iron-based materials for efficient Cr(VI) removal have attracted considerable interest, but challenges related to narrow working pH ranges iron utilization efficiency still remain. Herein, inspired by the hot-spot effect-triggered confined coordination strategy, a biomass-confined reductant (CMC-GTB/Febm) is designed reduction detoxification. Electron enrichment confinement on biomass carriers are achieved through electron transfer mediated interactions between anchored species biomass. Thus, CMC-GTB/Febm 99% at circumneutral (5-9), with maximum capacity of 180 mg g-1. Under dosing close stoichiometric ratio (Fe/Cr = 3/1), kinetics 53.2-870.5 5.5-48.8 times higher than those micro- or nano-zero-valent (ZVI), respectively. Mechanistic analyses revealed that facilitated species, which enhanced reduction. Moreover, biomass-tethered reduced Cr(III) stabilized electrostatic adsorption biomass-Cr(III) coordination, ultimately detoxifies phytotoxicity Cr(VI). The conversion this strategy kilogram-scale production simulated in real water matrices confirmed. This study provides basis controlled design industrial application environmentally friendly reductants.
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2024, Volume and Issue: unknown, P. 130610 - 130610
Published: Nov. 1, 2024
Language: Английский
Citations
0