Green Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Transforming
furfural
waste
into
biofuels
and
biochar
with
outstanding
PFOA
adsorption
capacity,
offering
sustainable
solutions
for
environmental
remediation.
Chemosphere,
Journal Year:
2024,
Volume and Issue:
357, P. 142088 - 142088
Published: April 20, 2024
Per-
and
poly-fluoroalkyl
substances
(PFAS)
are
synthetic
chemicals
widely
used
in
everyday
products,
causing
elevated
concentrations
drinking
water
posing
a
global
challenge.
While
adsorption
methods
commonly
employed
for
PFAS
removal,
the
substantial
cost
environmental
footprint
of
commercial
adsorbents
highlight
need
more
cost-effective
alternatives.
Additionally,
existing
exhibit
limited
effectiveness,
particularly
against
diverse
types,
such
as
short-chain
PFAS,
necessitating
modifications
to
enhance
capacity.
Biochar
can
be
considered
eco-friendly
alternative
conventional
adsorbents.
With
abundant
feedstocks
favorable
physicochemical
properties,
biochar
shows
significant
potential
applied
an
adsorbent
removing
contaminants
from
water.
Despite
its
effectiveness
adsorbing
different
inorganic
organic
environments,
some
factors
restrict
effective
application
adsorption.
These
related
characteristics
well
chemistry.
Therefore,
have
been
introduced
overcome
these
limitations
improve
biochar's
This
review
explores
preparation
conditions,
including
pyrolysis
process,
activation,
modification
techniques
capacity
types
PFAS.
It
addresses
critical
questions
about
performance
composites,
mechanisms
governing
adsorption,
challenges,
future
perspectives
this
field.
The
surge
research
on
indicates
growing
interest,
making
timely
valuable
resource
in-depth
exploration
remediation.
Biochar,
Journal Year:
2025,
Volume and Issue:
7(1)
Published: Jan. 17, 2025
Abstract
Per-
and
polyfluoroalkyl
substances
(PFASs),
commonly
known
as
‘‘forever
chemicals’’,
are
persistent
organic
pollutants
that
widely
distributed
in
the
environment.
Due
to
their
toxicity
resistance
degradation,
PFASs
classified
emerging
contaminants,
increasing
attention
is
being
paid
remediation.
Biochar,
an
environmentally
friendly
cost-effective
adsorbent,
shows
potential
for
remediating
contamination.
The
application
of
biochar
remediation
has
garnered
growing
interest.
Compared
other
adsorbents,
more
economical
raw
materials
its
preparation
readily
available.
However,
there
currently
no
comprehensive
review
summarizing
effects
on
environmental
behavior
PFASs.
This
aims
fill
gap
by
providing
in-depth
discussion
synthesis
existing
literature
this
area.
It
focuses
PFASs,
specifically
addressing
adsorption
mechanisms
factors
influencing
effectiveness
A
proposed
mechanism
which
photodegrades
through
generation
free
radicals,
addition
conventional
(such
pore
filling,
hydrogen
bonding,
hydrophobic
interactions,
electrostatic
interactions),
explored.
Furthermore,
discusses
ability
reduce
likelihood
entering
food
chain
water
soil
evaluates
feasibility
limitations
using
removal.
Finally,
we
identify
future
research
directions
support
safe
effective
use
remediation,
so
promote
advancement
green
technologies.
Graphic
Sustainability,
Journal Year:
2023,
Volume and Issue:
15(23), P. 16173 - 16173
Published: Nov. 21, 2023
Per
and
polyfluoroalkyl
substances
(PFAS)
have
been
extensively
employed
in
a
broad
range
of
manufacturing
consumer
goods
due
to
their
highly
persistent
nature.
PFAS
exposure
is
recognized
pose
serious
health
hazards;
therefore,
addressing
pollution
water
has
become
top
priority
for
public
environmental
protection
organizations.
This
review
article
focuses
on
the
efficiency
different
removal
techniques
(activated
carbon,
biochar,
ion
exchange
resin,
membrane
filtration,
reverse
osmosis,
metal-organic
frameworks,
foam
fractionation,
ozone
destruction
techniques)
eliminating
types
short-
long-chain
from
water.
Hydrophobicity
electrostatic
interactions
are
revealed
be
primary
mechanisms
elimination
PFAS.
The
all
eradicate
short-chain
comparatively
lower
compared
most
efficient
but
some
drawbacks,
including
formation
precursors
high
operational
costs.
According
findings
study,
it
anticipated
that
combined
methods
will
required
effectively
remediate
PFAS-contaminated
As
regulatory
standards
for
per-
and
polyfluoroalkyl
substances
(PFAS)
become
increasingly
stringent,
innovative
water
treatment
technologies
are
urgently
demanded
effective
PFAS
removal.
Reported
sorbents
often
exhibit
limited
affinity
frequently
hindered
by
competitive
background
substances.
Recently,
fluorinated
(abbreviated
as
fluorosorbents)
have
emerged
a
potent
solution
leveraging
fluorine-fluorine
(F···F)
interactions
to
enhance
selectivity
efficiency
in
This
review
delves
into
the
designs
applications
of
fluorosorbents,
emphasizing
how
F···F
improve
binding
affinity.
Specifically,
existence
results
removal
efficiencies
orders
magnitude
higher
than
other
counterpart
sorbents,
particularly
under
conditions.
Furthermore,
we
provide
detailed
analysis
fundamental
principles
underlying
elucidate
their
synergistic
effects
with
sorption
forces,
which
contribute
enhanced
efficacy
selectivity.
Subsequently,
examine
various
fluorosorbents
synthesis
fluorination
techniques,
underscore
importance
accurately
characterizing
through
advanced
analytical
methods,
emphasize
significance
this
interaction
developing
selective
sorbents.
Finally,
discuss
challenges
opportunities
associated
employing
techniques
guide
design
advocate
further
research
development
sustainable
cost-effective
interactions.