The Innovation Materials,
Journal Year:
2024,
Volume and Issue:
2(1), P. 100060 - 100060
Published: Jan. 1, 2024
<p>Inorganic,
organic,
and
hybrid
two-dimensional
(2D)
materials
are
being
developed
for
ever-expanding
numbers
of
applications,
though
energy
catalysis
remain
the
main
drivers
their
development.
We
present
overviews
bottom-up
top-down
synthetic
strategies
such
examine
manufacturing
scalability
issues.
Mechanical,
electrical,
thermal
properties
modulation
highlighted
because
they
fundamental
to
above-mentioned
drivers.
The
burgeoning
importance
heterostructures
in
materials,
particularly
electrode
design
function
is
stressed.
Detailed
attention
given
applications
2D
electrocatalysis
reactions:
oxygen
reduction,
evolution,
hydrogen
carbon
dioxide
nitrogen
reduction.
Water
splitting,
reduction
by
photocatalysis
also
examined.
A
perspective
expected
advances
expansion
types
with
a
focus
on
heterostructure
development,
presented
conclusion.</p>
Chemical Society Reviews,
Journal Year:
2021,
Volume and Issue:
50(4), P. 2764 - 2793
Published: Jan. 1, 2021
Two-dimensional
conjugated
MOFs
are
emerging
for
multifunctional
electronic
devices
that
brings
us
“MOFtronics”,
such
as
(opto)electronics,
spintronics,
energy
devices.
Advanced Energy Materials,
Journal Year:
2021,
Volume and Issue:
12(4)
Published: March 19, 2021
Abstract
Metal‐organic
frameworks
(MOFs)
and
covalent‐organic
(COFs)
are
two
emerging
families
of
functional
materials
used
in
many
fields.
Advantages
both
include
compositional
designability,
structural
diversity,
high
porosity,
which
offer
immense
possibilities
the
search
for
high‐performance
electrode
metal‐ion
batteries.
A
large
number
MOF/COF‐based
cathode
have
been
reported.
Despite
these
advantageous
features
research
advances,
MOFs/COFs
their
derivatives
face
various
challenges
as
materials.
In
this
review,
an
overview
progress
cathodes
advanced
batteries
is
presented,
including
lithium‐ion
other
nascent
technologies,
such
sodium‐ion
batteries,
zinc‐ion
aluminum‐ion
magnesium‐ion
Research
advances
on
summarized
terms
active
sites,
design,
protective
coatings.
Perspectives
directions
future
development
outlined
meeting
requirements
practical
applications.
ACS Nano,
Journal Year:
2023,
Volume and Issue:
17(13), P. 12510 - 12518
Published: June 23, 2023
Metal-organic
frameworks
(MOFs)
manifest
enormous
potential
in
promoting
electromagnetic
wave
(EMW)
absorption
thanks
to
the
tailored
components,
topological
structure,
and
high
porosity.
Herein,
rodlike
conductive
MOFs
(cMOFs)
composed
of
adjustable
metal
ions
Zn,
Cu,
Co,
or
Ni
ligands
hexahydroxytriphenylene
(HHTP)
are
prepared
attain
tunable
dielectric
properties
for
a
EMW
absorption.
Specifically,
influences
cMOFs'
composition,
charge
transport
characteristic,
crystalline
anisotropy
microstructure
on
performance
ascertained,
advancing
understanding
attenuation
mechanisms
MOFs.
The
boosted
polarization
losses
derived
from
conjugation
effects
terminal
groups,
as
well
shape
anisotropy,
lead
prominent
cMOFs.
Cu-HHTP
confers
minimum
reflection
loss
(RLmin)
-63.55
dB
at
thickness
2.9
mm
maximum
effective
bandwidth
5.2
GHz.
Moreover,
Zn-HHTP
showcases
superiority
S-band
(2-4
GHz)
with
an
RLmin
-62.8
1.9
mm.
This
work
not
only
hoists
mechanistic
structure-function
relationships
cMOFs
but
also
offers
guidelines
preparing
functional
MOF
materials.
Advanced Science,
Journal Year:
2021,
Volume and Issue:
8(13)
Published: May 2, 2021
From
basic
research
to
industry
process,
battery
energy
storage
systems
have
played
a
great
role
in
the
informatization,
mobility,
and
intellectualization
of
modern
human
society.
Some
potential
such
as
Li,
Na,
K,
Mg,
Zn,
Al
secondary
batteries
attracted
much
attention
maintain
social
progress
sustainable
development.
As
one
components
batteries,
electrolytes
play
an
important
upgrade
breakthrough
technology.
Since
room-temperature
ionic
liquids
(ILs)
feature
high
conductivity,
nonflammability,
nonvolatility,
thermal
stability,
wide
electrochemical
window,
they
been
widely
applied
various
show
improving
kinetics
performance,
density,
service
life,
safety.
Thus,
it
is
right
time
summarize
these
progresses.
In
this
review,
composition
classification
ILs
their
recent
applications
diverse
metal-ion
(Li,
Al)
are
outlined
enhance
performances.
Small Structures,
Journal Year:
2022,
Volume and Issue:
4(6)
Published: Sept. 16, 2022
The
2D
nanosheets
of
metal–organic
frameworks
(MOFs)
have
recently
emerged
as
a
promising
material
that
makes
them
valuable
in
widespread
electrocatalytic
fields
due
to
their
atomic‐level
thickness,
abundant
active
sites,
and
large
surface
area.
Efficient
electrocatalysts
for
hydrogen
evolution
reaction
(HER),
oxygen
(OER),
overall
water
splitting
are
highly
desired
with
low
overpotentials
promote
the
industrial
applications
energy
conversion
devices.
MOF
nanostructures
provide
long‐term
stability
high
electrical
conductivity
enhance
catalyst
activity
durability.
This
review
briefly
summarizes
synthesis
HER/OER/water
splitting.
More
attention
is
focused
on
synthetic
strategies
derivatives.
catalytic
performance
superior
properties
these
materials
highlighted.
outperformance
originates
from
rational
design,
myriad
thickness.
current
future
challenges
this
field
scientific
perspectives
overcome
It
suggested
construction
can
develop
state‐of‐the‐art
electrocatalyst
environmental
division.
eScience,
Journal Year:
2023,
Volume and Issue:
3(2), P. 100092 - 100092
Published: Jan. 10, 2023
Micro/nano
metal–organic
frameworks
(MOFs)
have
attracted
significant
attention
in
recent
years
due
to
their
numerous
unique
properties,
with
many
synthetic
methods
and
strategies
being
reported
for
constructing
MOFs
specific
micro/nano
structures.
In
addition,
the
design
of
energy
storage
conversion
applications
study
structure–activity
relationship
also
become
research
hotspots.
Herein,
a
comprehensive
overview
progress
on
is
presented.
We
begin
brief
introduction
various
synthesis
controlling
morphology
MOFs.
Subsequently,
structure-dependent
properties
as
electrode
materials
or
catalysts
terms
batteries,
supercapacitors,
catalysis
are
discussed.
Finally,
remaining
challenges
future
perspectives
this
field
Overall,
review
expected
inspire
advanced
efficient
technologies.
Dalton Transactions,
Journal Year:
2021,
Volume and Issue:
50(33), P. 11331 - 11346
Published: Jan. 1, 2021
Recent
progress
on
2D
conductive
MOFs
and
layered
containing
pillar-layered
nanosheets
as
electrode
materials
in
SCs
is
reviewed,
including
synthetic
design
strategies,
electrochemical
performances,
working
mechanisms.
