Advanced Materials,
Journal Year:
2022,
Volume and Issue:
34(31)
Published: June 10, 2022
Designing
scalable
coatings
with
a
wide
spectrum
of
functions
such
as
liquid
repellency,
anticorrosion,
and
antiflaming
high
level
mechano-chemical-thermal
robustness
is
crucial
in
real-life
applications.
However,
these
individual
functionalities
are
coupled
together
or
even
have
conflicting
requirements
on
the
interfacial
bulky
properties
materials,
thus,
simultaneously
integrating
all
features
into
one
coating
has
proved
challenging.
Herein,
an
integral
skin-inspired
triple-layered
(STC)
that
resolves
demands
imposed
by
structural,
chemical,
mechanical,
thermal
materials
proposed.
Specifically,
rational
design
multiple
gradients
roughness,
wetting,
strength,
flame
retardancy
formation
continuous
interfaces
along
its
triple
layers
endow
sustained
under
harsh
environments,
well
strong
antiabrasion
surfaces
adhesion
substrate.
Such
all-in-one
enhances
durability
lifetime
reduces
maintenance
repair,
thereby
contributing
to
cost
energy
saving.
Together
facile
spraying
fabrication
process,
this
STC
provides
feasible
sustainable
strategy
for
constructing
resource-saving
materials.
Advanced Science,
Journal Year:
2023,
Volume and Issue:
10(9)
Published: Jan. 22, 2023
Abstract
Advanced
elastomers
are
increasingly
used
in
emerging
areas,
for
example,
flexible
electronics
and
devices,
these
real‐world
applications
often
require
to
be
stretchable,
tough
fire
safe.
However,
date
there
few
successes
achieving
such
a
performance
portfolio
due
their
different
governing
mechanisms.
Herein,
supertough,
self‐extinguishing
polyurethane
by
introducing
dynamic
π
–
stacking
motifs
phosphorus‐containing
moieties
reported.
The
resultant
elastomer
shows
large
break
strain
of
≈2260%
record‐high
toughness
(ca.
460
MJ
m
−3
),
which
arises
from
its
microphase‐separated
microstructure
resulting
increased
entropic
elasticity,
strain‐hardening
at
strains.
also
exhibits
ability
thanks
the
presence
both
units
interactions.
Its
promising
as
reliable
yet
recyclable
substrate
sensors
demonstrated.
work
will
help
expedite
next‐generation
sustainable
advanced
devices
applications.
SusMat,
Journal Year:
2022,
Volume and Issue:
2(4), P. 411 - 434
Published: June 20, 2022
Abstract
Polymeric
materials
are
ubiquitously
utilized
in
modern
society
and
continuously
improve
quality
of
life.
Unfortunately,
most
them
suffer
from
intrinsic
flammability,
significantly
limiting
their
practical
applications.
Fundamentally,
free‐radical
reaction
is
a
critical
“trigger”
for
thermal
pyrolysis
following
combustion
process
regardless
the
anaerobic
condensed
phase
or
aerobic
polymers
gaseous
phase.
The
addition
free
radical
scavengers
represents
promising
effective
means
to
enhance
fire
safety
polymeric
materials.
This
review
aims
offer
state‐of‐the‐art
overview
on
creation
fire‐retardant
nanocomposites
by
adding
retardants
with
an
ability
trap
radicals.
Their
specific
modes
action
(condensed‐phase
action,
gaseous‐phase
dual‐phases
action)
performances
some
typical
reviewed
discussed
detail.
Following
this,
key
challenges
associated
these
capturers
discussed,
design
strategies
also
proposed.
provides
insights
into
capturing
agents
paves
avenue
advanced
expanded
real‐world
applications
industries.
Advanced Materials,
Journal Year:
2022,
Volume and Issue:
34(31)
Published: June 10, 2022
Designing
scalable
coatings
with
a
wide
spectrum
of
functions
such
as
liquid
repellency,
anticorrosion,
and
antiflaming
high
level
mechano-chemical-thermal
robustness
is
crucial
in
real-life
applications.
However,
these
individual
functionalities
are
coupled
together
or
even
have
conflicting
requirements
on
the
interfacial
bulky
properties
materials,
thus,
simultaneously
integrating
all
features
into
one
coating
has
proved
challenging.
Herein,
an
integral
skin-inspired
triple-layered
(STC)
that
resolves
demands
imposed
by
structural,
chemical,
mechanical,
thermal
materials
proposed.
Specifically,
rational
design
multiple
gradients
roughness,
wetting,
strength,
flame
retardancy
formation
continuous
interfaces
along
its
triple
layers
endow
sustained
under
harsh
environments,
well
strong
antiabrasion
surfaces
adhesion
substrate.
Such
all-in-one
enhances
durability
lifetime
reduces
maintenance
repair,
thereby
contributing
to
cost
energy
saving.
Together
facile
spraying
fabrication
process,
this
STC
provides
feasible
sustainable
strategy
for
constructing
resource-saving
materials.