Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 148802 - 148802
Published: Jan. 19, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 148802 - 148802
Published: Jan. 19, 2024
Language: Английский
Desalination, Journal Year: 2024, Volume and Issue: 574, P. 117278 - 117278
Published: Jan. 2, 2024
Language: Английский
Citations
31Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 484, P. 149666 - 149666
Published: Feb. 15, 2024
Language: Английский
Citations
26Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 487, P. 150437 - 150437
Published: March 16, 2024
Language: Английский
Citations
26Advanced Science, Journal Year: 2024, Volume and Issue: 11(28)
Published: May 2, 2024
Abstract Silver (Ag) is deemed a promising anode material for capacitive deionization (CDI) due to its high theoretical capacity and efficient selectivity Cl − . However, the strong volume change during conversion reaction significantly undermines cycling performance of Ag electrode. Additionally, achieving well‐dispersed in active matrix challenging, as electrodes prepared by conventional thermal reduction tend agglomerate. Herein, organic linker confinement strategy proposed, applying metal–organic framework (MOF) chemistry between nodes ligands construct Ag‐based MOF. The uniform dispersion at molecular level, confined matrix, efficiently enhances utilization sites, strengthens interfacial stability Ag. Consequently, Ag‐MOF CDI exhibits an excellent removal 121.52 mg g −1 20 mA 500 L NaCl solution, rate 60.54%. After 100 cycles, retention 96.93% achieved. Furthermore, capture mechanism elucidated through density functional theory (DFT) calculations, ex situ XRD, Raman XPS. This ingenious electrode design can offer valuable insights development high‐performance applications.
Language: Английский
Citations
26Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 148802 - 148802
Published: Jan. 19, 2024
Language: Английский
Citations
22