Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)
Published: Sept. 6, 2024
Language: Английский
Small Structures, Journal Year: 2022, Volume and Issue: 3(10)
Published: July 16, 2022
MXene nanomaterials stand out among 2D and have been extensively studied by researchers because of their unique layered structure, chemical diversity, outstanding physical properties. In recent years, materials rapidly opened the market for electromagnetic interference shielding technology due to excellent wave absorption (EMA) capability. However, so far, compared with development (EM) technology, there is still much room in construction MXenes application absorption. Herein, strategies, conversion mechanism, applications are reviewed. Through meticulous material design an interdisciplinary approach, expected become one smart tunable absorbers, scenarios will also broader.
Language: Английский
Citations
219
Symmetry, Journal Year: 2022, Volume and Issue: 14(11), P. 2232 - 2232
Published: Oct. 24, 2022
MXene, 2D transition metal carbides, nitrides, and carbonitrides with a unique structure, inspired series of function applications related to energy storage conversion, biometrics sensing, lighting, purification, separation. Its surface terminations are confined by the adjacent MXene layers, form planar space symmetrical surfaces, which is similar nanoreactor that can be utilized determined MXene’s function. Based on working principle, interface play critical roles in ion intercalation, physical/chemical adsorption, chemical reaction process, show significant effects properties functions. Although there have been some reviews less attention has paid underlying principle involved chemistry, controllable design, resultant properties. Herein, regulation methods, characterization techniques, were summarized understand effects, relationship between We expected this review offer route for ongoing studies address environment guidelines application.
Language: Английский
Citations
106
Advanced Materials, Journal Year: 2023, Volume and Issue: 36(14)
Published: Dec. 26, 2023
Abstract Transition metal carbides/nitrides (MXenes) demonstrate a massive potential in constructing lightweight, multifunctional wearable electromagnetic interference (EMI) shields for application various fields. Nevertheless, it remains challenging to develop facile, scalable approach prepare the MXene‐based macrostructures characterized by low density, thickness, high mechanical flexibility, and EMI SE at same time. Herein, ultrathin MXene/reduced graphene oxide (rGO)/Ag foams with porifera‐inspired hierarchically porous microstructure are prepared combining Zn 2+ diffusion induction hard template methods. The hierarchical porosity, which includes mesoporous skeleton microporous MXene network within skeleton, not only exerts regulatory effect on stress distribution during compression, making rubber‐like resistant wrinkling but also provides more channels multiple reflections of waves. Due interaction between Ag nanosheets, MXene/rGO, structure, is possible produce an outstanding shielding performance specific surface effectiveness reaching 109152.4 dB cm 2 g −1 . Furthermore, exhibit multifunctionalities, such as transverse Joule heating, longitudinal heat insulation, self‐cleaning, fire resistance, motion detection. These discoveries open up novel pathway development lightweight materials considerable anti‐interference devices.
Language: Английский
Citations
101
Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 474, P. 145904 - 145904
Published: Sept. 6, 2023
Language: Английский
Citations
99
Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)
Published: Sept. 2, 2023
Abstract Constructing flexible and robust thermally conductive but electrically insulating composite films for efficient safe thermal management has always been a sought-after research topic. Herein, nacre-inspired high-performance poly(p-phenylene-2,6-benzobisoxazole) (PBO)/MXene nanocomposite film was prepared by sol-gel-film conversion method with homogeneous gelation process. Because of the as-formed optimized brick mortar structure, strong bridging caging effects fine PBO nanofibre network on MXene nanosheets, resulting is (2.5 × 10 9 Ω cm), exhibits excellent mechanical properties (tensile strength 416.7 MPa, Young’s modulus 9.1 GPa toughness 97.3 MJ m −3 ). More importantly, synergistic orientation nanofibres nanosheets endows an in-plane conductivity 42.2 W −1 K . The also stability flame retardancy. This work broadens ideas preparing composites.
Language: Английский
Citations
90
Nano Research, Journal Year: 2022, Volume and Issue: 15(10), P. 9520 - 9530
Published: Aug. 5, 2022
Language: Английский
Citations
88
ACS Nano, Journal Year: 2023, Volume and Issue: 17(13), P. 12616 - 12628
Published: June 29, 2023
Gallium-based liquid metal (LM) with intriguing high electrical conductivity and room-temperature fluidity has attracted substantial attention for its potential application in flexible electromagnetic interference (EMI) shielding. However, the EMI shielding performance of existing LM-based composites is unsatisfying due to irreconcilable contradiction between efficiency (SE) low thickness. In addition, research on environmentally stable material become an urgent need increasingly sophisticated scenarios. Herein, we prepared a reduced graphene oxide (rGO) bridging LM layered heterostructure nanocomposite liquid-infused slippery surface (S-rGO/LM), which exhibits ultrahigh X-band SE 80 dB at mere internal thickness 33 μm, extremely value 100 67 μm. More significantly, protected by ultrathin (2 μm) yet effective surface, S-rGO/LM film exceptional stability (EMI stays above 70 dB) after enduring various harsh conditions (harsh chemical environments, extreme operating temperatures, severe mechanical wearing). Moreover, also demonstrates satisfying photothermal behavior excellent Joule heating (surface temperature 179 °C 1.75 V, thermal response <10 s), endows it capability anti-icing/de-icing. This work proposes way construct reliable high-performance capability, shows great applications wearable devices, defense, aeronautics astronautics.
Language: Английский
Citations
84
Chemical Engineering Journal, Journal Year: 2022, Volume and Issue: 453, P. 139823 - 139823
Published: Oct. 17, 2022
Language: Английский
Citations
80
ACS Applied Materials & Interfaces, Journal Year: 2022, Volume and Issue: 14(31), P. 36060 - 36070
Published: Aug. 1, 2022
Delicately aligned structures of two-dimensional (2D) MXene nanosheets have demonstrated positive effects on applications, especially in electromagnetic interference (EMI) shielding and infrared (IR) stealth. However, precise regulation structural assembly by theory-guided solution processing is still a great challenge. Herein, one-dimensional (1D) cellulose nanofibers (CNFs) with high aspect ratio are applied as reinforcing agent rheological modifier for MXene/CNF colloids to fabricate MXene-based materials EMI IR Notably, systematical study the proposed determine optimal solution-processing conditions finely oriented component arrangement requirements provides in-depth information interactions between components. The delicately regulated orientation structure assembled shear inducement convincingly through micro-CT wide-angle X-ray diffraction/small-angle scattering (WAXD/SAXS), which endows film significantly enhanced electrical conductivity 46 685 S m-1, tensile strength 281.7 MPa, Young's modulus 14.8 GPa. Furthermore, highly ultrathin possesses enhancement effectiveness (50.2 dB) stealth (0.562 emissivity). These findings provide fruitful understanding optimized fabrication high-performance functional composite films open up opportunity development multifunctional materials.
Language: Английский
Citations
79
Journal of Material Science and Technology, Journal Year: 2024, Volume and Issue: 186, P. 256 - 271
Published: Jan. 25, 2024
Language: Английский
Citations
79