Carbon-based single-atom catalysts derived from biomass: Fabrication and application DOI
Junkai Li, Guanhua Wang,

Wenjie Sui

et al.

Advances in Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 329, P. 103176 - 103176

Published: May 6, 2024

Language: Английский

Low-Pt anodes with gradient molybdenum isomorphism for high performance and anti-CO poisoning PEMFCs DOI
Changqing Jin,

Yucong Liao,

Aojie Zhang

et al.

Nano Energy, Journal Year: 2024, Volume and Issue: 122, P. 109305 - 109305

Published: Jan. 17, 2024

Language: Английский

Citations

15

Engineering a High-Loading Sub-4 nm Intermetallic Platinum–Cobalt Alloy on Atomically Dispersed Cobalt–Nitrogen–Carbon for Efficient Oxygen Reduction in Fuel Cells DOI
Pei Xiong,

Huiting Niu,

Zhaozhao Zhu

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(13), P. 3961 - 3970

Published: March 25, 2024

Developing a high-performance membrane electrode assembly (MEA) poses formidable challenge for fuel cells, which lies in achieving both high metal loading and efficient catalytic activity concurrently MEA catalysts. Here, we introduce porous Co@NC carrier to synthesize sub-4 nm PtCo intermetallic nanocrystals, an impressive Pt of 27 wt %. The PtCo–CoNC catalyst demonstrates exceptional remarkable stability the oxygen reduction reaction. Advanced characterization techniques theoretical calculations emphasize synergistic effect between alloys single Co atoms, enhances desorption OH* intermediate. Furthermore, PtCo–CoNC-based cathode delivers power density 1.22 W cm–2 test owing enhanced mass transport, is verified by simulation results O2 distributions current inside layer. This study lays groundwork design catalysts with practical applications cells.

Language: Английский

Citations

15

Ligand carbonization in-situ derived ultrathin carbon shells enable high-temperature confinement synthesis of PtCo alloy catalysts for high-efficiency fuel cells DOI

Kechuang Wan,

Jue Wang, Jingjing Zhang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 149060 - 149060

Published: Jan. 26, 2024

Language: Английский

Citations

11

Ultradurable Pt-Based Catalysts for Oxygen Reduction Electrocatalysis DOI Open Access
Ziting Li, Peng Zhou, Yuxin Zhao

et al.

Catalysts, Journal Year: 2024, Volume and Issue: 14(1), P. 57 - 57

Published: Jan. 12, 2024

An oxygen reduction reaction (ORR) is the key half of proton exchange membrane fuel cells (PEMFCs), and highly dependent on Pt-based nanocrystals as core electrocatalysts. Despite exceptional ORR activity from adjusting electronic structures surface or near-surface atoms, several serious issues, including corrosion carbon supports, preferential leaching active metal elements, instability low-coordinated atoms sintering/agglomeration nanocrystals, still exist, challenging durability developed catalysts. From point view catalyst structure design, in this review, we summarized state-of-the-art structural regulation strategies for improving The current limitation binary catalysts electrocatalysis firstly discussed, detailed are further classified into optimization metal-doped alloys, core/shell structures, intermetallics high-entropy etc. structure–performance relationship detailedly explained, especially emphasizing elimination above restrictions. Finally, existing challenges future research direction presented, aiming at practicing PEMFC devices ultradurable

Language: Английский

Citations

10

Carbon-based single-atom catalysts derived from biomass: Fabrication and application DOI
Junkai Li, Guanhua Wang,

Wenjie Sui

et al.

Advances in Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 329, P. 103176 - 103176

Published: May 6, 2024

Language: Английский

Citations

10