Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 24, 2025
Abstract
Recently,
the
enzyme‐inspired
nanoconfinement
effect
has
garnered
significant
attention
for
enhancing
efficiency
of
electrocatalysts
and
photocatalysts.
Despite
substantial
progress
in
these
fields,
there
remains
a
notable
absence
comprehensive
insightful
articles
providing
clear
understanding
nanoconfined
catalysts.
This
review
addresses
this
gap
by
delving
into
catalysts
electrocatalytic
photocatalytic
energy
conversion.
Initially,
on
thermodynamics
kinetics
reactions
is
explored.
Subsequently,
primary
secondary
structures
are
categorized,
their
properties
outlined,
typical
methods
construction
summarized.
Furthermore,
an
overview
state‐of‐the‐art
applications
provided,
focusing
hydrogen
oxygen
evolution,
reduction,
carbon
dioxide
peroxide
production,
nitrogen
reduction.
Finally,
current
challenges
future
prospects
discussed.
aims
to
provide
in‐depth
insights
guidelines
advance
development
conversion
technology
The Journal of Physical Chemistry Letters,
Journal Year:
2025,
Volume and Issue:
16(6), P. 1424 - 1431
Published: Jan. 31, 2025
Dual-metal
site
catalysts
(DMSCs)
supported
on
nitrogen-doped
graphene
have
shown
great
potential
in
heterogeneous
catalysis
due
to
their
unique
properties
and
enhanced
efficiency.
However,
the
precise
control
stabilization
of
metal
dimers,
particularly
oxygen
activation
reactions,
present
significant
challenges
practical
applications.
In
this
study,
we
integrate
high-throughput
density
functional
theory
calculations
with
machine
learning
techniques
predict
optimize
catalytic
DMSCs.
Transfer
is
employed
enhance
model's
generalization
capability,
successfully
predicting
performance
across
new
combinations.
Additionally,
application
SISSO
method
enables
derivation
interpretable
symbolic
regression
models,
revealing
critical
correlations
between
electronic
structure
features
This
approach
not
only
advances
understanding
dual-metal
but
also
provides
a
novel
framework
for
systematic
design
optimization
highly
efficient
catalysts,
broad
applicability
science.
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 24, 2025
Abstract
Recently,
the
enzyme‐inspired
nanoconfinement
effect
has
garnered
significant
attention
for
enhancing
efficiency
of
electrocatalysts
and
photocatalysts.
Despite
substantial
progress
in
these
fields,
there
remains
a
notable
absence
comprehensive
insightful
articles
providing
clear
understanding
nanoconfined
catalysts.
This
review
addresses
this
gap
by
delving
into
catalysts
electrocatalytic
photocatalytic
energy
conversion.
Initially,
on
thermodynamics
kinetics
reactions
is
explored.
Subsequently,
primary
secondary
structures
are
categorized,
their
properties
outlined,
typical
methods
construction
summarized.
Furthermore,
an
overview
state‐of‐the‐art
applications
provided,
focusing
hydrogen
oxygen
evolution,
reduction,
carbon
dioxide
peroxide
production,
nitrogen
reduction.
Finally,
current
challenges
future
prospects
discussed.
aims
to
provide
in‐depth
insights
guidelines
advance
development
conversion
technology
