Efficient asymmetric diffusion channel in MnCo 2 O 4 spinel for ammonium-ion batteries DOI Creative Commons
Kang Xiao,

Bo‐Hao Xiao,

Jianxi Li

et al.

Proceedings of the National Academy of Sciences, Journal Year: 2024, Volume and Issue: 121(37)

Published: Sept. 6, 2024

Transition metal oxides ion diffusion channels have been developed for ammonium-ion batteries (AIBs). However, the influence of microstructural features on storage and behavior NH 4 + is not fully unveiled. In this study, by using MnCo 2 O spinel as a model electrode, asymmetric regulated through bond length optimization strategy investigate effect channel size process . addition, reducing significantly decreases adsorption energy, thereby accelerating hydrogen formation/fracture kinetics reversible within 3D channels. The optimized with oxygen vacancies/carbon nanotubes composite exhibits impressive specific capacity (219.2 mAh g –1 at 0.1 A ) long-cycle stability. full cell 3,4,9,10-perylenetetracarboxylic diimide anode demonstrates remarkable energy density 52.3 Wh kg maintains 91.9% after 500 cycles. This finding provides unique approach development cathode materials in AIBs.

Language: Английский

A comprehensive review on photo-thermal co-catalytic reduction of CO2 to value-added chemicals DOI
Zhourong Xiao, Peng Li, Hui Zhang

et al.

Fuel, Journal Year: 2024, Volume and Issue: 362, P. 130906 - 130906

Published: Jan. 9, 2024

Language: Английский

Citations

60
Fabrication of 1D/2D In2O3 nanofibers/Ti3C2TX MXene composites for high performance detection of trimethylamine at low temperature DOI

Qingqing Xie,

Yongling Ding,

Qi Wang

et al.

Sensors and Actuators B Chemical, Journal Year: 2024, Volume and Issue: 405, P. 135338 - 135338

Published: Jan. 16, 2024

Language: Английский

Citations

48
Pt-decorated spinel MnCo2O4 nanosheets enable ampere-level hydrazine assisted water electrolysis DOI
Xuhui Ren, Cong Lin, Guorong Zhou

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 676, P. 13 - 21

Published: July 14, 2024

Language: Английский

Citations

35
Ruthenium–Cobalt Solid-Solution Alloy Nanoparticles for Enhanced Photopromoted Thermocatalytic CO2 Hydrogenation to Methane DOI
Yunxiang Tang, Hao Wang,

Chan Guo

et al.

ACS Nano, Journal Year: 2024, Volume and Issue: 18(17), P. 11449 - 11461

Published: April 22, 2024

Bimetallic alloy nanoparticles have garnered substantial attention for diverse catalytic applications owing to their abundant active sites and tunable electronic structures, whereas the synthesis of ultrafine with atomic-level homogeneity bulk-state immiscible couples remains a formidable challenge. Herein, we present RuxCo1–x solid-solution (ca. 2 nm) across entire composition range, highly efficient, durable, selective CO2 hydrogenation CH4 under mild conditions. Notably, Ru0.88Co0.12/TiO2 Ru0.74Co0.26/TiO2 catalysts, 12 26 atom % Ru being substituted by Co, exhibit enhanced activity compared monometallic Ru/TiO2 counterparts both in dark light irradiation. The comprehensive experimental investigations density functional theory calculations unveil that state is subtly modulated intimate interaction between Co nanoparticles, this effect results decline conversion energy barrier, thus ultimately culminating an elevated performance relative catalysts. In photopromoted thermocatalytic process, photoinduced charge carriers localized photothermal play pivotal role facilitating chemical reaction which accounts further boosted methanation performance.

Language: Английский

Citations

26
Synthesis of 1D LaFeO3 nanofibers/2D MXene heterostructures for formaldehyde detection at low temperature DOI

Buting Sun,

Miao Liu, Lu Liu

et al.

Sensors and Actuators B Chemical, Journal Year: 2024, Volume and Issue: 415, P. 136011 - 136011

Published: May 21, 2024

Language: Английский

Citations

19
Asymmetric Interaction between Carbon and Ni-Cluster in Ni–C–In Photothermal Catalysts for Point-Concentrated Solar-Driven CO2 Reverse Water–Gas Shift Reaction DOI
Shengpeng Mo, Shuangde Li,

Jiangjing Zhou

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 2796 - 2808

Published: Jan. 31, 2025

Language: Английский

Citations

3
Bimetallic-MOF Tunable Conductive Hydrogels to Unleash High Stretchability and Sensitivity for Highly Responsive Flexible Sensors and Artificial Skin Applications DOI
Mansoor Khan, Luqman Ali Shah,

Hifsa Hifsa

et al.

ACS Applied Polymer Materials, Journal Year: 2024, Volume and Issue: 6(12), P. 7288 - 7300

Published: June 6, 2024

Metal–organic frameworks (MOFs) are widely applied in various fields, including energy storage, drug delivery, wastewater treatment, and much more. However, their use hydrogels is limited due to low dispersion which causes agglomeration the hydrogel network many properties of sacrifices. Similarly, conductive have emerged as a promising material for skin-like sensors excellent biocompatibility mechanical flexibility. like MOFs, also face challenges such stretchability, toughness, susceptibility fatigue, resulting sensing range large response time-reduced durability sensors. In this study, highly stretchable, tough, antifatigue composite poly(dodecyl methacrylate-acrylamide-2-(acryloyloxy)ethyl trimethylammonium chloride) bimetallic metal–organic framework [p(DA-AM-AETAC)BM-MOF] was developed by integrating BM-MOFs into it. To achieve uniform within network, positively charged surfactant, ethyl hexadecyl dimethylammonium bromide, used. It facilitates formation hydrophobic interactions between matrix surface BM-MOFs. Furthermore, it can interact with surfactant polymer chains through physical interactions, significantly enhancing hydrogel. The BM-MOF-based exhibited impressive stretchability (1588%) toughness (537 kJ m–3), along exceptional properties. Moreover, demonstrated high conductivity 1.3 S/m tensile strain sensitivity ranging from 0.5 700% gauge factor 14.8 at response–recovery 195–145 ms. p(DA-AM-AETAC)BM-MOF displayed sensitive, reliable, repetitive detection wide human activities, wrist elbow rotation, finger bending, swallowing motion, speaking, well handwriting drawing. monitor pressure mimic skin. This highlights potential wearable strain, pressure, artificial skin flexible devices.

Language: Английский

Citations

16
Nb2CTx MXene/Delignified Wood–Supported Phase-Change Composites with Desirable Photothermal Conversion Efficiency and Enhanced Flame Retardancy for Solar–Thermal Energy Storage DOI
Yuhong Tang, Ziqiang Cheng, Hao Yue

et al.

ACS Applied Energy Materials, Journal Year: 2024, Volume and Issue: 7(6), P. 2178 - 2188

Published: March 14, 2024

Although organic phase-change materials (PCMs) have been widely used for thermal energy storage, their high flammability, poor photothermal conversion efficiency, and liquid leakage issues severely restrict practical applications in solar–thermal fields. Herein, novel form-stabilized composite PCMs (CMPCMs) with storage density, excellent flame retardancy, desirable efficiency were prepared by impregnating n-docosane into phytic acid (PA)/melamine (MEL)-modified Nb2CTx MXene/delignified wood (CMDW) under vacuum assistance. The interconnected three-dimensional porous CMDW supported avoided PCM leakage, owing to its strong surface tension capillary forces. Differential scanning calorimetry analysis revealed that the CMPCMs exhibited satisfactory encapsulation ratios (up 91.6%) superior densities (190.2–219.5 J/g). Decorating delignified through MXene nanosheet deposition considerably improved 89.5%). Furthermore, increasing content of PA MEL composites, total heat release peak rate decreased remarkably due synergistic nitrogen–phosphorus flame-retardant mechanism, suggesting improvement properties CMPCMs. Overall, shape-stabilized demonstrate tremendous potential management applications.

Language: Английский

Citations

12
Solar Gas-Phase CO2 Hydrogenation by Multifunctional UiO-66 Photocatalysts DOI Creative Commons
Celia M. Rueda‐Navarro,

Zahraa Abou Khalil,

Arianna Melillo

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(9), P. 6470 - 6487

Published: April 12, 2024

Solar-assisted CO2 conversion into fuels and chemical products involves a range of technologies aimed at driving industrial decarbonization methods. In this work, we report on the development series multifunctional metal-organic frameworks (MOFs) based nitro- or amino-functionalized UiO-66(M) (M: Zr Zr/Ti) supported RuOx NPs as photocatalysts, having different energy band level diagrams, for hydrogenation under simulated concentrated sunlight irradiation. RuOx(1 wt %; 2.2 ± 0.9 nm)@UiO-66(Zr/Ti)-NO2 was found to be reusable photocatalyst, selective methanation (5.03 mmol g-1 after 22 h;, apparent quantum yield 350, 400, 600 nm 1.67, 0.25, 0.01%, respectively), show about 3-6 times activity compared with previous investigations. The photocatalysts were characterized by advanced spectroscopic techniques like femto- nanosecond transient absorption, spin electron resonance, photoluminescence spectroscopies together (photo)electrochemical measurements. photocatalytic mechanism assessed operando FTIR spectroscopy. results indicate that most active photocatalyst operates dual photochemical photothermal mechanism. This investigation shows potential MOFs solar-driven recycling.

Language: Английский

Citations

12
Photothermal Catalysts, Light and Heat Management: From Materials Design to Performance Evaluation DOI Open Access
Enrique V. Ramos‐Fernández, Alejandra Rendón‐Patiño, Diego Mateo

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 21, 2025

Abstract Photothermal catalysis, a frontier in heterogeneous combines light‐driven and thermally enhanced chemical reactions to optimize energy use reaction efficiencies at catalytic active sites. By leveraging photothermal conversion, this approach links renewable sources with industrial processes, offering significant potential for sustainable applications. This review categorizes catalysis into three types: thermocatalysis, photocatalysis, photo‐thermo coupling catalysis. Each category is analyzed, emphasizing mechanisms, performance factors, the role of advanced materials such as plasmonic nanoparticles, semiconductors, hybrid composites enhancing light absorption, thermal distribution, stability. Key challenges include achieving uniform photonic distributions within reactors developing accurate evaluation metrics. Applications CO₂ reduction, ammonia synthesis, plastic upcycling highlight environmental relevance technology. The identifies limitations suggests innovations design energy‐storing mechanisms enable continuous processes. Future directions emphasize catalysis's transform systems advance green production. synthesis aims guide research foster practical adoption technologies an scale.

Language: Английский

Citations

2