ACS Applied Nano Materials,
Journal Year:
2024,
Volume and Issue:
7(11), P. 13481 - 13488
Published: May 27, 2024
Artificial
nanofluidic
channels
that
achieve
light-driven
ion
transport
in
biological
systems
based
on
photoelectric
effect
have
attracted
significant
attention
for
signal
transduction
and
light
energy
conversion.
However,
the
light-responsive
performance
is
limited
by
charge
separation
efficiency
surface
of
channels.
Herein,
we
introduce
semiconductor
p–n
junctions
into
to
enhance
their
transport.
The
junction
formed
an
n-type
titanium
dioxide
(TiO2)
nanoparticles
layer
electrochemically
fabricated
p-type
polypyrrole
(PPy)
membrane.
light-induced
at
increases
density
positively
charged
PPy
Consequently,
current
through
enhanced
from
79.6
111.9
nA
40.6%
when
compared
with
a
single-component
proof-of-concept
demonstration
provides
route
toward
high-performance
channels,
which
demonstrates
potential
applications
light-controlled
mass
transport,
transduction,
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
34(36)
Published: March 30, 2024
Abstract
Through
evolution,
biological
organisms
have
developed
ways
to
sense
light
using
ion
channels,
which
holds
several
advantages,
such
as
energy
efficiency
and
water
resistance,
over
humanmade
optoelectronic
devices.
Herein,
a
retina‐inspired
nanofluidic
system
is
presented
with
Janus
heterogeneous
membrane
(J‐HM),
can
achieve
underwater
visual
imaging
through
light‐driven
active
transport.
The
J‐HMs
are
obtained
sequentially
assembled
WS
2
,
kind
of
metal–organic
framework
nanosheets
via
the
reaction
between
2,3,6,7,10,11‐hexahydroxytriphenylene
hydrate
(HHTP)
Cu
2+
(Cu‐HHTP).
Due
formed
intramembrane
electric
field
caused
by
efficient
charge
separation
under
illumination,
photovoltaic
driving
force
generated
for
transport
from
Cu‐HHTP
.
Furthermore,
unidirectionally
be
enhanced
self‐diffusion
concentration
gradient.
J‐HM
single‐pixel
design
shows
nearly
linear
response
intensity
has
enough
resolution
basic
object
recognition
well
long‐term
memory
after
data
processing
defined
pixelated
matrix,
pave
an
avenue
designing
more
intelligent
sensing
systems.
Small,
Journal Year:
2024,
Volume and Issue:
20(42)
Published: July 3, 2024
Natural
organisms
have
evolved
precise
sensing
systems
relying
on
unique
ion
channels,
which
can
efficiently
perceive
various
physical/chemical
stimuli
based
ionic
signal
transmission
in
biological
fluid
environments.
However,
it
is
still
a
huge
challenge
to
achieve
extensive
applications
of
the
artificial
counterparts
as
an
efficient
wet
platform
due
fluidity
working
medium.
Herein,
nanofluidic
membranes
with
selective
cation
transport
properties
and
solid-state
organic
electrochemical
transistors
(OECTs)
amplified
signals
are
integrated
together
mimic
human
gustatory
sensation,
achieving
reagent
recognition
portable
configuration.
Cu-HHTP
through
their
uniform
micropores
constructed
first,
followed
by
assembly
OECTs
form
designed
membrane-assisted
(nanofluidic
OECTs).
As
result,
they
distinguish
typically
reagents,
even
liquids
(ILs),
demonstrating
enhanced
perception
performance
under
wide
concentration
range
(10
Langmuir,
Journal Year:
2024,
Volume and Issue:
40(36), P. 18821 - 18836
Published: Aug. 28, 2024
Carbon
monoxide
(CO)
is
a
harmful
gas
with
significant
impacts
on
human
health
and
the
environment.
Its
timely
detection,
especially
in
event
of
thermal
runaway
automotive
lithium
batteries,
crucial
to
prevent
casualties.
This
paper
reviews
progress
development
efficient,
sensitive,
reliable
CO
sensors,
focusing
electrochemical,
optical,
resistive
sensing
materials.
Low-dimensional
materials
have
large
specific
surface
area,
providing
an
abundant
number
active
sites,
which
has
drawn
extensive
attention
from
researchers.
According
different
sensor
signals,
we
categorized
these
sensors
into
electrical
optical
signal
sensors.
We
hope
that
by
systematically
introducing
mechanism
performance
two
kinds
appropriate
can
be
developed
application
scenarios
so
as
realize
early
warning
monitoring
maximum
extent,
reduce
industrial
losses,
ensure
life
personnel.
ACS Materials Letters,
Journal Year:
2024,
Volume and Issue:
unknown, P. 5454 - 5478
Published: Nov. 18, 2024
Gas
sensing
is
vital
for
ecological
protection
in
agriculture,
early
disease
diagnosis
biomedicine,
and
safety
industrial
production.
Covalent
organic
frameworks
(COFs),
a
new
class
of
porous
polymer
materials,
can
be
customized
through
specific
ligand
selection
to
tailor
pore
sizes
active
sites,
enabling
them
selectively
enrich
interact
with
targeted
gas
molecules,
making
promising
candidates
sensing.
To
advance
their
use
this
field,
it
essential
investigate
the
mechanisms
complex
interactions
between
COFs
target
molecules
as
well
improve
COF
film
fabrication
methods.
This
review
outlines
design
strategies
films
across
multiscale:
molecular
interaction
mechanisms,
macroscopic
interfacial
synthesis
methods,
microscale/nanoscale
approaches
such
double-layer
filtration
micro/nanostructured
improved
transfer.
Finally,
several
key
research
directions
are
proposed
suitability
COF-based
materials
environments.
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: June 3, 2024
Abstract
2D
semiconductor
heterostructures
exhibit
broad
application
prospects.
However,
regular
nanochannels
of
rarely
caught
the
researcher's
attention.
Herein,
a
metal–organic
framework
(i.e.,
Cu
3
(HHTP)
2
)
and
transition
metal
dichalcogenides
MoS
)‐based
multilayer
van
der
Waals
heterostructure
/MoS
realized
band
alignment‐dominated
light‐driven
ion
transport
further
light‐enhanced
ionic
energy
generation.
High‐density
channels
provide
high‐speed
pathways
for
transmembrane
transport.
Upon
light
illumination,
net
flow
occurs
at
symmetric
concentration,
suggesting
directional
cationic
from
to
.
This
is
because
containing
type‐II
alignment
can
generate
photovoltaic
motive
force
through
light‐induced
efficient
charge
separation
drive
After
introducing
into
power
generation
system,
maximum
density
under
illumination
achieve
notable
improvement
different
concentration
differences.
In
addition
force,
material
defect
capture‐induced
surface
increase
also
raise
selectivity
flux,
greatly
facilitating
work
demonstrates
that
with
rational
not
only
be
potential
platform
optimizing
harvesting
but
new
thought
biomimetic
iontronic
devices.
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Oct. 23, 2024
Abstract
Metal‐organic
frameworks
(MOFs)
hold
significant
promise
in
the
realm
of
gas
sensing.
However,
current
understanding
their
sensing
mechanisms
remains
limited.
Furthermore,
large‐scale
fabrication
MOFs
is
hampered
by
inadequate
mechanical
properties.
These
two
challenges
contribute
to
sluggish
development
MOF‐based
gas‐sensing
materials.
In
this
review,
selection
metal
ions
and
organic
ligands
for
designing
first
presented,
deepening
interactions
between
different
ions/organic
target
gases.
Subsequently,
typical
interfacial
synthesis
strategies
(gas‐solid,
gas‐liquid,
solid‐liquid
interfaces)
are
provided,
highlighting
potential
constructing
MOF
membranes
on
superhydrophobic
and/or
superhydrophilic
substrates.
Then,
a
multi‐scale
structure
design
proposed,
including
multi‐dimensional
membrane
heterogeneous
design,
improve
performance
through
enhanced
mass
transfer
specific
sieving.
This
strategy
anticipated
augment
task‐specific
capabilities
materials
complex
environments.
Finally,
several
key
future
research
directions
outlined
with
aim
not
only
further
investigate
underlying
principles
but
also
achieve
efficient
detection
gases
amidst
interfering
elevated
moisture
levels.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 13, 2025
Abstract
Water
molecules
are
ubiquitous
disruptors
of
conventional
gas
sensing
materials,
often
leading
to
diminished
performance
in
materials
that
reliant
on
electronic
signal
transmission.
This
creates
the
pressing
need
for
efficient
with
anti‐humidity
interference
properties.
Here,
a
hammerhead
shark‐inspired
microvillus‐structured
ionic
elastomer
based
transmission
nanoconfined
space
is
constructed
by
incorporating
liquids
into
polymer
matrix.
The
elastomers
optimized
microvillus
structure
demonstrated
1.68‐fold
higher
response
than
flat
ones,
short
time
(9
s)
toward
30
ppm
triethylamine
(TEA),
excellent
selectivity
and
low
limit
detection
(LOD)
(104.56
ppb).
Such
serves
as
proof‐of‐concept
effectively
combining
solvated
ion
transport
design
develop
advanced
systems.
With
such
an
evident
(23.52%),
similar
(12
s),
LOD
(498.05
ppb),
long‐term
stability
(at
least
days)
achieved
at
relative
humidity
70%.
Mechanistic
investigations
revealed
effective
ions
facilitated
after
sequential
water
TEA
surroundings
while
significantly
enhanced
transport.
Furthermore,
utility
system
shrimp
decay
monitoring
under
wet
conditions.
ACS Nano,
Journal Year:
2024,
Volume and Issue:
18(52), P. 35729 - 35737
Published: Dec. 16, 2024
Bioinspired
light-driven
ion
transport
in
two-dimensional
(2D)
nanofluidics
offers
exciting
prospects
for
solar
energy
harvesting.
Current
single-component
nanofluidic
membranes
often
suffer
from
low
light-induced
driving
forces
due
to
the
easy
recombination
of
photogenerated
electron–hole
pairs.
Herein,
we
present
a
Pt@WS2
Mott–Schottky
heterojunction-based
2D
membrane
boosting
active
and
enhanced
ionic
power
The
photovoltaic
effect
heterojunctions
photoconductance
WS2
multilayers
account
more
efficient
charge
separation
across
membrane.
In
an
equilibrium
electrolyte
solution,
observe
directional
cationic
Pt
region
under
visible-light
illumination.
10–3
M
KCl
electrolyte,
photocurrent
photovoltage
reach
11.84
μA
cm–2
30.67
mV,
respectively.
Moreover,
output
can
up
5.02
W
m–2
light
illumination,
compared
value
2.56
without
irradiation.
This
work
not
only
introduces
mechanism
but
also
pathway
integrating
multiple
sources.
Cell Reports Physical Science,
Journal Year:
2024,
Volume and Issue:
5(7), P. 102051 - 102051
Published: June 17, 2024
Salinity
gradient
energy
harvesting
is
still
limited
to
rather
small
working
areas
in
laboratories.
Here,
we
report
a
thylakoid-inspired
nanofluidic
system
based
on
two-dimensional
homogeneous
multilayer
membrane
for
salinity
harvesting,
assisted
by
light-driven
active
ion
transport.
The
assembled
graphene
oxide
(GO)
nanosheets
decorated
with
photoelectric
5,10,15,20-tetrakis(4-aminophenyl)
porphyrin
molecules,
denoted
as
TGO.
Upon
light
illumination
the
low
concentration
side,
photovoltaic
established
via
light-induced
charge
separation
drive
cation
transport
from
unilluminated
side
illuminated
through
interlayer
spacing.
Combining
self-diffusive
transport,
TGO
shows
an
enhanced
output
power
density
of
1.17
W
m−2
area
0.2
mm2
under
50-fold
gradient,
∼54%
increase
original.
Furthermore,
applications
different
electrolyte
solutions
mono-
or
multications
confirm
feasibility
photoenhanced
43%
combination
artificial
seawater/river
water.