Journal of Materials Chemistry A,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
The
controlled
transition
from
o-CoSe
2
to
the
c-CoSe
crystalline
phase
was
achieved
by
using
different
levels
of
Br
doping
strategies
modulate
microwave
absorption
properties.
Advanced Functional Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 5, 2025
Abstract
Microwave‐absorbing
materials
are
widely
used
in
electromagnetic
protection
and
military
stealth
fields.
Hollow
structure
materials,
as
efficient
microwave
absorbing
have
garnered
considerable
attention,
since
they
beneficial
to
multiple
reflection
enhance
the
attenuation
loss
of
microwaves.
Herein,
a
strategy
is
proposed
prepare
hollow
Ni/NiO@PPy
particles
using
water‐soluble
template
method
combined
with
situ
polymerization
process.
The
cuboid
constructed
Na
2
SO
4
templates
then
filled
into
epoxy
resin
form
composite
films
excellent
absorption
properties.
film
under
optimal
conditions
exhibits
minimum
value
−72.14
dB
rate
more
than
99.99%
filling
content
10
wt.%.
By
adjusting
thickness,
an
effective
bandwidth
15.94
GHz
can
be
achieved,
which
almost
completely
covers
S,
C,
X,
Ku
bands.
CST
simulation
results
confirm
outstanding
radar
cross‐section
film.
Remarkably,
ultra‐low
2.5
wt.%,
still
achieves
99.90%,
demonstrating
highly
content.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 15, 2024
Abstract
Curved
support
can
significantly
change
the
electronic
structure
of
a
metal
single‐atom
(M‐SA)
and
thereby
fine
tune
its
intrinsic
physicochemical
properties.
However,
constructing
asymmetrically
coordinated
M‐SAs
on
highly
curved
supports
remains
challenging.
Here,
an
efficient
strategy
driven
by
different
thermal
decomposition
rates
two
polymers
is
proposed
to
create
Turing
surface
with
stripes
hollow
carbon
spheres
(HCSs)
for
anchoring
Fe‐N
3
S
1
moieties.
Experimental
theoretical
calculation
results
reveal
that
asymmetric
atoms
strain
Fe─N
bonds
induced
efficiently
break
symmetric
distribution
charge
around
Fe
enhance
dielectric
loss
HCSs,
synergistically
improving
electromagnetic
wave
absorption
property.
Remarkably,
film
constructed
‐anchored
HCSs
natural
rubber
exhibits
wide
effective
bandwidth
7.68
GHz
at
filling
ratio
6%.
Moreover,
also
possesses
excellent
hydrophobicity,
frost‐resistant
ability,
adhesiveness,
flexibility,
stretchability,
heat‐dispersion
which
expand
practical
applications
into
various
environments.
This
work
provides
insights
synergistic
effects
configurations
their
properties
offers
new
method
preparation
multifunctional
films.
Advanced Functional Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 12, 2024
Abstract
Freeze
casting
is
a
solidification
technique
utilized
in
the
fabrication
of
porous
materials.
However,
freeze
process
quite
complex,
and
significant
challenges
remain
precisely
controlling
pore
size
shape
structures.
This
study
aims
to
investigate
customization
multifunctional
electromagnetic
wave
(EMW)
absorbers
with
3D
structures
via
casting.
review
initially
presents
fundamental
principles
underlying
examines
correlation
between
internal
external
factors
during
preparation
porosity.
The
emerging
trends
constructing
novel
intricate
macroscopic
through
are
subsequently
outlined.
Furthermore,
this
focuses
on
composites
various
microstructures
low‐dimensional
building
blocks,
their
EMW
response
properties.
By
regulating
influencing
mechanisms
casting,
absorption
materials
exhibit
outstanding
advantages
such
as
property
manipulation,
controllable
structure,
high
porosity,
specific
surface
area,
lightweight,
flexibility.
These
features
broaden
applications
shielding,
mechanical
property,
radar
stealth,
thermal
insulation
fire
prevention,
flexible
sensors,
antifreeze
ability,
etc.
In
addition,
we
discuss
prospects
high‐performance
using
techniques.