Design principles of underpotential deposition chemistry for highly reversible multivalent metal anodes DOI
Yu Zhang,

Yanzeng Ge,

Hengyue Xu

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 74, P. 103991 - 103991

Published: Dec. 28, 2024

Language: Английский

High-Performance Bipolar Small-Molecule Organic Cathode for Wide-Temperature-Range Aqueous Zinc-Ion Batteries DOI
Hua Kang,

Quanwei Ma,

Yangyang Liu

et al.

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Organic small-molecules with redox activity are promising cathode candidates for aqueous zinc-ion batteries (AZIBs) due to their low cost, high safety and theoretical capacity. However, severe dissolution leads unsatisfactory electrochemical performance. Here, a dihydro-octaaza-pentacene (DOP) compound is synthesized as AZIBs by extending its N heterocyclic molecular structure. The extended structure provides dual active sites of n-type (C═N) p-type (-NH-) reactions while reducing through enhanced π-conjugation. Hence, the Zn//DOP battery demonstrates improved performance, e.g., an capacity 360 mAh g-1 at 0.05 A g-1. Even under temperature conditions - 50 °C, still maintain capacities 172 312 g-1, respectively. In/ex-situ spectroscopy provide thorough understanding storage mechanisms cations anions (Zn2+/H+ ClO4-) multielectron transfer process occurring electroactive sites. This strategy offers approach designing high-performance zinc-organic sustainable energy storage.

Language: Английский

Citations

0
Environmentally Benign and Long Cycling Mn-Ion Full Batteries Enabled by Hydrated Eutectic Electrolytes and Polycarbonyl Conjugated Organic Anodes DOI

Tengfei Dai,

Binze Yang,

Jie Wei

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: April 14, 2025

Aqueous rechargeable manganese (Mn)-ion batteries have recently emerged as a promising candidate for multivalent ion batteries. However, challenges remain, particularly in expanding the electrolyte's voltage window and identifying compatible anode materials. Herein, we introduce Mn-ion full battery comprising nickel hexacyanoferrate (NiHCF) cathode, perylene-3,4,9,10-tetracarboxylic diimide (PTCDI) anode, novel hydrated eutectic electrolyte formulated from Mn(ClO4)2·6H2O acetamide. This composition, optimized molar ratio, provides stable solvation structure that suppresses water reactivity supports high ionic conductivity, confirmed by spectroscopic molecular dynamics analyses. The PTCDI facilitates highly reversible Mn2+ storage via unique enolization redox reaction, delivering exceptional rate capability cycling stability. As result, NiHCF||PTCDI achieves 1.2 V plateau, excellent performance (up to 5.0 A g-1), long life with 95.6% capacity retention over 1200 cycles at 1.0 g-1. study proposes feasible strategy construction of environment-friendly, long-life low-cost aqueous batteries, offering sustainable high-performance solution future energy applications.

Language: Английский

Citations

0
Micro-Nano Scale In-Sn Protective Coating Layer with Zincophilicity for Ultra-Stable Dendrite-free Zinc-Ion Batteries DOI
Long Huang, Jing Cuan, Chuang Yue

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 106492 - 106492

Published: April 1, 2025

Language: Английский

Citations

0
Aluminum Ion Batteries: Electrolyte and Anode Innovations and Outlook DOI
Cheng Lu, Liangming Wei, Jinjin Li

et al.

Energy storage materials, Journal Year: 2025, Volume and Issue: unknown, P. 104274 - 104274

Published: April 1, 2025

Language: Английский

Citations

0
Deep eutectic solvent for high-performance aluminum-based hydrated eutectic electrolyte DOI
Cheng Lu, Zhilong Wang,

Bowen Tao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 155858 - 155858

Published: Sept. 1, 2024

Language: Английский

Citations

1
An π-conjugated organic cathode with multiple cyano-substituted for stable aqueous aluminum batteries DOI

Yong Lu,

Qing Ge,

Changde Hu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 682, P. 281 - 287

Published: Nov. 29, 2024

Language: Английский

Citations

0
Hydrophobic conjugated microporous polymer with hierarchical porous structure for multifunctional modification of Zn metal anodes DOI

Wei-Hai Yi,

Jianglin Wang, Dong‐Ting Zhang

et al.

Journal of Energy Storage, Journal Year: 2024, Volume and Issue: 107, P. 115029 - 115029

Published: Dec. 16, 2024

Language: Английский

Citations

0
Design principles of underpotential deposition chemistry for highly reversible multivalent metal anodes DOI
Yu Zhang,

Yanzeng Ge,

Hengyue Xu

et al.

Energy storage materials, Journal Year: 2024, Volume and Issue: 74, P. 103991 - 103991

Published: Dec. 28, 2024

Language: Английский

Citations

0