Advancements in Understanding the Physicochemical Properties of Reticular Materials: An In Situ and Operando Spectroscopic Perspective

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 24, 2025

The application of in situ and operando spectroscopic techniques has significantly advanced the understanding reticular materials, particularly metal-organic frameworks (MOFs) covalent organic (COFs). These offer real-time insights into dynamic structural, electronic, chemical changes that occur within these materials during various processes, such as catalysis, sorption, material synthesis. This review offers a comprehensive overview key used to investigate formation, functionalization, catalytic behavior materials. How have elucidated roles active sites, reaction intermediates, structural transformations under conditions, especially single-site electrocatalysis, photocatalysis, is highlighted. also discusses challenges opportunities lie ahead integrating methods with aiming foster further innovation design versatile

Language: Английский

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Correlative transmission electron and soft x-ray microscopy for bridging length scales and functional properties in nanoscience and materials research

Nano Today, Journal Year: 2025, Volume and Issue: 63, P. 102732 - 102732

Published: April 21, 2025

Language: Английский

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Structure–reactivity relationships in CO₂ hydrogenation to C₂₊ chemicals on Fe-based catalysts

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 16, 2024

This review critically discusses recent in situ and operando studies on Fe-based catalysts CO 2 hydrogenation, particular focusing the effect of composition, promoters, support particle size.

Language: Английский

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Reshaping catalysis beyond the conventional

Nature Catalysis, Journal Year: 2024, Volume and Issue: 7(8), P. 860 - 861

Published: Aug. 27, 2024

Language: Английский

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