Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133583 - 133583
Published: May 1, 2025
Language: Английский
Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 116, P. 115972 - 115972
Published: March 5, 2025
Language: Английский
Citations
3
Advanced Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 24, 2024
Abstract Hydrogen peroxide (H 2 O ) is a high‐value chemical widely used in electronics, textiles, paper bleaching, medical disinfection, and wastewater treatment. Traditional production methods, such as the anthraquinone oxidation process direct synthesis, require high energy consumption, involve risks from toxic substances explosions. Researchers are now exploring photochemical, electrochemical, photoelectrochemical synthesis methods to reduce use pollution. This review focuses on 2‐electron oxygen reduction reaction (2e − ORR) for electrochemical of H 2, discusses how catalyst active sites influence adsorption. Strategies enhance selectivity by regulating these presented. Catalysts strong adsorption initiate reactions weak *OOH promote formation. The also covers advances single‐atom catalysts (SACs), multi‐metal‐based catalysts, highlights non‐noble metal oxides, especially perovskite their versatile structures potential 2e ORR. localized surface plasmon resonance (LSPR) effects performance discussed. In conclusion, emphasis placed optimizing through theoretical experimental achieve efficient selective production, aiming sustainable commercial applications.
Language: Английский
Citations
14
Journal of Power Sources, Journal Year: 2025, Volume and Issue: 640, P. 236818 - 236818
Published: March 20, 2025
Language: Английский
Citations
2
Small, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 23, 2024
Abstract Metal‐organic frameworks (MOFs) hold significant promise in the realm of gas sensing. However, current understanding their sensing mechanisms remains limited. Furthermore, large‐scale fabrication MOFs is hampered by inadequate mechanical properties. These two challenges contribute to sluggish development MOF‐based gas‐sensing materials. In this review, selection metal ions and organic ligands for designing first presented, deepening interactions between different ions/organic target gases. Subsequently, typical interfacial synthesis strategies (gas‐solid, gas‐liquid, solid‐liquid interfaces) are provided, highlighting potential constructing MOF membranes on superhydrophobic and/or superhydrophilic substrates. Then, a multi‐scale structure design proposed, including multi‐dimensional membrane heterogeneous design, improve performance through enhanced mass transfer specific sieving. This strategy anticipated augment task‐specific capabilities materials complex environments. Finally, several key future research directions outlined with aim not only further investigate underlying principles but also achieve efficient detection gases amidst interfering elevated moisture levels.
Language: Английский
Citations
3
Analytical Biochemistry, Journal Year: 2025, Volume and Issue: 701, P. 115791 - 115791
Published: Feb. 1, 2025
Language: Английский
Citations
0
Advanced Composites and Hybrid Materials, Journal Year: 2025, Volume and Issue: 8(2)
Published: Feb. 11, 2025
Language: Английский
Citations
0
Advanced Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 19, 2025
Abstract The interactions exploration between microorganisms and nanostructures are pivotal steps toward advanced applications, but the antibody‐level bacteria grabbing is limited by poor understanding of interface identification mechanisms in small‐sized systems. Herein, de novo design a bioinspired hedgehog artificial mesoporous nanostructure (core–shell Au@Pt (mAPt)) proposed to investigate association topography efficient grabbing. These observations indicate that virus‐like spiky compensates for obstacles faced materials grabbing, including lack requisite microscopic cavities sufficient contact area. Molecular dynamics simulation reveals with heightened mechano‐invasiveness (6.56 × 10 3 KJ mol −1 ) facilitates attributed “mechanic invasion”‐induced hierarchical dynamic ranging from rough surface penetration fixation. Furthermore, light reflectance finite element calculation confirmed mAPt exhibits near‐superblack characteristic plasmonic hot spot, facilitating enhanced photothermal conversion power dissipation density at 2.04 21 W m −3 . After integrating response, enables applications immunoassay 50‐fold sensitivity enhancement over 99.99% vitro sterilization. It anticipated this novel biomimetic provides deeper promising paradigm combating.
Language: Английский
Citations
0
Langmuir, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 21, 2025
The self-assembly of giant amphiphilic molecules with diverse topological structures has been widely investigated in bulk, solution, and interfacial environments because it can lead to interesting geometric patterns. However, many or their self-assembling units are built by covalent bonds, which may limit the movement molecular blocks, affecting process microstructure. In contrast, noncovalent interactions nanomorphologies nanostructures. this study, we (BPOSS&POM) forming electrostatic between hydrophobic isobutyl polyhedral oligomeric silsesquioxanes (BPOSSs) hydrophilic polyoxometalates (POMs) investigate behavior water/acetone, water/THF, hexane/acetone cosolvents. By controlling solvent parameters, BPOSS&POM self-assembled into nanosheet, nanobelt, nanosphere, nanocrumb structures. morphology detailed nanostructure different self-assemblies were revealed performing transmission electron microscopy (TEM), scanning (SEM), small-angle X-ray scattering (SAXS) measurements. TEM SAXS results indicated that microphase exhibited a lamellar structure an interlayer distance about 3 nm. was alternatively organized layers BPOSS POM according size dimension. polarity solvents substantially affected nanoassemblies but not aggregation POM. This research offers insights preparation nanomaterials micromorphologies simply adjusting solution components.
Language: Английский
Citations
0
Published: Jan. 1, 2025
Language: Английский
Citations
0
Small, Journal Year: 2025, Volume and Issue: unknown
Published: March 5, 2025
Well-defined nanostructures (WDNSs) represent a transformative frontier in nanotechnology, enabling precise control over material properties through nanoscale engineering. The connectivity of building blocks is increasingly critical defining the and applications WDNSs. Traditional dimensionality-based classifications provide foundational insights but overlook delicate influence architectures on functionality. This perspective introduces supplementary classification framework based modes, including discrete connections, serial 2.5D 3D interpenetrations. Each category defines specific structural configurations that decide spatial arrangement, interaction dynamics, functional integration components. establishes unique for understanding WDNSs, linking their design with diverse catalysis, energy storage, biomedicine, beyond. By regulating strategies emerging demands, WDNSs offer considerable opportunities designing multifunctional materials, providing foundation advancing nanotechnology addressing complex scientific societal challenges. Finally, advanced rational design, accurate synthesis, comprehensive deployment, sustainable development remain to bottlenecks development.
Language: Английский
Citations
0