Recent Advances in MOF−Based Dual−Atom Catalysts for CO2 Reduction DOI
Wenjie Shi, Tong‐Bu Lu

Chemistry - A European Journal, Journal Year: 2025, Volume and Issue: unknown

Published: April 26, 2025

Abstract In recent years, the development of efficient catalysts for photo−/electro−catalytic CO 2 reduction reaction (CO RR) has become a major research focus due to growing environmental concerns and energy demands. Dual−atom (DACs), composed two metal atoms with suitable metal−metal distance integrated into supports, have shown great promise in enhancing catalytic performance via dual−metal synergistic catalysis (DMSC) effect. This review highlights advancements Metal−organic framework (MOF)−based DACs, which combine high atomic efficiency DACs tunable defined structures loadings. this review, we summarized developments on synthesis strategies MOF−based their applications RR, focusing role DMSC effect improving activity, stability, selectivity. Additionally, also discuss influence local electronic structure, coordination environment, atom interactions performance. aims provide comprehensive understanding MOF − based offers insights future potential sustainable conversion.

Language: Английский

Nearly 100% CO Selectivity for CO2 Reduction via Synergistic Engineering of Heteronuclear CuCo Dual Atoms DOI
Xiaoxiao Zhu,

Xin An,

Yuan Cong

et al.

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Monatomic catalysts demonstrate exceptional activity in CO2 hydrogenation for mitigating the greenhouse effect and achieving carbon neutrality goals. However, single-atom are limited by having only one type of active site, resulting unsatisfactory selectivity. In this work, a heteronuclear dual-atom catalyst (CuCoDA) is successfully synthesized using dual-anchoring method applied to hydrogenation. The synergistic between Cu Co atoms results remarkable CO selectivity 99.1%, with conversion rate 28.1%. experimental theoretical calculations that incorporation into monatomic enhances adsorption H2 on CuCoDA surface throughout reaction, thereby significantly promoting conversion. Simultaneously, cooperative minimizes CO* inhibits formation *CHO (a key intermediate methane generation), which suppresses further CO2. This an extremely high CO. study provides general strategy constructing dual-heteronuclear incorporating multiple metal species highlights critical importance interactions adjacent single development advanced catalysts.

Language: Английский

Citations

1
Electron delocalization engineering via hierarchical modulation in single-atom catalysts for highly efficient electrochemical CO2 reduction DOI
Xu Han, Hong Liu, Pengfei Cao

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160634 - 160634

Published: Feb. 1, 2025

Language: Английский

Citations

0
Potential‐Driven Dynamic Spring‐Effect of Pd─Cu Dual‐Atoms Empowered Stability and Activity for Electrocatalytic Reduction DOI Creative Commons

Pei‐Hua Li,

Yuan‐Fan Yang,

Zong‐Yin Song

et al.

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: April 26, 2025

Abstract Atomic‐level catalysts are extensively applied in heterogeneous catalysis fields. However, it is a general but ineluctable issue that active metal atoms may migrate, aggregate, deactivate, or leach during reaction processes, suppressing their catalytic performances. Designing superior intrinsic‐structural stability of atomic‐level with high activity and revealing dynamic structure evolution vital for wide applications complex reactions harsh conditions. Herein, high‐stable Pd─Cu dual‐atom PdN 3 ─CuN coordination engineered via strong chelation Cu 2+ ‐ions electron pairs from palladium‐source, achieving the highest turnover frequency under lowest overpotential Cr(VI) electrocatalytic reduction detection strong‐acid electrolytes. In situ X‐ray absorption fine spectra reveal “spring‐effect” Cu─Pd Cu─N bonds reversibly stretched potential changes can be recovered at 0.6 V regeneration. The modulated electron‐orbit coupling effect prevents Cu‐atoms aggregating as metallic nanoparticles. dual‐atoms interact two O H 2 CrO 4 , forming stable bridge configurations transferring electrons to promote Cr─O bond dissociation, which prominently decreases energy barriers. This work provides feasible route boost robustness single‐atoms easily affected by conditions sustainable applications.

Language: Английский

Citations

0
Recent Advances in MOF−Based Dual−Atom Catalysts for CO2 Reduction DOI
Wenjie Shi, Tong‐Bu Lu

Chemistry - A European Journal, Journal Year: 2025, Volume and Issue: unknown

Published: April 26, 2025

Abstract In recent years, the development of efficient catalysts for photo−/electro−catalytic CO 2 reduction reaction (CO RR) has become a major research focus due to growing environmental concerns and energy demands. Dual−atom (DACs), composed two metal atoms with suitable metal−metal distance integrated into supports, have shown great promise in enhancing catalytic performance via dual−metal synergistic catalysis (DMSC) effect. This review highlights advancements Metal−organic framework (MOF)−based DACs, which combine high atomic efficiency DACs tunable defined structures loadings. this review, we summarized developments on synthesis strategies MOF−based their applications RR, focusing role DMSC effect improving activity, stability, selectivity. Additionally, also discuss influence local electronic structure, coordination environment, atom interactions performance. aims provide comprehensive understanding MOF − based offers insights future potential sustainable conversion.

Language: Английский

Citations

0