ACS Applied Materials & Interfaces,
Journal Year:
2021,
Volume and Issue:
13(32), P. 38761 - 38772
Published: Aug. 9, 2021
Wearable
electromagnetic
interference
(EMI)
shielding
fabrics
are
highly
desirable
with
the
rapid
development
of
electronic
devices
and
wireless
communications
where
pollution
is
a
great
concern
for
human
health
reliability
precision
equipment.
The
balance
between
EMI
efficiency
(SE)
flexibility
fabric
still
challenging
because
generally
opposite
requirements
coating
thickness.
In
this
work,
MXene/insulative
polymer
an
alternating
structure
fabricated
via
stepwise
assembly
technique
to
judiciously
combine
excellent
elements,
reasonable
structure,
high
nanofiller
content
together
in
coating.
Owing
novel
strategy,
nanoscale
thickness
(∼500
nm)
has
realized
commercial
requirement
SE
well
retained
air
permeability
fabric.
Compared
corresponding
pure
MXene
coating,
such
multilayered
demonstrates
138.95%
enhancement
due
improved
dielectrical
properties
intensive
multiple
reflections
waves.
Additionally,
hybrid
also
acts
as
fire-resistant
barrier
inner
flammable
protect
beings
case
accidental
fire.
This
work
provides
new
insights
into
rational
design
shields
nanometer
realize
performance
good
fire
resistance
new-generation
portable
wearable
products.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(13), P. 11432 - 11473
Published: May 10, 2022
Metal
ions
are
ubiquitous
in
nature
and
play
significant
roles
assembling
functional
materials
fields
spanning
chemistry,
biology,
science.
Metal-phenolic
assembled
from
phenolic
components
the
presence
of
metal
through
formation
metal-organic
complexes.
Alkali,
alkali-earth,
transition,
noble
as
well
metalloids
interacting
with
building
blocks
have
been
widely
exploited
to
generate
diverse
hybrid
materials.
Despite
extensive
studies
on
synthesis
metal-phenolic
materials,
a
comprehensive
summary
how
guide
assembly
compounds
is
lacking.
A
fundamental
understanding
engineering
will
facilitate
specific
properties.
In
this
review,
we
focus
diversity
function
material
emerging
applications.
Specifically,
discuss
range
underlying
interactions,
including
(i)
cation-π,
(ii)
coordination,
(iii)
redox,
(iv)
dynamic
covalent
highlight
wide
properties
resulting
these
interactions.
Applications
(e.g.,
biological,
catalytic,
environmental)
perspectives
also
highlighted.
Chemical Society Reviews,
Journal Year:
2021,
Volume and Issue:
50(20), P. 11668 - 11683
Published: Jan. 1, 2021
Biofouling
is
a
serious
problem
in
the
medical,
marine,
and
all
other
industrial
fields
as
it
poses
significant
health
risks
financial
losses.
Therefore,
there
great
demand
for
endowing
surfaces
with
antifouling
properties
to
mitigate
biofouling.
Zwitterionic
polymers
(containing
an
equimolar
number
of
homogeneously
distributed
anionic
cationic
groups
on
polymer
chains)
have
been
used
extensively
one
best
materials
surface
modification.
Being
superhydrophilic
polymer,
zwitterionic
need
strong
binding
agent
continue
remain
attached
long-term
applications.
The
use
mussel-inspired
dopamine
adhesive
functional
layer
most
widely
exploited
approaches
attachment
zwitterion
via
thiol
amine
chemistry.
Based
recent
studies,
we
categorized
this
conjugation
into
four
different
approaches:
(1)
zwitterions
by
direct
modification
moiety;
(2)
co-deposition
polymers;
(3)
post
polydopamine
(PDA)
coated
surface;
(4)
surface-initiated
polymerization
using
modified
initiators.
In
review,
briefly
discussed
about
possible
mechanisms
reactions
promising
how
conjugated
system
significantly
contributes
development
non-fouling
along
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(18), P. 14594 - 14678
Published: Sept. 2, 2022
Noncovalent
interactions,
which
usually
feature
tunable
strength,
reversibility,
and
environmental
adaptability,
have
been
recognized
as
driving
forces
in
a
variety
of
biological
chemical
processes,
contributing
to
the
recognition
between
molecules,
formation
molecule
clusters,
establishment
complex
structures
macromolecules.
The
marriage
noncovalent
interactions
conventional
covalent
polymers
offers
systems
novel
mechanical,
physicochemical,
properties,
are
highly
dependent
on
binding
mechanisms
that
can
be
illuminated
via
quantification.
This
review
systematically
discusses
nanomechanical
characterization
typical
polymeric
systems,
mainly
through
direct
force
measurements
at
microscopic,
nanoscopic,
molecular
levels,
provide
quantitative
information
(e.g.,
ranges,
strengths,
dynamics)
behaviors.
fundamental
understandings
intermolecular
interfacial
then
correlated
macroscopic
performances
series
noncovalently
bonded
polymers,
whose
functions
stimuli-responsiveness,
self-healing
capacity,
universal
adhesiveness)
customized
manipulation
providing
insights
into
rational
design
advanced
materials
with
applications
biomedical,
energy,
environmental,
other
engineering
fields.
Advanced Functional Materials,
Journal Year:
2021,
Volume and Issue:
32(8)
Published: Nov. 9, 2021
Abstract
Recently,
soaring
developments
in
microelectronics
raise
an
urgent
demand
for
thermal
management
materials
to
tackle
their
“overheating”
concerns.
Polymer
nanocomposites
are
promising
candidates
but
often
suffer
from
inability
of
mass
production,
high‐cost,
poor
mechanical
robustness,
and
even
flammability.
Hence,
it
is
desirable
scalably
fabricate
low‐cost,
robust
polymeric
that
highly
thermally
conductive
fire‐retardant
ensure
safe
efficient
management.
Herein,
the
scalable
production
nacre‐like
anisotropic
nanocomposite
films
using
layer‐by‐layer
assembly
phenylphosphonic
acid@graphene
nanoplatelets
(PPA@GNPs)‐poly(vinyl
alcohol)
(PVA)
layer
GNPs
layers,
demonstrated.
The
PPA
serves
as
interfacial
modifiers
fire
retardants
flammable
PVA
(film‐forming
agent)
(inexpensive
nanofillers)
via
hydrogen‐bonding
π–π
stacking.
resultant
exhibits
a
high
flexibility,
tensile
strength
259
MPa,
ultrahigh
in‐plane
conductivity
82.4
W
m
‐1
K
,
making
effectively
cool
smartphone
high‐power
light
emitting
diode
modules,
outperforming
commercial
tinfoil
counterparts.
Moreover,
as‐designed
intrinsically
can
shield
electromagnetic
interference.
This
work
offers
general
strategy
holding
great
promise
electronic,
military,
aerospace
fields.
Physical Chemistry Chemical Physics,
Journal Year:
2021,
Volume and Issue:
24(7), P. 4097 - 4115
Published: Dec. 2, 2021
While
the
layer-by-layer
(LbL)
assembly
method
has
already
reached
a
certain
maturity,
there
is
still
plenty
of
room
for
expanding
its
usefulness
fabrication
nanoarchitectonics-based
materials
and
devices.
Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
33(9)
Published: Dec. 25, 2022
Abstract
Nanofiltration
membrane
plays
an
increasingly
important
role
in
many
industrial
applications,
such
as
water
treatment
and
resource
recovery.
The
performance
of
the
smart
nanofiltration
is
largely
controlled
by
pore
size,
Donnan
effect,
surface
wettability,
which
are
determined
function
stimuli‐responsive
components.
Smart
membranes,
contain
components,
capable
changing
their
physical
chemical
properties
response
to
changes
environment
so
that
microstructure
will
have
more
efficient
performances
broader
application
prospects
than
current
traditional
membranes.
Herein,
preparation
methods
membranes
described
they
systematically
classified
accordingly
mechanisms.
Moreover,
latest
progress
main
mechanism
each
stimuli‐response
type
through
relevant
examples
discussed
summarized.
Finally,
this
review
provides
new
insights
into
remaining
challenges
future
directions
Fueled
advances
chemistry
materials
science,
it
expected
build
a
platform
for
benefit
mankind.
Pharmaceutics,
Journal Year:
2022,
Volume and Issue:
14(4), P. 778 - 778
Published: April 2, 2022
Liposomes
are
highly
advantageous
platforms
for
drug
delivery.
To
improve
the
colloidal
stability
and
avoid
rapid
uptake
by
mononuclear
phagocytic
system
of
conventional
liposomes
while
controlling
release
encapsulated
agents,
modification
with
well-designed
polymers
to
modulate
physiological,
particularly
interfacial
properties
carriers,
has
been
intensively
investigated.
Briefly,
incorporated
into
mainly
using
"grafting"
or
"coating",
defined
according
configuration
at
surface.
Polymer-modified
preserve
advantages
as
drug-delivery
carriers
possess
specific
functionality
from
polymers,
such
long
circulation,
precise
targeting,
stimulus-responsiveness,
thereby
resulting
in
improved
pharmacokinetics,
biodistribution,
toxicity,
therapeutic
efficacy.
In
this
review,
we
summarize
progress
polymer-modified
delivery,
focusing
on
change
physiological
factors
influencing
overall
