Energy & Fuels,
Journal Year:
2023,
Volume and Issue:
37(17), P. 12623 - 12664
Published: Aug. 15, 2023
Two-dimensional
(2D)
titanium
carbide
(Ti3C2)
MXenes
have
gained
increasing
attention
in
photocatalytic
applications
due
to
their
prominent
electrical
conductivity,
optical
properties,
and
abundant
surface
functional
groups.
The
unique
layered
microstructure
characteristics
of
Ti3C2
provide
a
large
area,
interlayer
spacing,
hydrophilic
groups,
contributing
high
efficiency.
Graphitic
carbon
nitride
is
very
promising
among
the
semiconductors
its
structure
higher
reduction
potential.
present
study
discusses
recent
advances
various
structures
coupled
with
g-C3N4
for
hydrogen
evolution
reactions
(HER),
CO2
(CO2
RR),
reforming
methane
RM).
Initially,
we
an
overview
fundamental
properties
Ti3C2-based
composites
synthesis
approaches,
including
development,
group
formation,
etching
agents.
We
further
explore
using
different
as
binary
ternary
composite
involvement
other
sensitizers.
performance
water
splitting
produce
systems,
conversion
H2O,
methanation,
dry
CH4
(DRM),
bireforming
(BRM),
discussed
detail.
groups
efficient
electron
transport
pathways
make
them
excellent
candidates
catalysts
yield
rates
selectivity.
Finally,
this
review
provides
valuable
insights
into
potential
composites,
future
research
directions
field
are
proposed.
Chemical Society Reviews,
Journal Year:
2024,
Volume and Issue:
53(6), P. 3002 - 3035
Published: Jan. 1, 2024
The
present
review
summarizes
the
current
state-of-the-art
in
MOF-based
heterojunctions
three
important
photocatalytic
processes:
hydrogen
evolution
reaction,
CO
2
photoreduction
and
photodegradation
of
dyes.
Journal of Materials Chemistry A,
Journal Year:
2023,
Volume and Issue:
11(13), P. 6966 - 6977
Published: Jan. 1, 2023
Based
on
the
idea
of
facilitating
charge
transfer
by
constructing
a
Schottky
junction,
we
assembled
porphyrin-based
MOF
(Co-TCPP(Fe))
with
Mxene
(Ti
3
C
2
T
x
)
through
hydrogen
bonding
to
offer
high-performance
chemiresistive
NO
sensing
hybrid.