Chemical Papers, Journal Year: 2024, Volume and Issue: 78(10), P. 5833 - 5850
Published: May 23, 2024
Language: Английский
Chemical Papers, Journal Year: 2024, Volume and Issue: 78(10), P. 5833 - 5850
Published: May 23, 2024
Language: Английский
Materials Chemistry and Physics, Journal Year: 2025, Volume and Issue: unknown, P. 130410 - 130410
Published: Jan. 1, 2025
Language: Английский
Citations
2International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 111, P. 606 - 622
Published: Feb. 27, 2025
Language: Английский
Citations
2Journal of Industrial and Engineering Chemistry, Journal Year: 2023, Volume and Issue: 132, P. 36 - 49
Published: Nov. 19, 2023
Deep eutectic solvents (DESs) are a group of eco-friendly, low-cost and tuneable that have gained significant attention in recent years due to their remarkable properties including high solubility conductivity, low toxicity easy recovery. DESs also demonstrated outstanding catalytic activity, especially as green alternative traditional catalysts several chemical reactions organic synthesis, biomass conversion pharmaceutical manufacturing, among others. In this review, we explore the potential co-solvents reaction media or diversity reactions, focusing on both homogeneous heterogeneous catalysis electrocatalysis during last quinquenium. The review article is organised three main sections: catalysis, electrocatalysis. each section, most research regarding versatile types synthesis presented discussed. Furthermore, offers insights into future perspectives catalysis.
Language: Английский
Citations
26Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: 685, P. 133282 - 133282
Published: Jan. 19, 2024
Language: Английский
Citations
10ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(7), P. 6749 - 6771
Published: March 27, 2024
CeO2 (cerium dioxide or ceria) is a versatile material for industrial catalysis because of its reversible Ce4+/Ce3+ redox pair and tunable oxygen vacancies. Purification air pollutants released from vehicles stationary chemical industries one the imperative catalytic applications CeO2. In this regard, significant efforts have been made to improve properties by precisely controlling its' particle shape. This fascinating shape-controlled strategy can stabilize surface-enriched crystal facets with excellent properties, abundant surface vacancies, enhanced active-site accessibility, high activities. The synergistic effect doping deposition transition metals in improving structure–activity ceria also unraveled pollution control. Thus, review aims summarize elucidate advances field control using ceria-based nanomaterials. adverse effects four types pollutants, namely carbon monoxide, soot particulates, nitrogen oxides, volatile organic compounds, while emphasizing drawbacks challenges associated current technologies were briefly provided. role various doped (Zr, Ti, Mn, Co, Fe, Ni, etc.) deposited (Au, Pt, Pd, Ru, Ag, Cu, well-defined morphologies (rods, cubes, tubes, polyhedra, spheres, fibers, was meticulously discussed. We hope that timely important provide promising strategies rational design advanced catalysts not only but energy-related applications.
Language: Английский
Citations
10Optical Materials, Journal Year: 2024, Volume and Issue: 148, P. 114871 - 114871
Published: Jan. 10, 2024
Language: Английский
Citations
8Ceramics International, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
Language: Английский
Citations
1ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(6), P. 5899 - 5911
Published: March 5, 2024
This study showed the dual role of Nb (dopant and active site) in improving structure–activity properties shape-controlled CeO2 nanorods for selective synthesis functional imines benzimidazoles via oxidative coupling benzyl alcohols with anilines o-phenylenediamines, respectively. The powder X-ray diffraction (XRD) studies lattice contraction fluorite ceria due to replacement larger Ce4+ (0.97 Å) by smaller Nb5+ (0.74 lattice, providing more defects (Ce3+ oxygen vacancies), as elucidated XPS studies. dispersion Nb2O5 on surface Nb-doped provided strong acid sites, confirmed pyridine-adsorbed Fourier transform infrared (FT-IR) study. combined effect vacancies sites could promote activation molecular alcohol, respectively, achieving ∼97–99% yields imine benzimidazole liquid-phase C–N reactions over Nb-CeO2 nanorod catalyst calcined at 400 °C (NbCeNR4). versatile catalytic efficiency NbCeNR4 nanomaterial is showcased synthesizing various good excellent yields. nanocatalyst stable during reaction revealed hot filtration test reusability 4 cycles.
Language: Английский
Citations
7Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113719 - 113719
Published: July 31, 2024
Language: Английский
Citations
7ACS Omega, Journal Year: 2024, Volume and Issue: 9(14), P. 16420 - 16428
Published: March 28, 2024
The microwave-assisted synthesis approach was used to synthesize Eu(OH)3 and Co–Eu(OH)3 nanorods. Various techniques were investigate the structural, optical, morphological features of NRs. Both NRs found be hexagonal with crystallite sizes ranging from 21 35 nm. FT-IR Raman spectra confirmed formation Co–Eu(OH)3. Rod-shaped average lengths diameters 27 50 nm 8 12 nm, respectively, by TEM. addition Co increase particle size. Furthermore, increased doping, band gap energies lowered (3.80–2.49 eV) in comparison Eu(OH)3, PL intensities doping quenched, suggesting lessening electron/hole recombination. effect these altered properties observed through photocatalytic degradation brilliant green dye (BG) photoelectrochemical activity. In BG, 5% had highest response. However, experiments suggested that 10% showed improved activity when exposed visible light. As a result, have potential promising visible-light active material for photocatalysis.
Language: Английский
Citations
5