Efficient CO2/CH4 Separation Using Polysulfone/NH2-MIL-125(Ti) Mixed Matrix Membranes DOI Creative Commons
Mustafa Alsaady, Sharjeel Waqas,

Muhammad Hamad Zeeshan

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

This study investigates the fabrication and optimization of mixed matrix membranes (MMMs) composed NH2-MIL-125(Ti), a metal–organic framework (MOF), dispersed within polysulfone (PSf) polymer matrix, for efficient CO2/CH4 separation. The MMMs were prepared by using solution casting method, their morphology gas separation performance systematically characterized. effect MOF addition into permeability, selectivity evaluated permeation setup. Results indicate that incorporating NH2-MIL-125(Ti) nanoparticles enhances CO2 over CH4 compared to pure while maintaining acceptable permeability. membrane demonstrates uniform distribution filler in matrix. PSf/NH2-MIL-125(Ti)-15% showed exceptional permeability performance. Specifically, it achieved 19.17 Barrer. Additionally, exhibited 31.95, indicating its ability effectively differentiate between gases, which is critical applications such as natural purification carbon capture. Furthermore, produced this outstanding resistance plasticization. demonstrated superior pressure resistance, withstanding up 14 bar without significant degradation pristine PSf membrane, succumbed plasticization at 4 bar. enhanced attributed incorporation combination high excellent selectivity, robust positions highly effective applications. results underscore potential these achieve significantly better metrics than traditional membranes, making them promising option industrial processes.

Language: Английский

Gradient Cross‐Linking Graphene Oxide–Integrated Nanofiltration Polyvinylpyrrolidone Membrane for Polycyclic Aromatic Hydrocarbons Removal DOI Creative Commons
Loai Alkhattabi, Noorfidza Yub Harun,

Muhammad Hamad Zeeshan

et al.

International Journal of Polymer Science, Journal Year: 2025, Volume and Issue: 2025(1)

Published: Jan. 1, 2025

Polycyclic aromatic hydrocarbons (PAHs) persist as organic contaminants within diverse water reservoirs, posing significant environmental and health risks. Nanofiltration (NF) membranes have emerged effective tools for PAHs removal owing to their ability separate based on size. However, membrane fouling limited rejection efficiency remain challenges. This study developed a novel gradient cross‐linking graphene oxide (GO)–integrated polyvinylpyrrolidone (PVP) NF enhance while mitigating issues. The approach GO integration are aimed at improving the membrane’s performance, stability, antifouling properties. Fourier transform spectroscopy spectra of GO‐PVP showed new peaks, indicating linkage. flux increased with concentration due hydrophilicity; however, decreased loading 0.5 wt% poor distribution. results exhibited higher 72.9 ± 2.9 L m −2 h −1 , obtained 0.4 loading. Salt development large pores; hence, there is always trade‐off between salt rejection. presents promising efficiently removing from sources. has potential be applied in various treatment applications, contributing improved quality protection.

Language: Английский

Citations

2
Synthesis of electrospun polymer nanofiber membranes with TiO2 particles for the photocatalytic degradation of venlafaxine DOI
Beatriz Caetano Benuto, Sharise B.R. Berton,

Milena P. Ferreira

et al.

Chemical Papers, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 7, 2025

Language: Английский

Citations

1
Current Progress on Dual‐Layer Hollow Fiber Mixed‐Matrix Membrane in CO2 Capture DOI
Muhammad Hamad Zeeshan, Yin Fong Yeong, Thiam Leng Chew

et al.

ChemBioEng Reviews, Journal Year: 2024, Volume and Issue: 11(3), P. 513 - 542

Published: May 1, 2024

Abstract Carbon dioxide (CO 2 ) is a greenhouse gas which mainly found in natural (NG), biogas, and flue gas. Anthropogenic CO emissions are the direct result of burning fossil fuels. Meanwhile, pre‐ postcombustion separation current state removal method an extensive manner. From environmental, economic, transportation perspectives, has driven development its process technology. Among reported technologies, membrane‐based technologies have grown substantially, breakthroughs advances past decades. This review paper aims to provide overview on competitive processes, different types membranes available, transport mechanisms, fabrication hollow fiber membranes, particularly dual‐layer membrane. The performance effect spinning parameters formation highlighted. In addition, approaches improve adhesion, strategies enhance filler compatibility mixed‐matrix post‐treatments membrane also discussed. Finally, challenges future perspectives toward capture, /CH 4 /N separation, included, due substantial relevance industry.

Language: Английский

Citations

4
Intercalation of GO-Ag nanoparticles in cellulose acetate nanofiltration mixed matrix membrane for efficient removal of chromium and cobalt ions from wastewater DOI
Muhammad Hamad Zeeshan,

Umm E. Ruman,

Muhammad Imtiaz Shafiq

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(5), P. 113713 - 113713

Published: July 30, 2024

Language: Английский

Citations

4
Efficient CO2/CH4 Separation Using Polysulfone/NH2-MIL-125(Ti) Mixed Matrix Membranes DOI Creative Commons
Mustafa Alsaady, Sharjeel Waqas,

Muhammad Hamad Zeeshan

et al.

ACS Omega, Journal Year: 2025, Volume and Issue: unknown

Published: March 18, 2025

This study investigates the fabrication and optimization of mixed matrix membranes (MMMs) composed NH2-MIL-125(Ti), a metal–organic framework (MOF), dispersed within polysulfone (PSf) polymer matrix, for efficient CO2/CH4 separation. The MMMs were prepared by using solution casting method, their morphology gas separation performance systematically characterized. effect MOF addition into permeability, selectivity evaluated permeation setup. Results indicate that incorporating NH2-MIL-125(Ti) nanoparticles enhances CO2 over CH4 compared to pure while maintaining acceptable permeability. membrane demonstrates uniform distribution filler in matrix. PSf/NH2-MIL-125(Ti)-15% showed exceptional permeability performance. Specifically, it achieved 19.17 Barrer. Additionally, exhibited 31.95, indicating its ability effectively differentiate between gases, which is critical applications such as natural purification carbon capture. Furthermore, produced this outstanding resistance plasticization. demonstrated superior pressure resistance, withstanding up 14 bar without significant degradation pristine PSf membrane, succumbed plasticization at 4 bar. enhanced attributed incorporation combination high excellent selectivity, robust positions highly effective applications. results underscore potential these achieve significantly better metrics than traditional membranes, making them promising option industrial processes.

Language: Английский

Citations

0