Research, Journal Year: 2024, Volume and Issue: 7

Published: Jan. 1, 2024

This review comprehensively covers recent developments of cyclodextrin-mediated chemical transformations for green chemistry. These cyclic oligomers glucose are nontoxic, eco-friendly, and recyclable to accomplish eminent functions in water. Their most important feature is form inclusion complexes with reactants, intermediates, and/or catalysts. As a result, their cavities serve as sterically restricted apolar reaction fields promote the efficiency selectivity reactions. Furthermore, unstable reagents intermediates protected from undesired side The scope applications has been further widened through covalent or noncovalent modifications. Combinations them metal catalysis especially successful. In terms these effects, various reactions achieved high yield so that valuable chemicals synthesized multiple components one-pot cyclodextrin units orderly assembled polymers show cooperation advanced properties. Recently, cyclodextrin-based metal–organic frameworks polyoxometalate–cyclodextrin have fabricated employed unique applications. Cyclodextrins fulfill many requirements chemistry should make enormous contributions this growing field.

Language: Английский