Progress and Prospects in Cathode Materials for Sodium-Ion Batteries: Synthesis, Characterization, and Engineering Aspects

Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(21), P. 20285 - 20313

Published: Oct. 23, 2024

The need for sustainable and economically viable energy storage technologies is increasing critically as the world transitions toward renewable electrified transportation. Sodium-ion batteries (SIBs) have emerged a promising alternative to lithium-ion (LIBs) due abundant availability of sodium potential lower costs. However, development high-performance cathode materials remains key challenge in realizing full SIBs. Recent advancements focused on improving electrochemical properties through various strategies, particularly doping cations anions into layered transition metal oxides (LTMOs). Researchers enhanced specific capacity, cycling stability, rate performance. Doping not only improves structural stability but also mitigates issues such phase voltage decay, which are critical long-term performance In addition these advancements, there growing priority eliminating cobalt from environmental economic concerns. Cobalt-free alternatives, manganese-rich iron-based compounds, shown considerable promise, delivering competitive without ethical supply chain associated with cobalt. Global research efforts made significant strides overcoming technical barriers SIB commercialization. Collaborative projects across North America, Europe, Asia accelerating scalable synthesis techniques optimization material properties. These ionic conductivity ensuring integrity cathodes during cycling. integration advanced characterization has played pivotal role understanding mechanisms at play, guiding design next-generation materials. As technology continues evolve, its applications large-scale grid stabilization becoming increasingly apparent. combination raw materials, improved doping, shift cobalt-free compositions positions SIBs strong contender market. This review highlights progress challenges that remain, outlining future directions will be crucial transitioning laboratory real-world applications.

Language: Английский

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Unlocking the Potential: Na₄Fe₃(PO₄)₂(P₂O₇) Supporting the Innovation of Commercial Sodium‐Ion Batteries

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 26, 2025

Abstract Sodium‐ion batteries (SIBs) are highly anticipated as an efficient energy storage solution in addressing contemporary challenges. The pursuit of high‐performance cathode materials is critical for the commercialization SIBs. Among contenders, Na 4 Fe 3 (PO ) 2 (P O 7 (NFPP) one most promising commercial due to its stable structure framework and excellent sodium capability. Although research on NFPP has achieved great progress, especially last 10 years, timely dedicated summary progress prospect this rising star SIBs not been reported. This review provides a comprehensive overview advancement material In review, crystal mechanism examined first. Then, different proposed preparation methods have elaborated following section. After that, optimization strategies discussed enhance performance detail. At last, gap between current practical application highlighted, possible future directions proposed.

Language: Английский

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Advancing High-Voltage Cathodes for Sodium-Ion Batteries: Challenges, Material Innovations and Future Directions

Energy storage materials, Journal Year: 2025, Volume and Issue: 76, P. 104133 - 104133

Published: Feb. 19, 2025

Language: Английский

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Boosting the cycling stability of Na3VFe(PO4)3 cathodes for sodium-ion batteries by zinc oxide coating

Journal of Energy Storage, Journal Year: 2025, Volume and Issue: 118, P. 116295 - 116295

Published: March 19, 2025

Language: Английский

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Investigating the interfacial interactions in CoSe₂@CNTs for improved sodium storage performance

New Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

Cobalt diselenide @ carbon nanotube (CoSe 2 @CNTs) composites featuring a heterogeneous structure were synthesized using solvothermal method.

Language: Английский

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Carbonyl based electrode materials for rechargeable sodium (Na)-ion batteries (SIBs): a review

Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 46, P. 102711 - 102711

Published: April 19, 2025

Language: Английский

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Design and preparation of novel Na4Ca3(AlO2)10 material with superior corrosion resistance to alkali erosion

Ceramics International, Journal Year: 2025, Volume and Issue: unknown

Published: April 1, 2025

Language: Английский

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Structural, morphological, and electric study of doped- Na2Zn2TeO6 family in a wide range of temperatures

Materials Science and Engineering B, Journal Year: 2024, Volume and Issue: 312, P. 117865 - 117865

Published: Nov. 27, 2024

Language: Английский

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A Comprehensive Review on Iron-Based Sulfate Cathodes for Sodium-Ion Batteries

Nanomaterials, Journal Year: 2024, Volume and Issue: 14(23), P. 1915 - 1915

Published: Nov. 28, 2024

Sodium-ion batteries (SIBs) are advantageous for large-scale energy storage due to the plentiful and ubiquitous nature of sodium resources, coupled with their lower cost relative alternative technologies. To expedite market adoption SIBs, enhancing density SIBs is essential. Raising operational voltage cathode regarded as an effective strategy achieving this goal, but it requires stable high-voltage materials. Sodium iron sulfate (NFSO) considered be a promising material its framework, adjustable structure, safety, high electronegativity SO

Language: Английский

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Enhanced High-Rate Performance of Zr-Doped P2-Na0.67ni0.33mn0.67o2 Cathode for Sodium-Ion Batteries

Published: Jan. 1, 2024

Language: Английский

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