Small Methods,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 7, 2025
Abstract
Metal
oxide
semiconductors
(MOSs)
have
emerged
as
pivotal
materials
for
gas
sensing
technologies
due
to
their
inherent
advantages,
including
cost‐effectiveness,
simplicity
in
synthesis,
and
easy
fabrication
of
nanodevices.
These
characteristics
made
MOSs
widely
applicable
industrial,
environmental,
biological
monitoring.
While
offer
intrinsic
gas‐sensing
properties,
limited
active
site
density
function
diversity
restrict
sensitivity
selectivity,
especially
complex
gaseous
environments.
To
overcome
these
limitations,
extensive
research
efforts
been
devoted
functionalizing
through
strategies
such
heterojunction
construction,
noble
metal
nanoparticle
loading
(e.g.,
Au,
Pt,
Ag,
Pd),
heteroatom
doping
Si,
Cr).
Furthermore,
composite
an
effective
approach
enhance
MOSs‐based
sensors
by
integrating
carbon‐based
or
polymers
leverage
synergistic
interactions.
modifications
expand
the
applicability
detecting
volatile
organic
compounds,
toxic
gases,
flammable
gases.
This
review
systematically
examines
synthesis
performance
enhancements
achieved
functionalization
material
integration,
emphasizing
structure‐property
relationships,
interfacial
charge
transfer
dynamics,
adsorption
mechanisms.
Finally,
challenges
future
directions
rational
design
next‐generation
are
outlined,
providing
critical
insights
advancing
intelligent
technologies.
Small Methods,
Journal Year:
2025,
Volume and Issue:
unknown
Published: May 7, 2025
Abstract
Metal
oxide
semiconductors
(MOSs)
have
emerged
as
pivotal
materials
for
gas
sensing
technologies
due
to
their
inherent
advantages,
including
cost‐effectiveness,
simplicity
in
synthesis,
and
easy
fabrication
of
nanodevices.
These
characteristics
made
MOSs
widely
applicable
industrial,
environmental,
biological
monitoring.
While
offer
intrinsic
gas‐sensing
properties,
limited
active
site
density
function
diversity
restrict
sensitivity
selectivity,
especially
complex
gaseous
environments.
To
overcome
these
limitations,
extensive
research
efforts
been
devoted
functionalizing
through
strategies
such
heterojunction
construction,
noble
metal
nanoparticle
loading
(e.g.,
Au,
Pt,
Ag,
Pd),
heteroatom
doping
Si,
Cr).
Furthermore,
composite
an
effective
approach
enhance
MOSs‐based
sensors
by
integrating
carbon‐based
or
polymers
leverage
synergistic
interactions.
modifications
expand
the
applicability
detecting
volatile
organic
compounds,
toxic
gases,
flammable
gases.
This
review
systematically
examines
synthesis
performance
enhancements
achieved
functionalization
material
integration,
emphasizing
structure‐property
relationships,
interfacial
charge
transfer
dynamics,
adsorption
mechanisms.
Finally,
challenges
future
directions
rational
design
next‐generation
are
outlined,
providing
critical
insights
advancing
intelligent
technologies.