Atomic Ru Species Driven SnO2-Based Sensor for Highly Sensitive and Selective Detection of H2S in the ppb-Level DOI

Mingjia Zheng,

Youde Cheng,

Xiuli Zhang

et al.

ACS Sensors, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 12, 2025

Timely and accurate detection of H2S is crucial for preventing serious health issues in both humans livestock upon exposure. However, metal-oxide-based sensors often suffer from mediocre sensitivity, poor selectivity, or long response/recovery time. Here, an atomic Ru species-driven SnO2-based sensor fabricated to realize highly sensitive selective at the parts per billion level as low 100 ppb. The shows a high sensing response (Rair/Rgas = 310.1) ultrafast time (less than 1 s) 20 ppm operating temperature 160 °C. Operando SR-FTIR spectroscopic characterizations DFT calculations prove that superior properties can be mainly attributed driven effect species on formation surface-adsorbed oxygen surface SnO2, which provides more active sites enhances performance SnO2 H2S. Furthermore, lab-made wireless portable monitoring system developed rapidly detect early warning, suggesting potential application system. This work novel approach fabricating gas by metal loaded metal-oxide semiconductors.

Language: Английский

Facile physical entrapment of halochromic dye via UV-photografting for the fabrication of colorimetric cotton sensors to detect toxic ammonia gas DOI Creative Commons
Sanghyun Yoon, Youngki Park, Joonseok Koh

et al.

Progress in Organic Coatings, Journal Year: 2024, Volume and Issue: 192, P. 108450 - 108450

Published: April 27, 2024

Textile-based halochromic gas sensors are useful for detecting volatile organic compounds (VOCs) such as ammonia, because they undergo changes that distinguishable to the naked eye. Herein, we report UV photografting system developed fabrication of cotton with reduced amounts salt, resources, and effluents. First, 4-hydroxycoumarin-based dye (HD) was synthesized a indicator, where after dye, monomer, photoinitiators were introduced bath fabricate system. This produced by grafting monomers on fiber surface under light irradiation formulate polymer network entraps molecules. A series different monomer concentrations bath. Subsequently, dyeability detection performance fabricated evaluated. In addition, fastness reusability tests performed ensure durable sustainable. The increased concentration color change upon exposure ammonia followed same tendency. sensor prepared highest underwent distinctive 300 s (ΔE > 15). Furthermore, exhibited remarkable durability washing (wash level: 5, ΔE maintenance rate washing: ∼85 %) rubbing (rubbing 4/5, rubbing: ∼95 %). Reusability testing showed property retained repeated (10 cycles). results confirmed UV-induced had been optimized suggested offered an eco-friendly alternative conventional dyeing textile sensors.

Language: Английский

Citations

6

Influence of the Pd Oxidation State in PdNi Thin Films on Surface Acoustic Wave Hydrogen Sensing Performance DOI
Jing Jin,

Baile Cui,

Linyu Zhou

et al.

ACS Sensors, Journal Year: 2024, Volume and Issue: 9(5), P. 2395 - 2401

Published: May 9, 2024

PdNi alloy thin films demonstrate exceptional hydrogen sensing performance and exhibit significant potential for application in surface acoustic wave (SAW) sensors. However, the long-term stability of SAW H2 sensors utilizing as catalysts experiences a substantial decrease during operation. In this paper, X-ray photoelectron spectroscopy (XPS) is employed to investigate failure mechanisms under operational conditions. The XPS analysis reveals that formation PdO species on plays crucial role sensing. Additionally, density functional theory (DFT) calculations indicate atoms encounter diffusion energy barrier penetration process from PdNiOx subsurface region. identification film through DFT offers valuable insights into development gas with enhanced stability. Guided by these mechanisms, we propose method restore response time magnitude certain extent reducing partially oxidized atmosphere at 70 °C, thereby restoring Pd its metallic state zero valence.

Language: Английский

Citations

4

Flexible Hybrid Nanostructured Chemiresistive Sensing Platform for Low-Temperature Trace Hydrogen Detection DOI
Gulshan Verma,

Hind Kadiri,

Anisha Gokarna

et al.

Sensors and Actuators B Chemical, Journal Year: 2024, Volume and Issue: 422, P. 136621 - 136621

Published: Sept. 10, 2024

Language: Английский

Citations

4

High-Aspect-Ratio In2–xGaxO3 Integrated with Amorphous Al2O3 Nanofibers: All-Inorganic Self-Supporting Wearable Membranes for Ultralow-Concentration NO Sensing in Simulated Exhalation DOI
Yumeng Liu, Jia Liu,

Shuangju Jia

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 6, 2025

Achieving high flexibility, breathability, and sensitivity in inorganic semiconductor gas sensors remains a substantial challenge, especially for wearable applications high-humidity environments. This study develops hyper-flexible, thermally stable, highly breathable full-inorganic, self-supporting In2–xGaxO3–Al2O3/Al2O3 nanofiber membrane sensor, fabricated using dual-spinneret electrospinning method with an interlocking design. innovative sensor has bilayer structure amorphous Al2O3 substrate layer supporting active of high-aspect-ratio interwoven In2–xGaxO3 nanofibers, providing outstanding elevated strong thermal stability. Owing to low-concentration Ga3+ doping its nanofiber-built porous design, the In1.98Ga0.02O3–Al2O3/Al2O3 demonstrates excellent sensitivity, selectivity, cycling stability detecting ultralow-concentration NO biomarker (≈15 ppb) under simulated breath conditions, without performance deterioration, even after 10000 large-angle bending cycles. work advances universal fabrication high-performance, full-inorganic breath-based diagnostic applications.

Language: Английский

Citations

0

A room temperature hydrogen sensor based on 3D self-assembled nanosheets-frame ZnO DOI

J. L. Shen,

Jun Deng, Jiawei Wang

et al.

International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 105, P. 797 - 805

Published: Jan. 28, 2025

Language: Английский

Citations

0

All-Fiber Multicomponent Gas Raman Probe Based on Platinum-Coated Capillary Enhanced Raman Spectroscopy DOI
Dexun Yang, Qilu Nie,

Mengen Cheng

et al.

ACS Sensors, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 30, 2025

This paper presents a compact all-fiber multicomponent gas Raman probe using dual-fiber architecture within platinum-coated capillary. The eliminates the need for conventional optical components like filters and dichroic mirrors by strategically employing metal coating on excitation fiber's surface to suppress interference signals. A detailed analysis of silica signal fluorescence propagation system facilitated this design. Metal-coated capillary (MCC), produced via atomic layer deposition (ALD) platinum capillaries, exhibits excellent properties environmental resilience, boosting reception. Careful alignment dual fibers relative optimizes signal-to-noise ratio enhancement. achieves detection limits 21 ppm CH4, 30 C2H4, 51 C2H6 45 s exposure, alongside rapid response time 25 (relative systems based hollow-core antiresonant fibers) robust stability. Its streamlined path design enhance practicality across diverse fields, including agriculture, industry, monitoring, healthcare, advancing technology.

Language: Английский

Citations

0

Room Temperature Operated Flexible MWCNTs/Nb2O5 Hybrid Breath Sensor for the Non-Invasive Detection of Exhaled Diabetes Biomarker DOI
Gulshan Verma, Sonu Sarraf, Aviru Kumar Basu

et al.

Journal of Materials Chemistry B, Journal Year: 2025, Volume and Issue: 13(10), P. 3460 - 3470

Published: Jan. 1, 2025

Flexible gas/breath sensors have emerged as a transformative solution in personalized healthcare, offering innovative approaches for remote, non-invasive, and continuous monitoring of health indicators from breath samples.

Language: Английский

Citations

0

Advances in semiconductor-based sensors for hazardous gas detection in coal mines DOI Creative Commons

Xuezhan Xu,

Kequan Wang,

Sheng Xue

et al.

Alexandria Engineering Journal, Journal Year: 2025, Volume and Issue: 121, P. 452 - 464

Published: March 6, 2025

Language: Английский

Citations

0

Nanosensors Based on Breathomics for Human Disease Diagnosis: a New Frontier in Personalized Healthcare DOI Creative Commons
Bakr Ahmed Taha, Ali J. Addie, Adawiya J. Haider

et al.

BioNanoScience, Journal Year: 2025, Volume and Issue: 15(2)

Published: March 14, 2025

Language: Английский

Citations

0

Co-Sensitization of ZnCo2O4 Hierarchical Microspheres with MoO3 and Ag Nanoparticles for Chemiresistive Detection of Acetone DOI
Xingtang Xu, Guang Sun, Xueling Wang

et al.

Langmuir, Journal Year: 2025, Volume and Issue: unknown

Published: March 24, 2025

Recently, the detection of acetone by using a gas sensor fabricated with metal oxide semiconductors has stimulated intense research enthusiasm, owing to its promising application in noninvasive diagnosis diabetes monitoring human exhaled breath. In this work, potential was comodification nanosheets-assembled ZnCo2O4 hierarchical microspheres (HMSs) MoO3 and Ag nanoparticles (NPs). The HMSs were synthesized via solvothermal route then sequentially modified NPs immersion, calcination, photoreduction routes. results sensing measurement indicated that after modification Ag, continuous improvement sensitivity realized on sensor. At optimal working temperature 260 °C, response best Ag/MoO3/ZnCo2O4 50 ppm 7.23, which about 3.3 1.4 times higher than MoO3/ZnCo2O4, respectively. Apart from response, selectivity speed also improved. density functional theory calculations showed enhanced absorbability for should be responsible improved

Language: Английский

Citations

0