Designing
bio-based
adhesives
with
multiple
crosslinking
networks
has
significant
implications
for
the
green
and
sustainable
development
of
forestry
industry.
A
sawdust
based
network
adhesive
system
was
constructed
by
a
small
molecule
covalent
bridge
hydrogen
bond
grafting
chain
thioctic
acid
(TA)
supramolecule
oxidized
(OS)
as
carrier
first
second
network,
which
realized
toughening
strengthening
sawdust/thioctic
(OSTA)
adhesive.
Furthermore,
wood
interface
regulated
3-glycidyl
ether
oxy
propyl
trimethoxysilane,
introduced
active
epoxy
groups
to
interface.
Then,
third
interfacial
reaction
carboxyl
group,
hydroxyl
amino
group
in
OSTA
system.
The
dry
bonding
strength
OSTA-modified
can
reach
2.09
MPa,
is
75.6%
50.4%
higher
than
that
OS
TA
adhesives,
respectively,
water
resistance
increased
from
0
MPa
1.25
1.71
MPa.
In
addition,
not
only
shows
adhesion
performance
but
also
manifests
excellently
on
various
surface
energy
substrates,
such
skin,
glass,
ceramics,
plants,
rubber,
stainless
steel,
etc.,
multi-functional
properties.
This
work
broadens
prospects
applications
scenarios.
Cellulose Chemistry and Technology,
Journal Year:
2024,
Volume and Issue:
58(7-8), P. 819 - 832
Published: Sept. 25, 2024
In
this
experimental
study,
the
usability
of
waste
corn
husk
was
investigated
as
a
source
reinforcement
material
for
first
time
in
eco-friendly
particleboard
manufacture.
For
purpose,
effect
most
appropriate
filler/binder
(f/b)
ratio
and
pressing
temperature
manufacturing
conditions
on
three-point
flexural
strength
manufacture
examined.
To
improve
mechanical
properties,
water
resistance
combustion
manufactured
particleboards,
different
amounts
silk
fiber
(0~1.50%
by
weight)
colemanite
(0~20%
were
added.
According
to
results,
husk-based
determined
f/b
0.75,
100
°C,
loading
0.75
wt%.
Additionally,
synthetic
binders
beet
molasses
used
together
The
particleboards
comply
with
specifications
EN
312
standard,
being
below
maximum
limit
values
terms
thickness
swelling,
absorption
rates.
addition,
increasing
content
board
composition,
limiting
oxygen
index
(LOI)
boards
increased.
However,
use
reduced
boards.
When
5%
added
met
minimum
value
requirement
P1
type
board,
according
312.
dimensional
stability
conditions,
is
quite
good.
Particleboards
from
husks
can
be
interior
exterior
applications
building
materials.
The
construction
of
laminated
composites
using
biomass
materials
for
furniture
manufacturing
has
important
research
value
and
practical
significance.
Gelatin,
a
renewable
non-toxic
resource,
holds
significant
potential
diverse
applications.
However,
its
low
mechanical
strength
poor
water
resistance
have
hindered
use
as
wood
adhesive.
In
this
work,
gelatin
(GE)
is
used
the
main
raw
material,
citric
acid
(CA)
sucrose
(Su)
are
to
construct
highly
efficient
crosslinking
water-resistant
structure,
GE/Su-CA
adhesive
prepared.
influence
distribution
ratio,
hot-press
temperature,
time,
other
factors
on
composite
system
studied.
FTIR,
13C
NMR,
XPS,
GPC
were
prove
that
can
be
cross-linked
with
gelatin/sucrose
form
tight
network
structure
by
covalent
or
non-covalent
binding.
Because
high
density,
it
had
better
waterproof
properties.
results
property
test
show
dry
shear
reach
1.91
MPa,
hot
immersion
boiling
1.41
MPa
1.37
respectively.
project
will
provide
new
way
prepare
high-performance
environment-friendly
gelatin-based
composites.
Designing
bio-based
adhesives
with
multiple
crosslinking
networks
has
significant
implications
for
the
green
and
sustainable
development
of
forestry
industry.
A
sawdust
based
network
adhesive
system
was
constructed
by
a
small
molecule
covalent
bridge
hydrogen
bond
grafting
chain
thioctic
acid
(TA)
supramolecule
oxidized
(OS)
as
carrier
first
second
network,
which
realized
toughening
strengthening
sawdust/thioctic
(OSTA)
adhesive.
Furthermore,
wood
interface
regulated
3-glycidyl
ether
oxy
propyl
trimethoxysilane,
introduced
active
epoxy
groups
to
interface.
Then,
third
interfacial
reaction
carboxyl
group,
hydroxyl
amino
group
in
OSTA
system.
The
dry
bonding
strength
OSTA-modified
can
reach
2.09
MPa,
is
75.6%
50.4%
higher
than
that
OS
TA
adhesives,
respectively,
water
resistance
increased
from
0
MPa
1.25
1.71
MPa.
In
addition,
not
only
shows
adhesion
performance
but
also
manifests
excellently
on
various
surface
energy
substrates,
such
skin,
glass,
ceramics,
plants,
rubber,
stainless
steel,
etc.,
multi-functional
properties.
This
work
broadens
prospects
applications
scenarios.