Photocatalytic Conversion of Formic Acid to Syngas (CO + H2) and Methane with Homogeneous Molecular Cobaloxime Catalysts DOI
Taotao Wang, Li Zhang,

Jin-Bao Wu

et al.

The Journal of Physical Chemistry C, Journal Year: 2024, Volume and Issue: 128(31), P. 12849 - 12857

Published: July 26, 2024

The catalytic conversion of formic acid is a promising method for accessing clean fuels. H2 and CO, as products the process, have been extensively researched, but other direct processes remain to be developed. Herein, first time, we report use homogeneous molecular cobaloxime catalysts combined with CdS nanorods (NRs) highly efficient photocatalytic system produce syngas CH4 from HCOOH. As result, highest rate production reached 80.5 μmol g–1 h–1, CO evolution rates 60.5 24 mmol respectively. Moreover, also markedly enhanced long-term stability resulting material gas evolution. superior performance can attributed promoted charge transfer separation in systems. This work provides new insights into

Language: Английский

Engineering semiconductor quantum dots for co-upcycling of CO2 and biomass-derived alcohol DOI

Lin-Xing Zhang,

Zi‐Rong Tang, Ming–Yu Qi

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(30), P. 19029 - 19038

Published: Jan. 1, 2024

A heterointerface engineering strategy of immobilizing core–shell CdSe/CdS quantum dots onto SiO 2 spheres was realized to efficiently integrate CO photoreduction with the oxidation furfuryl alcohol in one system.

Language: Английский

Citations

32
Photocatalytic and Electrochemical Synthesis of Biofuel via Efficient Valorization of Biomass DOI Creative Commons

Dalin Sun,

Yan Zhang, Yue Zhou

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 3, 2025

Abstract The excessive use of fossil fuels has significantly increased environmental stress, driving the need for green, sustainable biofuel alternatives. Innovations in photocatalysis (PC), electrocatalysis (EC), and their synergistic approaches, like photothermal catalysis (PTC), photo‐enzymatic (PENC), photoelectrocatalysis (PEC), offer advanced methods biomass conversion into biofuels, surpassing traditional limitations. However, comprehensive research on these processes is still lacking. This review aims to systematically analyze recent progress catalytic strategies biomass‐to‐biofuel conversion. It first describes characteristics, types, properties biofuels. Then, it explores fundamental mechanisms PC, EC, combined technologies. chemical pathways involved conversion—such as transesterification, esterification, hydrogenation, decarboxylation, bond cleavage, cyclization—are examined. Efficient catalyst design specific reactions factors influencing efficiency rates are also discussed. Additionally, this paper assesses impact economic benefits green technology production, offering a valuable reference energy application. addresses challenges deployment production suggests future directions, aiming provide scientific guidance technical support development vital field. In summary, underscores importance continued innovation promote solutions.

Language: Английский

Citations

1
Photothermal-assisted magnetic recoverable Cd0.9Zn0.1S/NiCoB heterojunction with extraordinary photocatalytic hydrogen evolution DOI
Zeshuang Kong,

Jixian Dong,

Jiahui Yu

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 678, P. 1026 - 1035

Published: Sept. 13, 2024

Language: Английский

Citations

8
Photocatalytic Conversion of Formic Acid to Syngas (CO + H2) and Methane with Homogeneous Molecular Cobaloxime Catalysts DOI
Taotao Wang, Li Zhang,

Jin-Bao Wu

et al.

The Journal of Physical Chemistry C, Journal Year: 2024, Volume and Issue: 128(31), P. 12849 - 12857

Published: July 26, 2024

The catalytic conversion of formic acid is a promising method for accessing clean fuels. H2 and CO, as products the process, have been extensively researched, but other direct processes remain to be developed. Herein, first time, we report use homogeneous molecular cobaloxime catalysts combined with CdS nanorods (NRs) highly efficient photocatalytic system produce syngas CH4 from HCOOH. As result, highest rate production reached 80.5 μmol g–1 h–1, CO evolution rates 60.5 24 mmol respectively. Moreover, also markedly enhanced long-term stability resulting material gas evolution. superior performance can attributed promoted charge transfer separation in systems. This work provides new insights into

Language: Английский

Citations

0