C2H2/CO2 Separation by a Carborane Hybrid 2D Metal–Organic Framework DOI
Changhong Liu, Yingzhi He, Shuangshuang Wu

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 6, 2025

The separation of acetylene (C2H2) from carbon dioxide (CO2) is important in industry but challenging due to their similar physical properties. Herein, a boron-rich 2D metal-organic framework ZNU-14 based on the carborane backbone was readily prepared by supramolecular assembly Zn2+, p-C2B10H10-(COOH)2, and di(pyridin-4-yl) amine under mild conditions for C2H2/CO2 separation. displays straight 1D channel (7.6 × 12.5 Å2) with an electronegative pore surface. Gas adsorption isotherms show that has good C2H2 capacity 43.6 cm3 g-1, 181% CO2 uptake capacity. calculated ideal adsorbed solution theory (IAST) selectivity as high 6.3-9.7, outperforming many popular materials. moderate heat 34.3 kJ mol-1 facilitates straightforward desorption regeneration ZNU-14. Furthermore, theoretical study confirmed stronger binding compared CO2. practical performance fully demonstrated breakthrough experiments excellent dynamic recyclability various conditions.

Language: Английский

Recent progress on customizable multi-dimensional carbon-supported metal–organic frameworks (Cx/MOFs) composites for efficient adsorption of gases and vapors DOI
Weiqiu Huang, Yuning Li, Xufei Li

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132203 - 132203

Published: Feb. 1, 2025

Language: Английский

Citations

0
C2H2/CO2 Separation by a Carborane Hybrid 2D Metal–Organic Framework DOI
Changhong Liu, Yingzhi He, Shuangshuang Wu

et al.

Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: May 6, 2025

The separation of acetylene (C2H2) from carbon dioxide (CO2) is important in industry but challenging due to their similar physical properties. Herein, a boron-rich 2D metal-organic framework ZNU-14 based on the carborane backbone was readily prepared by supramolecular assembly Zn2+, p-C2B10H10-(COOH)2, and di(pyridin-4-yl) amine under mild conditions for C2H2/CO2 separation. displays straight 1D channel (7.6 × 12.5 Å2) with an electronegative pore surface. Gas adsorption isotherms show that has good C2H2 capacity 43.6 cm3 g-1, 181% CO2 uptake capacity. calculated ideal adsorbed solution theory (IAST) selectivity as high 6.3-9.7, outperforming many popular materials. moderate heat 34.3 kJ mol-1 facilitates straightforward desorption regeneration ZNU-14. Furthermore, theoretical study confirmed stronger binding compared CO2. practical performance fully demonstrated breakthrough experiments excellent dynamic recyclability various conditions.

Language: Английский

Citations

0