Side Reactions/Changes in Lithium‐Ion Batteries: Mechanisms and Strategies for Creating Safer and Better Batteries DOI Creative Commons
Hao Du, Yadong Wang,

Yuqiong Kang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(29)

Published: May 2, 2024

Lithium-ion batteries (LIBs), in which lithium ions function as charge carriers, are considered the most competitive energy storage devices due to their high and power density. However, battery materials, especially with capacity undergo side reactions changes that result decay safety issues. A deep understanding of cause battery's internal components mechanisms those is needed build safer better batteries. This review focuses on processes failures, voltage temperature underlying factors. Voltage-induced failures from anode interfacial reactions, current collector corrosion, cathode overcharge, over-discharge, while temperature-induced failure include SEI decomposition, separator damage, between electrodes electrolytes. The also presents protective strategies for controlling these reactions. As a result, reader offered comprehensive overview features various LIB components.

Language: Английский

Prospects for lithium-ion batteries and beyond—a 2030 vision DOI Creative Commons
Clare P. Grey, David S. Hall

Nature Communications, Journal Year: 2020, Volume and Issue: 11(1)

Published: Dec. 8, 2020

It would be unwise to assume 'conventional' lithium-ion batteries are approaching the end of their era and so we discuss current strategies improve next generation systems, where a holistic approach will needed unlock higher energy density while also maintaining lifetime safety. We by briefly reviewing areas fundamental science advances enable revolutionary new battery systems.

Language: Английский

Citations

650
Phase Behavior during Electrochemical Cycling of Ni‐Rich Cathode Materials for Li‐Ion Batteries DOI
Chao Xu, Philip J. Reeves, Quentin Jacquet

et al.

Advanced Energy Materials, Journal Year: 2020, Volume and Issue: 11(7)

Published: Dec. 21, 2020

Abstract Although layered lithium nickel‐rich oxides have become the state‐of‐the‐art cathode materials for lithium‐ion batteries in electric vehicle (EV) applications, they can suffer from rapid performance failure—particularly when operated under conditions of stress (temperature, high voltage)‐the underlying mechanisms which are not fully understood. This essay aims to connect electrochemical with changes structure during cycling. First, structural properties LiNiO 2 compared substituted Ni‐rich compounds NMCs (LiNi x Mn y Co 1− − O ) and NCAs Al ). Particular emphasis is placed on decoupling intrinsic behavior extrinsic “two‐phase” reactions observed initial cycles, as well after extensive cycling NMC NCA cathodes. The need revisit various high‐voltage that occur modern characterization tools highlighted aid understanding accelerated degradation cathodes at voltages.

Language: Английский

Citations

272
Toward practical lithium-ion battery recycling: adding value, tackling circularity and recycling-oriented design DOI
Jianfeng Mao, Chao Ye, Shilin Zhang

et al.

Energy & Environmental Science, Journal Year: 2022, Volume and Issue: 15(7), P. 2732 - 2752

Published: Jan. 1, 2022

Recent progress in battery recycling is critically reviewed, including closed-loop design of new batteries and recycling-oriented configurations components, together with an appraisal predicted future research.

Language: Английский

Citations

227
Pushing the limit of 3d transition metal-based layered oxides that use both cation and anion redox for energy storage DOI
Minghao Zhang,

Daniil A. Kitchaev,

Zachary W. Lebens-Higgins

et al.

Nature Reviews Materials, Journal Year: 2022, Volume and Issue: 7(7), P. 522 - 540

Published: Feb. 8, 2022

Language: Английский

Citations

184
Research Progresses of Liquid Electrolytes in Lithium‐Ion Batteries DOI

Yu‐Kun Liu,

Chen‐Zi Zhao, Juan Du

et al.

Small, Journal Year: 2022, Volume and Issue: 19(8)

Published: Dec. 5, 2022

Abstract In recent years, the rapid development of modern society is calling for advanced energy storage to meet growing demands supply and generation. As one most promising systems, secondary batteries are attracting much attention. The electrolyte an important part battery, its composition closely related electrochemical performance batteries. Lithium‐ion battery mainly composed solvents, additives, lithium salts, which prepared according specific proportions under certain conditions needs characteristics. This review analyzes advantages current problems liquid electrolytes in lithium‐ion (LIBs) from mechanism action failure mechanism, summarizes research progress future trends requirements electrolytes, points out emerging opportunities development.

Language: Английский

Citations

171
Two electrolyte decomposition pathways at nickel-rich cathode surfaces in lithium-ion batteries DOI Creative Commons
Bernardine L. D. Rinkel, J. Padmanabhan Vivek, Nuria Garcı́a-Aráez

et al.

Energy & Environmental Science, Journal Year: 2022, Volume and Issue: 15(8), P. 3416 - 3438

Published: Jan. 1, 2022

Preventing the decomposition reactions of electrolyte solutions is essential for extending lifetime lithium-ion batteries. However, exact mechanism(s) at positive electrode, and particularly soluble products that form initiate further negative are still largely unknown. In this work, a combination operando gas measurements solution NMR was used to study NMC (LiNi x Mn y Co1-x-y O2) LCO (LiCoO2) electrodes. A partially delithiated LFP (Li FePO4) counter electrode selectively identify formed through processes Based on detected gaseous products, two distinct routes with different onset potentials proposed At low (<80% state-of-charge, SOC), ethylene carbonate (EC) dehydrogenated vinylene (VC) surface, whereas high (>80% 1O2 released from transition metal oxide chemically oxidises solvent CO2, CO H2O. The formation water via mechanism confirmed by reacting 17O-labelled EC characterising reaction via1H 17O spectroscopy. produced initiates secondary reactions, leading various identified Noticeably fewer were in NMC/graphite cells compared NMC/Li FePO4 cells, which ascribed consumption (from EC) graphite preventing reactions. insights mechanisms contribute understanding origin capacity loss hoped support development strategies mitigate degradation NMC-based cells.

Language: Английский

Citations

164
Comprehensive recycling of lithium-ion batteries: Fundamentals, pretreatment, and perspectives DOI
Wenhao Yu, Yi Guo, Shengming Xu

et al.

Energy storage materials, Journal Year: 2022, Volume and Issue: 54, P. 172 - 220

Published: Oct. 17, 2022

Language: Английский

Citations

147
Electrolyte Reactivity at the Charged Ni-Rich Cathode Interface and Degradation in Li-Ion Batteries DOI Creative Commons
Wesley M. Dose, Israel Temprano, J. P. Allen

et al.

ACS Applied Materials & Interfaces, Journal Year: 2022, Volume and Issue: 14(11), P. 13206 - 13222

Published: March 8, 2022

The chemical and electrochemical reactions at the positive electrode-electrolyte interface in Li-ion batteries are hugely influential on cycle life safety. Ni-rich layered transition metal oxides exhibit higher interfacial reactivity than their lower Ni-content analogues, reacting via mechanisms that poorly understood. Here, we study pivotal role of electrolyte solvent, specifically cyclic ethylene carbonate (EC) linear ethyl methyl (EMC), determining charged LiNi0.33Mn0.33Co0.33O2 (NMC111) LiNi0.8Mn0.1Co0.1O2 (NMC811) cathodes by using both single-solvent model electrolytes mixed solvents used commercial cells. While NMC111 exhibits similar parasitic currents with EC-containing EC-free during high voltage holds NMC/Li4Ti5O12 (LTO) cells, this is not case for NMC811. Online gas analysis reveals solvent-dependent related to extent lattice oxygen release accompanying decomposition, which electrolytes. Combined findings from impedance spectroscopy (EIS), TEM, solution NMR, ICP, XPS reveal solvent has a profound impact degradation cathode electrolyte. Higher coupled impedance, thicker oxygen-deficient rock-salt surface reconstruction layer, more salt breakdown, amounts dissolution. These processes suppressed electrolyte, highlighting incompatibility between conventional solvents. Finally, new mechanistic insights into oxidation pathways and, critically, knock-on further degrade electrodes curtailing battery lifetime provided.

Language: Английский

Citations

108
Hollow-core optical fibre sensors for operando Raman spectroscopy investigation of Li-ion battery liquid electrolytes DOI Creative Commons
Ermanno Miele, Wesley M. Dose,

Ilya Manyakin

et al.

Nature Communications, Journal Year: 2022, Volume and Issue: 13(1)

Published: March 28, 2022

Improved analytical tools are urgently required to identify degradation and failure mechanisms in Li-ion batteries. However, understanding ultimately avoiding these detrimental requires continuous tracking of complex electrochemical processes different battery components. Here, we report an operando spectroscopy method that enables monitoring the chemistry a carbonate-based liquid electrolyte during cycling batteries with graphite anode LiNi0.8Mn0.1Co0.1O2 cathode. By embedding hollow-core optical fibre probe inside lab-scale pouch cell, demonstrate effective evolution species by background-free Raman spectroscopy. The analysis measurements reveals changes ratio carbonate solvents additives as function cell voltage show potential track lithium-ion solvation dynamics. proposed methodology contributes better current limitations paves way for studies energy storage systems.

Language: Английский

Citations

93
High‐Voltage Electrolyte Chemistry for Lithium Batteries DOI Creative Commons

Kanglong Guo,

Shihan Qi, Huaping Wang

et al.

Small Science, Journal Year: 2022, Volume and Issue: 2(5)

Published: Feb. 18, 2022

Lithium batteries are currently the most popular and promising energy storage system, but current lithium battery technology can no longer meet people's demand for high density devices. Increasing charge cutoff voltage of a greatly increase its density. However, as increases, series unfavorable factors emerges in causing rapid failure batteries. To overcome these problems extend life high‐voltage batteries, electrolyte modification strategies have been widely adopted. Under this content, review first introduces degradation mechanism under voltage, then presents an overview recent progress using strategies. Finally, future direction electrolytes is also proposed.

Language: Английский

Citations

91