Green Energy & Environment,
Journal Year:
2023,
Volume and Issue:
9(2), P. 217 - 310
Published: Jan. 3, 2023
Carbon
peaking
and
carbon
neutralization
trigger
a
technical
revolution
in
energy
&
environment
related
fields.
Development
of
new
technologies
for
green
production
storage,
industrial
saving
efficiency
reinforcement,
capture,
pollutant
gas
treatment
is
highly
imperious
demand.
The
emerging
porous
framework
materials
such
as
metal–organic
frameworks
(MOFs),
covalent
organic
(COFs)
hydrogen-bonded
(HOFs),
owing
to
the
permanent
porosity,
tremendous
specific
surface
area,
designable
structure
customizable
functionality,
have
shown
great
potential
major
energy-consuming
processes,
including
sustainable
catalytic
conversion,
energy-efficient
separation
storage.
Herein,
this
manuscript
presents
systematic
review
global
comprehensive
applications,
from
macroscopic
application
perspective.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(13)
Published: Jan. 24, 2022
Owing
to
the
finite
building
blocks
and
difficulty
in
structural
identification,
it
remains
a
tremendous
challenge
elaborately
design
synthesize
three-dimensional
covalent
organic
frameworks
(3D
COFs)
with
predetermined
topologies.
Herein,
we
report
first
two
cases
of
3D
COFs
non-interpenetrated
hea
net,
termed
JUC-596
JUC-597,
by
using
combination
tetrahedral
triangular
prism
units.
Due
presence
triptycene
functional
groups
fluorine
atoms,
exhibits
an
exceptional
performance
H2
adsorption
up
305
cm3
g-1
(or
2.72
wt%)
at
77
K
1
bar,
which
is
higher
than
previous
benchmarks
from
porous
materials
reported
so
far.
Furthermore,
strong
interaction
between
COF
verified
through
DFT
theoretical
calculations.
This
work
represents
captivating
example
rational
based
on
reticular
chemistry
guide
demonstrates
its
promising
application
clean
energy
storage.
Green Energy & Environment,
Journal Year:
2023,
Volume and Issue:
9(2), P. 217 - 310
Published: Jan. 3, 2023
Carbon
peaking
and
carbon
neutralization
trigger
a
technical
revolution
in
energy
&
environment
related
fields.
Development
of
new
technologies
for
green
production
storage,
industrial
saving
efficiency
reinforcement,
capture,
pollutant
gas
treatment
is
highly
imperious
demand.
The
emerging
porous
framework
materials
such
as
metal–organic
frameworks
(MOFs),
covalent
organic
(COFs)
hydrogen-bonded
(HOFs),
owing
to
the
permanent
porosity,
tremendous
specific
surface
area,
designable
structure
customizable
functionality,
have
shown
great
potential
major
energy-consuming
processes,
including
sustainable
catalytic
conversion,
energy-efficient
separation
storage.
Herein,
this
manuscript
presents
systematic
review
global
comprehensive
applications,
from
macroscopic
application
perspective.