
Chem Catalysis, Journal Year: 2022, Volume and Issue: 2(11), P. 3163 - 3173
Published: Sept. 8, 2022
Language: Английский
Chem Catalysis, Journal Year: 2022, Volume and Issue: 2(11), P. 3163 - 3173
Published: Sept. 8, 2022
Language: Английский
Chem Catalysis, Journal Year: 2024, Volume and Issue: 4(3), P. 100903 - 100903
Published: Feb. 1, 2024
Language: Английский
Citations
12ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 4541 - 4549
Published: March 3, 2025
Language: Английский
Citations
1Organic Letters, Journal Year: 2021, Volume and Issue: 23(22), P. 8683 - 8687
Published: Nov. 4, 2021
The asymmetric synthesis of P-stereogenic phosphinates through allylic alkylation H-phosphinates has been developed. With and acetates as the starting materials, a variety P-chiral were accessed in high enantioselectivities up to 92% ee generally yields. In addition, further study demonstrated applicability this protocol, including scale-up facile transformation chiral products from phosphine oxides with organolithium reagents under mild reaction conditions.
Language: Английский
Citations
47Chemical Science, Journal Year: 2022, Volume and Issue: 13(5), P. 1307 - 1312
Published: Jan. 1, 2022
Chiral bisphosphine ligands are of key importance in transition-metal-catalyzed asymmetric synthesis optically active products. However, the transition metals typically used scarce and expensive noble metals, while synthetic routes to access chiral phosphine cumbersome lengthy. To make homogeneous catalysis more sustainable, progress must be made on both fronts. Herein, we present first catalytic hydrophosphination α,β-unsaturated oxides presence a complex earth-abundant manganese(i). This system offers short two-step, one-pot sequence easily accessible structurally tunable 1,2-bisphosphines high yields enantiomeric excess. The resulting bidentate were successfully as part metal based organometallic catalysts.
Language: Английский
Citations
37Chem Catalysis, Journal Year: 2022, Volume and Issue: 2(11), P. 3163 - 3173
Published: Sept. 8, 2022
Language: Английский
Citations
29