Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(33)
Published: May 27, 2024
Triggering
the
lattice
oxygen
oxidation
mechanism
is
crucial
for
improving
evolution
reaction
(OER)
performance,
because
it
could
bypass
scaling
relation
limitation
associated
with
conventional
adsorbate
through
direct
formation
of
oxygen-oxygen
bond.
High-valence
transition
metal
sites
are
favorable
activating
oxygen,
but
deep
pre-catalysts
suffers
from
a
high
thermodynamic
barrier.
Here,
taking
advantage
Jahn-Teller
(J-T)
distortion
induced
structural
instability,
we
incorporate
high-spin
Mn
Chemical Society Reviews,
Journal Year:
2024,
Volume and Issue:
53(3), P. 1447 - 1494
Published: Jan. 1, 2024
A
comprehensive
overview
on
organic
polymers
as
electrocatalysts
is
summarized.
By
presenting
the
engineering
strategies,
insightful
understandings,
challenges,
and
perspectives,
we
hope
this
review
can
provide
valuable
references
for
readers.
Small Science,
Journal Year:
2023,
Volume and Issue:
3(9)
Published: Aug. 2, 2023
Developing
energy
production,
storage,
and
conversion
technologies
based
on
sustainable
or
renewable
is
essential
to
address
the
environmental
crisis.
Electrochemical
water
splitting
one
of
most
promising
approaches
realize
production
green
hydrogen.
The
design
catalytic
materials
with
low
cost,
high
activity,
long‐term
stability
exploration
specific
reaction
mechanisms
are
key
focus
for
involved
electrochemical
hydrogen
evolution
(HER).
Recently,
substantial
efforts
have
been
devoted
rational
synthesis
non‐noble
metallic
heterostructures
fascinating
synergistic
effects
among
different
components.
These
heterostructured
demonstrate
comprehensive
properties
exceeding
estimations
by
rule
mixtures
display
activity
in
industrial
conditions
HER.
Herein,
mechanism
parameters
improving
performance
HER
process
discussed
detail.
latest
advances
synthetic
methods
electrocatalytic
characteristics
from
experimental
computational
perspectives
summarized
according
role
various
insights
provided
this
review
into
an
in‐depth
understanding
as
electrocatalysts,
opportunities
challenges
scale
up
future‐oriented
developments
highlighted.
Materials Chemistry Frontiers,
Journal Year:
2023,
Volume and Issue:
7(20), P. 4833 - 4864
Published: Jan. 1, 2023
This
review
provides
a
comprehensive
of
recent
advances
in
the
design
OER
catalysts.
Specifically,
it
focuses
on
kinetics
and
stability
catalysts,
catalytic
mechanism
innovative
strategies.
Advanced Science,
Journal Year:
2023,
Volume and Issue:
10(32)
Published: Oct. 2, 2023
Abstract
Researchers
are
investigating
innovative
composite
materials
for
renewable
energy
and
storage
systems.
The
major
goals
of
this
studies
i)
to
develop
a
low‐cost
stable
trimetallic
oxide
catalyst
ii)
change
the
electrical
environment
active
sites
through
site‐selective
Mo
substitution.
effect
on
NiCoMoO
4
is
elucidated
using
both
in
situ
X‐ray
absorption
spectroscopy
diffraction
analysis.
Also,
density
functional
theory
strategies
show
that
has
extraordinary
catalytic
redox
activity
because
high
adsorption
atom
crystal
plane.
Further,
it
demonstrated
hierarchical
nanoflower
structures
reduced
graphene
can
be
employed
as
powerful
bifunctional
electrocatalyst
oxygen
reduction/evolution
reactions
alkaline
solutions,
providing
small
overpotential
difference
0.75
V.
Zn–air
batteries
based
developed
exhibit
outstanding
cycling
stability
high‐power
125.1
mW
cm
−2
.
This
work
encourages
use
practical
applications
provides
an
interesting
concept
designing
electrocatalyst.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(33)
Published: May 27, 2024
Triggering
the
lattice
oxygen
oxidation
mechanism
is
crucial
for
improving
evolution
reaction
(OER)
performance,
because
it
could
bypass
scaling
relation
limitation
associated
with
conventional
adsorbate
through
direct
formation
of
oxygen-oxygen
bond.
High-valence
transition
metal
sites
are
favorable
activating
oxygen,
but
deep
pre-catalysts
suffers
from
a
high
thermodynamic
barrier.
Here,
taking
advantage
Jahn-Teller
(J-T)
distortion
induced
structural
instability,
we
incorporate
high-spin
Mn