Asian Journal of Organic Chemistry,
Journal Year:
2023,
Volume and Issue:
12(10)
Published: Aug. 23, 2023
Abstract
In
the
last
two
decades,
chiral
hydrogen
bonding
catalysis
has
been
enormously
utilized
to
trigger
several
valuable
synthetic
transformations.
Similarly,
modern
day
radical
chemistry
witnessed
potency
of
visible
light
photoredox
generate
radicals
via
single
electron
transfer
pathway.
Recently,
their
cooperative
effect
proved
be
a
key
strategy
access
many
elegant
transformations
that
are
only
feasible
under
synergistic
action
these
catalytic
systems.
This
dual
system
demonstrates
high
efficiency
for
introducing
molecular
complexity
in
an
enantioselective
fashion.
this
mini
review,
we
have
compiled
most
recent
development
surfaced
three
years
with
particular
attention
paid
mechanistic
details
and
its
substrate
scope.
We
hope
review
will
provide
readers
brief
overview
advancement
application
catalysts
bond
donors
reactions.
Advanced Synthesis & Catalysis,
Journal Year:
2023,
Volume and Issue:
365(18), P. 3044 - 3062
Published: July 28, 2023
Abstract
Chiral
phosphoric
acid
(
CPA
)
has
been
established
as
a
cornerstone
in
chemical
synthesis
reactions
for
over
five
decades,
owing
to
its
distinctive
molecular
structure
and
remarkable
catalytic
effect.
However,
recent
years,
revolutionary
approach
asymmetric
emerged,
utilizing
photocatalytic
excitation
of
molecules
generate
free
radicals,
effectively
surpassing
the
limitations
classical
organic
methodologies.A
prominent
significant
area
research
dedicated
investigation
chiral
synergistic
photocatalysis
enantioselective
synthesis.
This
unique
system
encompasses
bifunctional
hydrogen‐bonding
catalyst,
enabling
simultaneous
interactions
between
radical
intermediates
substrates.
The
review
paper
focuses
on
application
progress
this
throughout
past
decade.
Asian Journal of Organic Chemistry,
Journal Year:
2023,
Volume and Issue:
12(10)
Published: Aug. 23, 2023
Abstract
In
the
last
two
decades,
chiral
hydrogen
bonding
catalysis
has
been
enormously
utilized
to
trigger
several
valuable
synthetic
transformations.
Similarly,
modern
day
radical
chemistry
witnessed
potency
of
visible
light
photoredox
generate
radicals
via
single
electron
transfer
pathway.
Recently,
their
cooperative
effect
proved
be
a
key
strategy
access
many
elegant
transformations
that
are
only
feasible
under
synergistic
action
these
catalytic
systems.
This
dual
system
demonstrates
high
efficiency
for
introducing
molecular
complexity
in
an
enantioselective
fashion.
this
mini
review,
we
have
compiled
most
recent
development
surfaced
three
years
with
particular
attention
paid
mechanistic
details
and
its
substrate
scope.
We
hope
review
will
provide
readers
brief
overview
advancement
application
catalysts
bond
donors
reactions.
