Metal-organic cages containing two types of binding sites: trapping hydrocarbon gas in solution DOI
Meng‐Ying Sun, Mo Xie,

Chuang‐Wei Zhou

et al.

Science China Chemistry, Journal Year: 2023, Volume and Issue: 66(7), P. 2004 - 2010

Published: June 8, 2023

Language: Английский

Subtle adjustments for constructing multi-nuclear luminescent lanthanide organic polyhedra with triazole-based chelates DOI Creative Commons
Xiaoqing Guo, Li‐Peng Zhou,

Shao‐Jun Hu

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: 53(10), P. 4772 - 4780

Published: Jan. 1, 2024

Subtle chelating arm tweaks facilitate controlled high-nuclear LOP synthesis and enhance lanthanide ion luminescence, offering a unique construction method.

Language: Английский

Citations

4
Deciphering the mechanism of structural transformation between Pd3L6 and Pd4L8 metal-organic cages DOI

Xian‐Chao Zhou,

Y. Tan,

Ying-Ying Ge

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 20, 2025

Language: Английский

Citations

0
Concentration Gradient-Induced Syntheses and Crystal Structures of Two Copper(II) Coordination Polymer Based on Phthalic Acid and 2,2′-Bipyridine DOI Creative Commons
Tao Zhou, Gengyi Zhang,

Chunhong Tan

et al.

Molecules, Journal Year: 2025, Volume and Issue: 30(9), P. 1953 - 1953

Published: April 28, 2025

The reaction of copper nitrate, phthalic acid (1,2-H2BDC), and bipyridine in ammonia/ethanol media affords two multi-copper (II) cluster-based coordination polymers, namely {[Cu4(bpy)4(OH)2(BDC)2]·2OH·13H2O}n (USC-CP-6) {[Cu2(BDC)2(bpy)2(H2O)]·3H2O}n (USC-CP-7), under ambient conditions, with CP-6 forming at the bottom CP-7 upper edge same beaker. single-crystal structures reveal that it is a rare case gradient-induced formation different multi-copper(II) CPs within single-solution chemical reaction. crystallizes monoclinic system, sp. gr. P21/c, composed chair-like tetranuclear [Cu4(μ3-OH)2(bpy)4(BDC)2]2+ clusters as secondary building units, bridged by BDC2- ligands to form two-dimensional layer framework, while P21/n, binuclear [Cu2(1,2-BDC)2(bpy)2(H2O)] linked bridging one-dimensional looped double chain. Through intermolecular π-π stacking hydrogen bonds between water, lattice free oxygen atoms from carboxylate, both compounds yield 3D supramolecular structure.

Language: Английский

Citations

0
A Double‐Walled Tetrahedron with AgI4 Vertices Binds Different Guests in Distinct Sites** DOI Creative Commons
Samuel E. Clark, Andrew W. Heard, Charlie T. McTernan

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(16)

Published: Feb. 23, 2023

A double-walled tetrahedral metal-organic cage assembled in solution from silver(I), 2-formyl-1,8-naphthyridine, halide, and a threefold-symmetric triamine. The AgI4 X clusters at its vertices each bring together six naphthyridine-imine moieties, leading to structure which eight tritopic ligands bridge four an (AgI4 X)4 L8 arrangement. Four form inner set of tetrahedron walls that are surrounded by the outer four. has significant interior volume, was observed bind anionic guests. also possesses external binding clefts, located edges cage, bound small aromatic Halide ions silver were exchange well-defined hierarchy, allowing modulation cavity volume. principles uncovered here may allow for increasingly more sophisticated cages with silver-cluster vertex architectures, post-assembly tuning volume enabling targeted behavior.

Language: Английский

Citations

9
Metal-organic cages containing two types of binding sites: trapping hydrocarbon gas in solution DOI
Meng‐Ying Sun, Mo Xie,

Chuang‐Wei Zhou

et al.

Science China Chemistry, Journal Year: 2023, Volume and Issue: 66(7), P. 2004 - 2010

Published: June 8, 2023

Language: Английский

Citations

9